氟苯

First, the preparation of l,2-dichloro-4-nitrobenzene, which l-chloro-4-nitrobenzene reacted with chlorine in a self-designed chlorinator, in presence of Lewis acid catalyst,.was investigated. By means of the Orthogonal Experiments design and single factor experiments, the influence of several reaction variables on the yield were examined and the optimum reaction conditions under the intervallic operation were obtained, the yield of l,2-diehloro-4-nitrobenzene was 83.26%.

为此，本文首先在自行设计的塔式氯化器中，以对硝基氯苯为原料，路易氏酸作催化剂，分子氯氯化合成3，4-二氯硝基苯(合成3-氯-4-氟-硝基苯的原料)，根据该氯化过程特征，利用正交试验设计方法结合单因素实验考察了有关因素对氯化过程的影响，优化得到了最佳的氯化工艺条件，3，4—二氯硝基苯的收率可达83.26％。

All products are characterized with 1H-NMR. The products are used as PTC in the fluoridation of p-chloronitrobenzene, tetrachloroterephthaloyl chloride and N-benzyltetrachloridephthalimide to detect the performance of the different PTCs.

分别将上述化合物作为相转移催化剂应用于对硝基氯苯、四氯对苯二甲酰氯和N-苯基四氯邻苯二甲酰亚胺等化合物的氟化反应中，以检测各催化剂的催化性能。

The general formula of said soluble fluorine- containing aromatic medlin is as follows: the substituent group on side phenyl group in diamine monomer Ar includes methyl, trifluoromethyl, two trifluoromethyls or chlorine and trifluoromethyl.

可溶性含氟芳香聚酰亚胺具有如下通式：二胺单体Ar中苯侧基上取代基为甲基、三氟甲基、两个三氟甲基或者氯和三氟甲基。

After the use niter benzene even treatment and the treatment all around, separately makes the electroencephalogram inspection to two groups of case of illness.results: after the use niter benzene even treatment all around, the treatment group electroencephalogram restores quickly to the comparison group, exceptionally leads obviously to be lower than the comparison group.conclusions: the niter benzene is even is treats the recovery period fluorine acetamide to be poisoned patient's effective method, may enable his/her the brain harm to obtain the as soon as possible repair, improves the brain function, makes the unusual electroencephalogram to restore normal or the change for the better as soon as possible.

在使用硝苯地平治疗前和治疗4周后，分别对两组病例均作脑电图检查。结果：使用硝苯地平治疗4周后，治疗组脑电图恢复快于对照组，异常率明显低于对照组。结论：硝苯地平是治疗恢复期氟乙酰胺中毒患者的有效手段，可使其脑损害得到尽快修复，改善脑功能，使异常的脑电图尽早恢复正常或好转。

