氟化的

The influence of each condition on the reaction speed and yield was studied, and the optimal conditions were: the ratio of the amount of substance of aromatic amine and heptafluoro-isopropyl iodine was 1:1.1~1.5, the amount of substance of sodium dithionite, sodium bicarbonate, aniline compounds were respectively 1.1~1.3, the amount of substance of phase transfer catalyst TBAB and aniline compounds was 0.05~0.1, the concentration of aniline compound was 0.5~1.0 mol/L, reaction temperature was 10~20 ℃, and the solvent was aether.

最佳结果为：芳胺与七氟异丙基碘的物质的量比1：1.1~1.5，连二亚硫酸钠、碳酸氢钠与苯胺的物质的量分别为1.1~1.3，相转移催化剂四丁基溴化铵与苯胺的物质的量比在0.05~0.1，溶剂总用量使苯胺浓度在0.5~1.0 mol/L；反应温度10~20℃；溶剂采用乙醚。取代基供电子性越强，反应时间越短，产率越高；氨基的对位优先反应，氨基的邻位较难发生反应；且七氟异丙基总是优先取代在芳环电子云密度较高的位置上。

Fluorin boric acid acidification system's acid liquid delay corrode,matching,delay velocity capability,sullage test,iron ion stabilization test,depend expanding capability was evaluated through static state and rock core acidification dynamic test.

对石南油田选用的氟硼酸酸化体系从酸液缓蚀性能、配伍性能、缓速性能、残渣试验、铁离子稳定试验、防膨性能等方面进行了较全面的室内静态评价和岩芯酸化动态评价。

Element analysis shows that Si exists on the surface of hybrid membrane when TEOS content is not too low. The effects of TEOS content on the performance of hybrid membranes were investigated.

实验初步考察了正硅酸乙酯的添加量对聚偏氟乙烯－硅杂化膜的超滤性能和力学性能的影响，对杂化膜进行了能谱分析。

Poly with sulfonic acid groups were readily synthesized with biphenol and 1,3-bis(4-fluorobenzoyl)benzene in the presence of excess potassium carbonate followed by sulfonation with chlorosulfonic acid.

以二氯二苯甲烷和2，6-二甲基苯酚为原料合成了含有阻碍基团的双酚单体，用此双酚单体和1，3-二(4-氟苯甲酰基苯)在无水碳酸钾存在的条件下反应制得聚芳醚酮，然后用氯磺酸磺化，控制反应条件，使磺酸基团恰好进入苯环对位，制得新型结构的磺化聚芳醚酮。

Objective The aim of this study was to investigate the effect of enamel remineralization with application of calcifying solution, fluoride solution and fluoride foam.

目的 本研究对矿化液、低浓度氟化物溶液和氟泡沫再矿化作用进行了比较，从而寻找出一种再矿化效果较好的制剂。

CPP-ACP has the ability of promoting remineralization of enamel artificial white spot lesions which can be enhanced by fluorid.The remineralization ability depends on the concentration of calcium phosphate stabilized by CPP-ACP.

CPP-ACP溶液可于体外使脱矿牙釉质发生再矿化，且矿化作用可被氟加强；再矿化作用与CPP稳定的钙磷浓度呈剂量-效应关系。

This Ph.D. thesis describes further studies on theformation of fluorinated phosphorus ylide-anions resultingfrom organometallics and their reactions, stereochemistry andapplications in organic synthesis. We found that inverse stereochemical results wereobserved in the reaction of the fluorinated ylide-anions withvarious proton donors.

本博士论文进一步研究了用有机金属试剂对含氟膦叶立德的亲核加成导致的叶立德阴离子的反应性、立体选择性及其在有机合成中的应用：首次发现含氟叶立德阴离子在与不同的质子化试剂作用时，反应呈现完全相反的立体化学结果。

We have synthesized 4,4'-dinitro-3 4''-dimethyl triphenylamine,(1), in 84% yield in an one-step condensation process between 3,4-dimethyl aniline and 4-fluoro-nitrobenzene. After the auto-oxidation of (1) and the subsequent hydrogenation of the nitro-groups, an AB2 type triphenylamine polyimide intermediate bearing two amine groups and one acid-anhydride group each on individual phenyl ring,{AB2 PI Intermediate}, was prepared successfully. The yields of the autoxidation and the hydrogenation steps are 81% and 90% respectively.

中文摘要本研究以3，4-二甲苯胺及4-氟硝基苯为原料，经一步骤缩合反应得到产率为84 %之4，4'-二硝基-3&，4&-二甲基三苯胺(1)，由(1)经自氧化法后再以氢化法还原硝基，成功地制备出带有二胺基与一羧基的三官能基之AB2型三苯胺中间体(AB2型PI中间体)，自氧化反应与氢化法的产率各为81%及90%。

Treatment of the diacetoxy-calix [4] arene with a series of ditosylates in dry MeCN in the presence of NaOH resulted in formation of electron-rich calix [4] areneocrowns, which reacted with 4, 4'-bipyrindinium and p-bis -benzene at room temperature in dry MeCN to afford self-assembling [2] catenanes by π-π stacking interaction.

以杯[4]芳烃为原料，通过三氟乙酸铊将其氧化成醌，醌类化合物在Zn粉、冰醋酸、少量盐酸和过量的乙酸酐中反应得到双乙酰化产物，利用氢氧化钠使其水解，然后再与各种对甲苯磺酸二酯进行环化反应，得到一系列具有富电子空腔的杯[4]芳烃并冠醚。

We investigated fluoroalkylation of 5,10,15-triarylporphyrins with fluoroalkyl halides by sulfinatodehalogenation system.

本章研究了在亚磺化脱卤反应条件下5，10，15-三芳基卟啉的氟烷基化反应，并对反应条件进行了优化。

Lugalbanda was a god and shepherd king of Uruk where he was worshipped for over a thousand years.

Lugalbanda 是神和被崇拜了一千年多 Uruk古埃及喜克索王朝国王。

I am coming just now,' and went on perfuming himself with Hunut, then he came and sat.

我来只是现在，'歼灭战perfuming自己与胡努特，那麼，他来到和SAT 。