氢

With the characterization of NMR and IR, combining with the synthesis of active species and studies of their structures, it is suggested that the hydride [RuHCl(PPh3)3], being favorably formed in the acid media, exhibited higher activity in the reduction of the C=C bond, while the hydride [RuH4(PPh3)3], being preponderantly formed in the basic media, showed activity and higher selectivity towards the C=O reduction.

通过核磁、红外等表征手段，并结合可能催化活性配合物的合成和结构研究，推测了在非水介质中对C=C和C=O双键起到活化作用的催化剂活性物种和可能的选择加氢反应机理，即，催化剂[RuCl2(PPh3)3]在酸性环境下倾向于生成[RuHCl(PPh3)3]物种，该Ru-H物种对C=C双键加氢反应表现出较高的活性；而碱性环境下则易于生成[RuH4(PPh3)3]物种，该Ru-H物种对C=O双键加氢具有较高的催化活性。

Study on Surface Enhanced Raman Scattering of Piperidine;2. Using piperidine as catalyst and ethanol as solvent, a series of new 2-amino-3-cyano-4-aryl-6-methoxy-1,4,9,10-tetrahydronaphtho[2,1-b]pyran derivatives were synthesized by one-pot reaction of aromatic aldehydes, malononitrile and 7-methoxy-1,2,3,4-tetrahydronaphthalen-2-one at room temperature in good yields.

以芳醛、丙二腈和 7 甲氧基 1，2 ，3 ，4 四氢萘 2 酮为原料，在六氢吡啶催化下以乙醇为溶剂，在室温合成了一系列新的 2 氨基 3 氰基 4 芳基 6 甲氧基 1，4，9，10 四氢萘并 [2 ，1 b]吡喃衍生物，反应条件温和，产率较高，并通过IR ，1HNMR和元素分析表征产物的结构，还通过单晶X射线衍射分析确证产物的构

Asymmetric hydrogenation of quinoline derivatives is a hot topic in asymmetric hydrogenation. However, some problems still remained.

芳香杂环化合物喹啉衍生物的不对称氢化一直是不对称氢化领域的一个热点，然而对于苄基取代喹啉和一些多取代的喹啉衍生物至今没有实现有效的不对称氢化。

In this dissertation, Ir-catalyzed asymmetric hydrogenation, asymmetric transfer hydrogenation and asymmetric hydrosilylation of quinoline derivatives have been studied.

本论文研究了铱催化喹啉衍生物的不对称氢化、不对称转移氢化和不对称硅氢化反应。

The 2/SegPhos/I2 system can be applied in asymmetric hydrosilylation of quinoline and quinoxaline derivatives successfully, and up to 93% ee was obtained.

芳香杂环化合物喹啉衍生物的不对称硅氢化反应一直是不对称氢化领域的一个难点，我们利用2/-SegPhos/I2催化体系首次实现了杂芳香化合物：喹啉和喹喔啉的不对称硅氢化反应，最高获得了93%的ee值。

Hydrofining- hydrovisbreaking combined process has been adopted in the 5 000 b/d oil refining unit of Hangzhou Refinery and the hydrofining catalyst and hydrovisbreaking catalyst have been sectionally loaded in a single reactor to process inferior coker gasoline and gas oil.

杭州炼油厂 2 5 0kt/a油品精制装置采用加氢精制/临氢降凝组合工艺，在同一台反应器中分段装填精制和降凝催化剂，加工劣质汽油、柴油，操作弹性大，拓宽了柴油加氢精制的原料来源，大大提高了低凝柴油收率，且产品颜色浅、硫含量低、氧化安定性好。

The hydrogen storage properties of NaAlH4 doped by 3% TiZr alloy hydride with ball-milling method was investigated by X-ray diffractometry, scanning electron microscopy and sievert's technology test.

摘 要：采用机械球磨方法在NaAlH4 络合氢化物中添加3%TiZr合金氢化物，合成复合储氢材料。

Methods The antimony in urine reacted with sodium borohydride to generate gas molecules of stibine from which antimony atom was isolated under the flame heating. Atomic absorption spectrometer was applied to measure antimony content.

利用尿样中锑与硼氢化钠反应生成气态锑化氢分子，在火焰加热下，锑化氢分子解离出锑原子，用原子吸收光谱仪测定锑的含量。

Anaerobic synecology of the hydrogen-producing fermentation system was investigated under certain test condition in this thesis. In the continuous flow system of anaerobic hydrogen-producing fermentation, the succession of hydrogen-producing acidogenic microbiology may be regressive process. By regressive process we means that the original community getting from nature which structure being complex with a high ability would degenerate gently to a certain climax community which structure being simple with less ability.

产氢发酵系统的微生物群落生态学研究证明，在连续流发酵产氢反应系统中产氢产酸发酵细菌群落的演替过程，是在人为控制的生境条件下，微生物从自然群落这种稳定性大、组成及生化反应过程复杂的生态群落，向稳定性小、组成和生化反应过程相对简单的某一产酸发酵顶极群落进行的"逆行演替"。

The hydrogenation of terpineol to dihydroterpineol catalyzed by Raney Nickel modified by potassium borohydride was studied.

研究了以硼氢化钾修饰的雷尼镍催化剂催化松油醇加氢制备二氢松油醇的反应。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。