Mission:"equality and mutual benefit, reputation first, unity and cooperation and friendship between the long-term" supply products: ethylenediamine; diethylamide; triethylamine; Diethylenetriamine; three ethylene diamine; three ethylene amines 40; 40 Five ethylene amines; five ethylene amines 6; caprolactam; DMF; allyl amine; N, N dimethylaniline; propylamine; are butylamine; are TOA; 3 Poly Cyanamide; 1,2 c diamine; ethanolamine; diethanolamine, triethanolamine; potassium iodide, potassium hydroxide, potassium permanganate, toluene, xylene, toluene of chlorine ; Acetone, butanone; acetylacetone; ethyl acetate, butyl acetate; Y-butyrolactone; DMC; acetyl of methyl acetate; Sanfu acetyl acid; Sanfu acetyl B Ethyl; methanol, ethanol, isopropanol; propylene glycol; glycerol; propargyl alcohol; 1.3 propylene glycol; xylitol; acetic acid; have acid; mercaptoacetic acid; vary Bitterness; adipic acid; trifluoroacetic acid; oxalic acid, the amino acid; o-amygdalin acid; DL-Acid; anhydrous piperazine; six non-piperazine, furfural, castor oil, ethylene Aldehyde; glutaraldehyde, multi-POM; isopropyl ether; anisole; tetrahydropyrrole; pure pyridine; 1.2 dichloroethane; methylene chloride, chloroform, carbon tetrachloride; hydrazine hydrate; Nonylphenol;-m-cresol; Se phenol; phenol; the tert-butyl phenol; Titanium Dioxide; iron; full Tangfen; Bisphenol A; azo two different nitrile; sodium azide; sodium carbonate ; Sodium chloride; iron oxide; cuprous chloride; thionyl chloride; D4; sodium bicarbonate; ammonia, potassium chloride; anhydrous sodium sulphite; ammonium persulfate; glycol Dingmi; B Glycol ether; calcium chloride; cyclohexanone; cyclohexane, methyl tertiary butyl ether, potassium carbonate, ferric chloride, potassium nitrate; Linsuansanna; zinc oxide; sodium nitrite; antimony oxide; Tartrate; OP-10; TX-10; tablets base; AES; sodium benzoate, sodium citrate; partial sodium silicate, sodium perborate, a sodium carbonate, sodium benzene; Asia sodium chlorate; Wuluo Care products; urea; hydrochloric acid, sulfuric acid, lactic acid; amino acid, hydrogen peroxide, ammonium bicarbonate

公司宗旨："平等互利，信誉至上，团结合作，友谊长久"乙二胺；二乙胺；三乙胺；二乙烯三胺；三乙烯二胺；三乙烯四胺；四乙烯五胺；五乙烯六胺；己内酰胺；二甲基甲酰胺；烯丙基胺；N，N二甲基苯胺；正丙胺；正丁胺；正辛胺；三聚氰胺；1，2丙二胺；一乙醇胺；二乙醇胺；三乙醇胺；碘化钾；氢氧化钾；高锰酸钾；甲苯；二甲苯；对氯甲苯；丙酮；丁酮；乙酰丙酮；醋酸乙酯；醋酸丁酯；Y-丁内酯；碳酸二甲酯；乙酰乙酸甲酯；三伏乙酰乙酸；三伏乙酰乙酸乙酯；甲醇；无水乙醇；异丙醇；丙二醇；丙三醇；丙炔醇；1.3丙二醇；木糖醇；冰醋酸；己醛酸；巯基乙酸；异辛酸；己二酸；三氟乙酸；乙二酸；对氨基苯乙酸；邻氯苦杏仁酸；DL-扁桃酸；无水哌嗪；六无哌嗪；糠醛；蓖麻油；乙二醛；戊二醛；多聚甲醛；异丙醚；苯甲醚；四氢吡咯；纯吡啶；1.2二氯乙烷；二氯甲烷；三氯甲烷；四氯化碳；水合肼；壬基酚；纯间甲酚；硒酚；苯酚；对叔丁基苯酚；钛白粉；铁粉；全糖粉；双酚A；偶氮二异丁腈；叠氮化钠；碳酸钠；氯化钠；三氧化二铁；氯化亚铜；氯化亚砜；D4；碳酸氢钠；氨水；氯化钾；无水亚硫酸钠；过硫酸铵；乙二醇丁醚；乙二醇乙醚；氯化钙；环己酮；环己烷；甲基叔丁基醚；碳酸钾；三氯化铁；硝酸钾；磷酸三钠；氧化锌；亚硝酸钠；氧化锑；酒石酸；OP-10；TX-10；粒碱；AES；苯甲酸钠；柠檬酸钠；偏硅酸钠；过硼酸钠；过碳酸钠；苯磺酸钠；亚氯酸钠；乌洛托品；尿素；盐酸；硫酸；乳酸；氨基磺酸；双氧水；碳酸氢铵

Bifluoro nitrobenzene was the raw material of synthesis of asymmetry chromotropic acid bisazo fluoroarsen reagent, By way of ammonia substitution, arsonation, reduction and coupled reactions, bisazo fluoroarsen was synthesized.

