氟化氧

Nucleophilic opening of the terminalepoxide 57 by a lithium acetylide from 27 in the presence of BF3·EtO furnishedcompound 58, which had the skeleton of target molecule, subsequent conversionsinvolved the introduction of γlactone gave Annonacin.

然后以三氟化硼参与的炔负离子开环氧反应建立分子骨架，得到化合物58。随后经氢化，引入α，β不饱和丁内酯环、去保护等几步反应，就得到Annonacin。

In this research, we used a sol-gel process to prepare UV-curable antiglare coatings. First the inorganic monomer tetraethoxylsilane was formed into colloidal silica by hydrolysis and condensation reactions. Then, added the couple agent 3- propyl methacrylate and surfactant fluoroalkylsilane (13F) to modify the colloidal silica. Finally, organic monomer dipentaerythritol hexaacrylate were added to form hybrid material.

中文摘要本研究是经由溶胶凝胶制程，将无机单体四乙氧基矽烷先行水解、缩合反应成为二氧化矽，接著分别加入偶合剂三异丙基矽基丙烯酸酯、氟化矽氧烷(13F)、对二氧化矽微粒进行表面改质；之后再导入交联剂DPHA加以强化合成出奈米混成涂料。

The 3-chloro-4-trifluoromethoxy benzonitrile was synthesized from 3-chloro-4-trifluorome- thoxy aniline by diazotization, formaldoximation ,hydrolysis and cyanation.

以3-氯-4-三氟甲氧基苯胺为原料，经重氮化、甲醛肟化、水解和腈化反应得到纯度≥99。

The crosslinked PEG-20M glass capillary column was prepared by dynamic coating method with boron trifluoride as catalyst,3-glvcidyl-oxypropyl-trimethoxysilane as crosslinking agent.

以PEG－20M为固定相，三氟化硼为催化剂，3－缩甘油氧丙基三甲氧基硅烷（简称KH－560）为交联剂，二氯甲烷为溶剂，对预先用氯化钠沉积法粗糙化的玻璃毛细管柱进行动态涂渍。

Nitratomethyl-3-ethyloxetane was synthesized by the process of cyclization, nitation from trimethlolpropane and diethyl carbonate, and the homopolymer of 3-nitratomethyl-3-ethyloxetane was synthesized with 1,4-butanediol as initator and boron trifluoride etherate as an catalyst by cationic ring-opening polymerization.

以三羟-甲基丙烷和碳酸二乙酯为原料经环化、硝化两步反应合成了化合物3-硝酸酯甲基－3-乙基氧丁环；采用1，4-丁二醇为引发剂，三氟化硼乙醚(BF3Et2O)为催化剂，NIMEO发生阳离子开环聚合得到一种端羟硝酸酯均聚醚PNIMEO。

Using butanediol as initiator, boron-trifluoride etherate as catalyst, 3-azidomethyl-3-methyloxetane homopolymer was synthesized by the cationic polymerization of 3-azidomethyl-3-methyloxetane which was carried out in dichlorometane.

以1，4-丁二醇为引发剂，以三氟化硼乙醚络合物为催化剂，以3-叠氮甲基－3-甲基氧丁环为单体，以CH2Cl2为溶剂，按阳离子开环聚合机理，合成了含能粘合剂3-叠氮甲基－3-甲基氧丁环均聚物。

Using pentaerythritol as initiator, boron trifluoride diethyl etherate as catalyst.dichloroethane as dispersion agent, the chloride polyether polyol is synthesized based on the mechanism of cationic ring-opening polymerization of epiclilnrohyclrin.The azide polyether polyol is synthesized, in DMF through A and sodium azide, and the non-reported azide energetic curing agent is synthesized through the adduction of B and IIDI.

以季戊四醇为起始剂，三氟化硼乙醚为催化剂，1，2—二氯乙烷为分散剂，环氧氯丙烷经阳离子开环聚合反应制成氯化聚醚多元醇，A在N，N—二甲基甲酰胺中与叠氮化钠反应制得叠氮聚醚多元醇，B与六亚甲基二异氰酸酯加成反应制得未见文献报道的叠氮固化剂。

Water samples were extracted and purified and collected by solid-phase extraction LC-18 column. Soil samples were extracted by ethyl acetate/petroleum ether (2:1, by vol) and purified by sulphonation. Wheat sample was extracted by acetonitrile/water (4:1, by vol) and purified and collected by SPE- Florisil column.

水样直接用LC-18固相萃取小柱分离、净化和富集；采用乙酸乙酯／石油醚（体积比2：1）振荡提取，磺化法净化，测定土壤中氯氟吡氧乙酸残留量；以乙腈／水（体积比4：1）为提取剂，氟罗里硅土固相萃取小柱分离、净化，测定小麦样品中氯氟吡氧乙酸的残留量。

It reacts violently with oxygen difluoride and barium peroxide.

一氧化碳同氟化氧、氧化钡会发生剧烈反应。

Optimum conditions are as follows: DMF is used as solvent, compound quaternary ammonium salt as catalyst, n(p-nitrochloro benzene):n=1: 1.2, m:m(p-nitrochloro benzene)=4%, m:m(p-nitrochloro benzene)1:1, and reacted under 155~160℃ for 18 h; reduction reaction is carried out in methanol with Raney nickel, which is used as catalyst; the raw product is added an antioxidant, and distilled simply under reduced pressure to obtain 4-fluoroaniline with excellence quality, purity is over 99.5%, total yield is 89.3%.

实验结果表明，氟化反应的最佳条件为：二甲基甲酰胺为溶剂、复合季铵盐为催化剂，n：n=1：1.2，m（催化剂：m=4%，m：m=1：1，于155~160℃下反应18h；还原反应在甲醇中进行，以阮内镍为催化剂；粗产品加入抗氧剂，减压条件下简单蒸馏得高品位的对氟苯胺。

The labia have now been sutured together almost completely.The drains and the Foley catheter come out at the top.

此刻阴唇已经几乎完全的缝在一起了，排除多余淤血体液的管子和Foley导管从顶端冒出来。

To get the business done, I suggest we split the difference in price.

为了做成这笔生意，我建议我们在价格上大家各让一半。