氟化

The 3-chloro-4-trifluoromethoxy benzonitrile was synthesized from 3-chloro-4-trifluorome- thoxy aniline by diazotization, formaldoximation ,hydrolysis and cyanation.

以3-氯-4-三氟甲氧基苯胺为原料，经重氮化、甲醛肟化、水解和腈化反应得到纯度≥99。

Both CaCN2 and urea inhibited the chlamydospore germination, mycelial growth and sporulation of the pathogen, but CaCN2 by using at the rates of 0.5 and 1.0%, had two inhibition zones for chlamydospore germination with time while urea had only one. Calcium cyanamide was also more effective on reducing mycelial growth and sporulation of the pathogen than urea did. Therefore, the suppression of pea wilt might be due to fungicidal effect of the intermediate products including hydrogen cyanamide and urea from calcium cyanamide.

由氰氮化钙（0.5及1.0%处理者）之抑制曲线在不同的时间出现两个抑制区，而尿素则仅有一个，及氰氮化钙对萎凋病菌菌丝生长及产胞的影响远较尿素为甚，显示氰氮化钙之所以能有效抑制萎凋病的主要因子，或许是来自其中间产物，包括尿素及氟酸的杀菌作用。

For developing an immunoassay for multiple residues of pyrethroid pesticides, the hapten N-2- carbanmoyl-(3"-phenoxyphenyl) methyl 3-(2"-Cldoro-3",3",3"-trifluoropropenyl)-2, 2-dimethylcyclopropane- carboxylate was synthesized from cyanohydrin and 3-(2"-Chloro-3",3",3- trifluoropropenyl)-2, 2-dimethylcyclopropanecarboxylic acid via hydrolysis and esterification. The synthesis of the hapten was foundation of preparaing anti- cyhalothrin polyclonal antibodies.

为了制备对单一拟除虫菊酯高特异性的抗体，以菊酸和氰醇为起始原料，通过水解、酯化反应合成了半抗原N-2-氨甲酰-(3-苯氧基苄基)甲基-3-(2-氯-3，3，3-三氟丙烯基)-2，2-二甲基环丙烷羧酸酯，为进一步制备抗三氟氰菊酯的特异性抗体奠定基础。

The influence of each condition on the reaction speed and yield was studied, and the optimal conditions were: the ratio of the amount of substance of aromatic amine and heptafluoro-isopropyl iodine was 1:1.1~1.5, the amount of substance of sodium dithionite, sodium bicarbonate, aniline compounds were respectively 1.1~1.3, the amount of substance of phase transfer catalyst TBAB and aniline compounds was 0.05~0.1, the concentration of aniline compound was 0.5~1.0 mol/L, reaction temperature was 10~20 ℃, and the solvent was aether.

最佳结果为：芳胺与七氟异丙基碘的物质的量比1：1.1~1.5，连二亚硫酸钠、碳酸氢钠与苯胺的物质的量分别为1.1~1.3，相转移催化剂四丁基溴化铵与苯胺的物质的量比在0.05~0.1，溶剂总用量使苯胺浓度在0.5~1.0 mol/L；反应温度10~20℃；溶剂采用乙醚。取代基供电子性越强，反应时间越短，产率越高；氨基的对位优先反应，氨基的邻位较难发生反应；且七氟异丙基总是优先取代在芳环电子云密度较高的位置上。

To evaluate the bioactivity of the glass-ceramics,the specimens were soaked in the simulated body fluid. The results indicate that fluorapatite shows needle-like microstructure, which is similar to that in human bone and teeth. The formation of needle-like fluorapatite is related to the heat treatment procedure, which results in needle-like fluorapatite crystals by accelerating one-dimension growth along the c-axis through the screw dislocation growth mechanism. The mechanical properties of the glass-ceramics are close to those of the human bone and teeth. The bioactivity test results show that apatite layer is precipitated on the materials surface after 3 d immersion in SBF, which indicates the glass-ceramics have a good bioactivity.

