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The longer fluorinatd alkyl chain on the three-ring was advantageous to the formation of smectic phase. The mesogens with chiral center located between fluorinated tail and mesogenic core exhibited chiral smectic C phase and other smectic phases when the alkoxyl adhering to the other side of the mesogenic core was of intermediate length.

三环系液晶化合物中较长的烷基边链有利于近晶相的形成,且当液晶核另一端的烷氧基链的长度适中时,在烷基边链和液晶核之间具有手性中心的液晶分子显示了手性近晶C相和其它液晶相。

In this study, EPMA and LA-ICP-MS were used to determine the major and trace element concentrations, respectively, of apatites from Transhimalayan granitoids. The results indicate that F, Mn, Sr and REEs in apatites generally show good correlations with compositions of their host magmas and thus have high potential to be utilized as petrogenetic tracers. More specifically, F and Mn contents in apatites are covariant with the aluminosity of the host rocks so that can be used as an indicator for magma differentiation. Combining with Sr and REE data, which show significant variations in apatites from different rock types, these elements may be furthermore used to construct "discrimination diagrams" for more detailed investigations of complex petrogenetic processes such as magma mixing and compositional heterogeneity.

本研究中,电子微探以及雷射烧蚀感应耦合电浆质谱术分别被用以量测藏南火成岩中磷灰石的主量与微量元素含量,微区分析的结果显示,磷灰石的、锰、锶以及稀土元素均与岩浆源成分展现良好的对比关系,揭示了它们应用在岩石成因示踪上的优秀潜力:其中,磷灰石、锰含量的变化与原岩的铝饱和情形息息相关,因此可以作为岩浆分异程度的指标;而锶以及稀土元素则在不同岩石类型来源的磷灰石中展现了明显的丰度变化,因此综合这些元素将有机会进一步建立岩浆来源的「鉴别图」,甚而以此讨论岩石成因,例如:岩浆混合与源区组成的不均一性。

Domestic products raw material, which bastnasite was used as active component for DeSOx additives, were selected to use for the first time, the bastnasite can replace industrial cerium nitrate, it may improve DeSOx activity and abrasive resistance, due to admission bastnasite, but also reduce cost of material of DeSOx additives.

本文采用三种方法拟在活性组分的选择、活性评价及作用机理等方面对DeSOx添加剂强度进行有益的探索;尤其首次选用国产原料——碳铈矿作为镁铝尖晶石DeSOx添加剂的活性载体,使得炭铈矿可以代替工业硝酸铈,它既可提高脱硫添加剂的活性和耐磨强度,还可以降低原料成本。

The initial interaction modes of pyreno[2,1-b]pyrrole and its dimeric derivative with F in MeCN can be understood as hydrogen-bonded complexes. Excess F ions promotes deprotonation of N-protons and results in the bathochromic changes in both absorption and fluorescence spectra.

实验过程中发现,在初始模式中,芘骈吡咯及双芘骈吡咯与离子形成氢键附合物;之后加入的离子,因其带有极强的碱性,将促使吡咯官能基中氮上氢进行去质子化,而造成吸收及萤光光谱的红位移现象。

Based on broad information collection, author compared and studied on the old synthesis process, and proposed the better process that started from benzyl chloride, then according to the sequence of " synthesis of benzylamine, synthesis of N-benzyl-N--acetamine, synthesis of 2-chloro-5-methylpridine ,2-chloro-5-trichloromethylpyridine,2-chloro-5-trifluropyridine " five steps to get the final product, CTFP.

本文在查阅大量文献资料和对2-氯-5-三甲基吡啶合成路线进行分析比较的基础上,提出了较佳合成路线,即以氯化苄为原料,合成的反应步骤为&苄胺&合成、&N-苄基-N--乙酰胺&合成、&2-氯-5-甲基吡啶&合成、&2-氯-5-三氯甲基吡啶&合成、&2-氯-5-三甲基吡啶&合成五步。

Trifluoromethanesulfonic acid was found to be able to efficiently activate the benzylic sp3 C—F bond.

甲磺酸被发现能够高效地活化(SP3)碳-键。

The main pathogenic bacteria of each area is dissimilar, most of which were hyper sensitive to Ciprofloxacin, Levofloxacin, Ofloxacin, Cefazolin, but were completely not sensitive to Benzylpenicillin, Erythromycin and Vancomycin.

各个地区优势菌群存在差异,药敏试验结果也不相同,分离出的细菌绝大部分对环丙沙星、左沙星、氧沙星和先锋霉素V高度敏感,但对青霉素、红霉素和万古霉素有较强耐药性。

Fluorous biphase system formed by organic solvents and perfluorous nonene or perfluorous hexane and toluene nitration were investigated.

研究了溶剂和有机溶剂组成的两相体系、等当量的甲苯和硝酸的硝化反应。

A series of crosslinked sulfonated polys were synthesized from 4,4'-difluorodiphenyl sulfone, 4,4'-biphenol, 3,3'-disulfonate-4,4'-difluorodiphenyl sulfone and 1,3,5-trihydroxy benzene by nucleophilic substitution polycondensation reactions. The trifunctional crosslinker of THB was in the mass fraction range of 3%-7%.

以4,4'-二二苯砜、4,4'-联苯二酚、3,3'-二磺化-4,4'-二二苯砜二钠盐和三羟基苯为原料,经高温溶液缩聚反应,制备了一系列不同磺化度的新型交联磺化聚芳醚砜。

Sulfonated poly are prepared by direct polymerization of biphenol A, disodium 4, 4"-difluoro-3, 3"-disulfonate-1, 1-diphenylketone and 2, 6-difluorobezonitrile. The polymers are characterized with ~1H-NMR, FT-IR.

以双酚A,2,6-二苯腈和4,4′-二-3,3′-二磺酸钠-1,1′-二苯酮采用直接缩合法合成了不同磺化度的磺酸型聚芳醚腈酮,通过FT-IR和~1H-NMR对聚合物进行了表征,证明其结构正确。

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此刻阴唇已经几乎完全的缝在一起了,排除多余淤血体液的管子和Foley导管从顶端冒出来。

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