以2，4—二氟硝基苯为起始原料，经过氨取代、胂酸化、还原、偶联反应合成了偶氮氟胂Ⅰ，然后分别选择不同的取代苯胺与偶氮氟胂Ⅰ偶联，合成了一系列的不对称变色酸偶氮氟胂。

Methyl-2,3,5,6-tetrafluoro-benzene methanol was synthesized by chlorination, acylation, fluorination, esterifica- tion, reduction, bromization, reduction from terephthalic acid. Tefluthrin was obtained from-(1RS,3RS)-3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl cycolpropa-necarboxylate acid by reacting with 4-methyl-2,3,5,6-tetrafluoro-benzene methanol.

以对苯二甲酸为原料，经氯化、酰氯化、氟化、酯化、还原、溴化、还原七步反应合成了4-甲基-2，3，5，6-四氟苄醇，甲基苄醇与-(1RS，3RS)-3-(2-氯-3，3，3-三氟丙-1-丙烯基)-2，2-二甲基环丙甲酸一步酯化合成了七氟菊酯。

The para-/ortho- product isomer ratio is 6.2 for the nitration of chlorobenzene at 18℃ for 8h with n/n(NH4NO3)=5. The para-/ortho- product isomer ratio is 14.0 for the nitration of bromobenzene at 0℃ for 8h with n/n(NH4NO3)=5. The pars-product, p-nitrobromobenzene, from the nitration of bromobenzene in [HSO4] under 0℃ precipitates with 98% purity, which facilitates the separation of the pure isomert.

其中氯苯在18℃下反应8h，三氟乙酸酐/硝酸铵为4时产物的对邻比达到6.2，而溴苯在0℃下反应8h，TFAA/硝酸铵为5时产物的对邻比可达到14.0，并且生成的对硝基溴苯可以从反应液中析出，得到对硝基溴苯含量为98%的产物。

The application results from fluorination showed microwave heating could accelerate chemical reactions markedly. The reaction time could be shortened 50% at least than that of conventional heating. The relationship between fluorinating agents\' structure and their activity was studied systematically. In addition, an anhydrous KF with higher activity was prepared by using expansion effect of microwave heating. As we known, solvents were very important to reaction. The comprehensive study showed some less polar aromatic solvents could be used as dipolar solvents. In addition, they had better effect than dipolar solvents in some occasions, such as fluorination of chlorobenzaldehydes and chlorinated diphenyl ketones etc. The primary applications of ionic liquids were also studied which indicated reactions with ionic liquids as solvents were more efficient and simple.

研究表明，微波是一种节能高效的加热方式，在微波作用下的卤素交换氟化反应具有反应速度快、转化率高、选择性好的优点，其反应时间可较常规加热缩短50%以上；同时也系统地研究了氟化剂种类及制备方式对其反应活性的影响，并利用微波加热的膨化作用制备出了一种活性较高的KF，其活性与喷雾干燥KF相差不大；溶剂对反应具有重要的作用，在此系统地研究了强极性非质子溶剂和中等极性非质子溶剂的应用情况，发现一些中等极性的非质子溶剂如硝基芳烃和氯代芳烃类溶剂在氯代苯甲醛类化合物的氟化反应中具有比强极性非质子溶剂更好的使用效果。

M Trifluoromethylacetophenone was synthesized by the reaction of acetic anhydride with the Grignard reagent of 3 bromo benzene prepared from trifluoromethylbenzene , in 40% overall yield.

以三氟甲基苯为原料，经过溴化、格氏反应后与乙酸酐反应合成间三氟甲基苯乙酮，总收率40%。

The labia have now been sutured together almost completely.The drains and the Foley catheter come out at the top.

此刻阴唇已经几乎完全的缝在一起了，排除多余淤血体液的管子和Foley导管从顶端冒出来。

To get the business done, I suggest we split the difference in price.

为了做成这笔生意，我建议我们在价格上大家各让一半。