氟化的

Based on this model, the structures, dipole moments and the nuclear magnetic resonance parameters were calculated for a series of functionalized nanotubes, including nitrene and carbene modification, as well as 1,2- and 1,4-fluorination.

本文采用C80H20模型来表示(10，0)碳纳米管，基于此模型计算了一系列氮烯、卡宾和氟化的单壁纳米管的结构、偶极矩，以及核磁共振参数。

The results indicated that the high level density functional theory calculations can be used to predict the 13C chemical shifts of the modified nanotubes. The calculated results also provided the characteristic chemical shifts values of nitrene (superscript -), carbene (superscript -) and 1,2- and 1, 4-fluorinated nanotubes, which would be helpful for experimental spectrogram assignments. Combined with NMR experiments, these predicted characteristic chemical shifts can be further used to monitor the addition mechanism and the extent of surface modifications on nanotubes.

研究表明高精度的密度泛函理论计算能够用来预测纳米管的13C化学位移，理论研究的结果揭示了氮烯、卡宾以及1，2和1，4氟化的单壁纳米管的若干13C信号特征化学位移值，为实验NMR谱图的归属提供了一定的依据，并且可通过与实验相结合来监测表面官能化碳纳米管加成反应是否发生以及确认其加成方式。

Results show that the best value of w is 7~10% and 5~7%, i is 0.08~0.2 A/cm^2 and 0.03~0.05 A/cm^2 respectively, during the electrolysis fluorination of pyridine and tributylamine; the addition of N-butyl mercaptan into the organic mixture can stabilize electrolysis process with its mass fraction 15~20% at best; impulse current polarization work status of low load is helpful to the electrolysis process and reduces corrosion rate of anode; electrolysis temperature is suitable at 0~20℃; electrobath can use electrolyte inner circulation structure, exterior circulation structure or blending structure.

结果表明：吡啶和N-三丁胺电解氟化的最佳值w分别为7%~10%和5%~7%，i分别为0.08~0.2A/平方公分和0.03~0.05A/平方公分；有机混合物中添加N-丁基硫醇可稳定电解过程，其质量分数最佳为15%~20%；采用低负荷的脉冲电流极化工况有利电解过程，降低阳极的腐蚀速度；电解温度0~20℃为宜；电解槽可采用电解液内循环、外循环结构，或其混合结构。

The reaction mechanism and the latest research status of displacement fluorination of aromatics are summarized, and the development trends are forecasted also.

摘要综述了芳香族置换氟化的反应机理与最新研究状况，并展望了其未来发展前景。

A clean production technology for fluorine and silica white is introduced, with fluorine-containing gas raw material directly absorbed by ammonium fluoride, or ammonia to obtain ammonium fluorosilicate ,and to get ammonium fluoride and silica white by ammonization, further to manufacture other fluoride product with high value.

介绍一种利用磷肥生产中的含氟废气生产氟化合物与白炭黑的清洁生产方法：用氟化铵或氨直接吸收含氟气体生成氟硅酸铵，然后氨化得氟化铵与白炭黑(SiO2)，氟化铵可进一步加工为其它高价值氟化物产品。

The main products are inorganic fluoride, with the integrated capacity of 150 thousand tons per year, our main products are: synthetic cryolite, aluminium fluoride, sodium fluoride, silica white, hydrofluoride, potassium fluoroborate, potassium fluotitanate, potassium aluminium fluoride, magnesium fluoride, barium fluoride, lithium fluoride ,potassium fluoride, magnesium fluorosilicate, potassium fluorosilicate, potassium fluorosilicate etc.

多氟多公司生产区多氟多化工股份有限公司，公司注册资本8000万元，为河南省高新技术企业，是中国最大的无机氟化盐生产基地之一。综合产能15万吨/年，主要产品有冰晶石、氟化铝氟化钠、白炭黑、氢氟酸、氟硼酸钾、氟钛酸钾、氟铝酸钾、氟化镁、氟化钡、氟锆酸钾、氟化氢铵、氟化铵、氟化钾、氟化锂、氟硅酸钠、氟硅酸钾、氟硅酸镁等。

The result indicated that: the amount of the excess HF formed direct ratio to the yield of phosphorus pentafluoride and the optimum amount of the excess HF used is about 35%; the trickling rate of oleum shouldnt make the temperature of hexafluorophosphoric acid exceed 25 ℃ and the amount of oleum is 110% to 125% that of stoichiometry so that the content of phosphorus pentafluoride can be achieved 90%; the time and temperature of heating hexafluorophosphoric acid influenced both the yield and the content of phosphorus pentafluoride, and the optimum time should be about 30 minutes and the proper temperature was 148 to 153℃; when alcohol used asrefrigerant, the content of phosphorus pentafluoride was 94.03%, and the content can be up to 97.38%, provided that using liquid nitrogen as refrigerant.

通过实验发现，氟化氢用量与五氟化磷的产率成正比，最佳过量百分率宜在35％左右；发烟硫酸的滴加速度不能使中间产物温度大于25℃，发烟硫酸用量大于理论量10％～25％时，得到的五氟化磷纯度高于90％；六氟磷酸的加热温度对五氟化磷的产率和纯度均有影响，宜在148～153℃的范围内，加热时间应在30分钟左右；用工业酒精做冷凝介质得到的五氟化磷纯度最高只能到达94.03％，使用液氮做冷凝介质可以使五氟化磷的纯度达97.38％以上。

The process of the present invention consists in bringing into contact, on the one hand, gaseous phosphorus pentafluoride or a gaseous mixture comprising phosphorus pentafluoride and hydrochloric acid, and, on the other hand, a solution of lithium fluoride in hydrofluoric acid, in a column (10) having a sufficient number of transfer units to carry out the reaction of PF5 with LiF under the chosen conditions of temperature, of pressure and of molar ratio of the two contrasting reactants and with complete or substantially complete absorption of the PF5 in the column.

本发明方法是让气态五氟化磷或五氟化磷与盐酸的气态混合物与氟化锂的氟氢酸溶液在塔（10）中接触，该塔转化单元数足以在选定温度、压力与两种反应剂摩尔比条件下使PF5与LiF反应，塔中五氟化磷完全或基本完全被吸收。

Methods A set of demineralized bovine teeth specimens we re measured for microhardness to assess the degree of remineralization,and other two sets of bovine teeth specimens were examined with polarizing microscope to assess the anti-demineralization and anti-caries effect.

利用显微硬度计测定氟化牛奶和氟水对早期人工龋的再矿化作用。利用偏光显微镜观察氟化牛奶和氟水的抗酸脱矿作用及抗龋作用。

This paper, aimed at the problem of drying aluminum fluoride trihydrate, studied the most possible binding format of crystal water, and hereby deduced the process of crystal water dehydration.

本论文针对三水氟化铝的干燥脱水问题，应用晶体结构理论、价键理论以及各种相关化学原理推测了三水氟化铝可能的结晶水结合形式，并据此推断了其结晶水的脱除过程：对氟化铝干燥特性进行了实验研究，研究了温度和升温速率对氟化铝干燥效果的影响：采用非等温TG-DTG法，对三水氟化铝进行了热分解行为和热分解动力学分析，进一步验证了三水氟化铝的脱水过程，并得出了其脱水和水解过程的动力学参数及方程。

Lugalbanda was a god and shepherd king of Uruk where he was worshipped for over a thousand years.

Lugalbanda 是神和被崇拜了一千年多 Uruk古埃及喜克索王朝国王。

I am coming just now,' and went on perfuming himself with Hunut, then he came and sat.

我来只是现在，'歼灭战perfuming自己与胡努特，那麼，他来到和SAT 。