研究结果表明：氟磷灰石相呈针状，与人体骨和牙齿的磷灰石形貌相似，有利于提高材料的生物活性和生物相容性；氟磷灰石的形成是材料被迅速加热至高温进行热处理，使磷灰石以螺旋位错生长机制沿c轴晶化长大所致；经热处理获得的材料具有优良的力学性能，基本满足骨科和齿科用生物材料的性能要求；材料在体外模拟体液中浸泡3 d后，样品表面已有磷灰石层生成，表明该材料具有较高的生物活性。

Large single crystals were also obtained by using pyrocatechol as additive. It was shown by 〓Si-NMR and IR that Sipyrocatechol complex was formed in the reaction system.

在F〓体系中，F〓对铝源和硅源起络合和矿化作用，形成可溶性氟硅酸盐AlF〓〓、SiF〓〓络合物，然后缓慢水解成含氧氟硅酸盐络合物，它们再发生定向缩聚，提供了分子筛晶体生长所需的可溶性结构单元。

This invention is directed to the-tartaric acid salt of 2-amino-N-{1-(2,4-difluoro-benzyloxymethyl)-2-oxo-2-3-oxo-3a-pyridin-2-ylmethyl-2-(2,2,2-trifluoroethyl-2,3,3a, 4,6,7-hexahydro-pyrazolo(4,3-c) pyridin-5-yl-ethyl}-2-methyl-propionamide which is a growth hormone secretagogue and as such is useful for increasing the level of endogenous growth hormone.

本发明涉及2－氨基－N－{1－－(2，4－二氟－卞氧甲基)－2－氧代－2－3－氧代－3a－(R－吡啶－2－基甲基－2－(2，2，2－三氟－乙基)－2，3，3a，4，6，7－六氢化－吡唑子基(4，3－c)吡啶－5－基－乙基}－2－甲基－丙酰胺的－－酒石酸盐，它是一种生长激素促分泌素，并且可用于提高内源性生长激素水平。

The initial interaction modes of pyreno[2,1-b]pyrrole and its dimeric derivative with F in MeCN can be understood as hydrogen-bonded complexes. Excess F ions promotes deprotonation of N-protons and results in the bathochromic changes in both absorption and fluorescence spectra.

实验过程中发现，在初始模式中，芘骈吡咯及双芘骈吡咯与氟离子形成氢键附合物；之后加入的氟离子，因其带有极强的碱性，将促使吡咯官能基中氮上氢进行去质子化，而造成吸收及萤光光谱的红位移现象。

Sulfonated poly are prepared by direct polymerization of biphenol A, disodium 4, 4"-difluoro-3, 3"-disulfonate-1, 1-diphenylketone and 2, 6-difluorobezonitrile. The polymers are characterized with ~1H-NMR, FT-IR.

以双酚A，2，6-二氟苯腈和4，4′-二氟-3，3′-二磺酸钠-1，1′-二苯酮采用直接缩合法合成了不同磺化度的磺酸型聚芳醚腈酮，通过FT-IR和~1H-NMR对聚合物进行了表征，证明其结构正确。

Sulfonated poly are prepared by direct polymerization of biphenol A, disodium 4, 4"-difluoro-3, 3"-disulfonate-1, 1-diphenylsulfone and 1, 3-(4-difluorophenyl)benzene. The polymers are characterized with ~1H-NMR, FT-IR.

以双酚A，1，3-二(4-氟苯基)苯和4，4′-二氟-3，3′-二磺酸钠-1，1′-二苯砜采用直接缩合法合成了不同磺化度的磺酸型聚芳醚酮砜，通过FT-IR和~1H-NMR对聚合物进行了表征，证明其结构正确。

Lugalbanda was a god and shepherd king of Uruk where he was worshipped for over a thousand years.

Lugalbanda 是神和被崇拜了一千年多 Uruk古埃及喜克索王朝国王。

I am coming just now,' and went on perfuming himself with Hunut, then he came and sat.

我来只是现在，'歼灭战perfuming自己与胡努特，那麼，他来到和SAT 。