氟

Teflubenzuron was synthesized from 2,4-difluoronitrobenzene and 2,6-dichlobenil as starting reagent through six-step reaction with the yield of 75.3%.3,5-Dichloro-2,4-difluoroaniline was synthesized by chlorination,reduction reaction from 2,4-difluoronitrobenzene,the yield was 84.5%;2,6-difluorobenzamide with the yield of 87.7% was synthesized by fluoridation and hydrolysis from 2,6-dichlobenil.

以2，4-二氟硝基苯和2，6-二氯苯腈为起始原料，经过6步反应合成伏虫隆，总收率为75.3%。以2，4-二氟硝基苯为原料，经过氯化、还原反应合成3，5-二氯-2，4-二氟苯胺，产率为84.5%；以2，6-二氯苯腈为原料，经过氟化和水解，制得2，6-二氟苯甲酰胺，产率为87.7%；将Ⅱ与二碳酸酯酰化，合成2，6-二氟苯甲酰异氰酸酯，产率为91.3%；Ⅲ与Ⅰ加成，得到杀虫剂伏虫隆，产率为95%。

Currently,made up of 8 companies and 3 R %26amp; D institutes, Dongyue group has formed powerful industry fundaments and R %26amp; D platform and created hi-tech industrial chain and product group from fluorspar mining to AHF the base material of fluorchemical industry, from chloride methane to environment friendly protection refrigerants, and to fluoropolymer and post-treated products, up to top tech product HFP, VDF, TFE,PFSA and ion membrane etc.

集团拥有8个企业和三个科研机构，形成了强大的产业基础和研发平台，建成了从氟矿石开采到氟化工基础材料无水氟化氢，从甲烷氯化物到绿色环保制冷剂，再到含氟高分子材料及其深加工，以至到尖端技术六氟丙烯、偏氟乙烯、全氟乙烯、全氟离子交换树脂及离子膜等组成的高新技术产业链和产业群。

In the wet-process phosphoric acid production from the Hubei phosphate ore, one of the bothersome problems is that potassium fluosilicate and sodium fluosilicate scales are liable to form on the filtration system owing to its high potassium and sodium content, which greatly restrains the application of Hubei phosphate ore.

本文首先采用人工冷却系统模拟湿法磷酸生产的真空过滤系统冷却过程，研究垢物的析出规律，实验结果得知：垢物的主要成分为氟硅酸钠和氟硅酸钾，氟硅酸钠首先析出，结构致密，其次是氟硅酸钾，最后是二水硫酸钙，氟硅酸钠对氟硅酸钾有很强的结晶诱导作用；然后在三种生产中常用的不同的材质钼二钛、聚氯乙烯和聚四氟乙烯表面进行结垢试验，发现聚四氟乙烯表面最不易结垢，而在钼二钛表面最易结垢。

Based on the raw materials "HF" with the best quality supplied by the inner of the Chemical Group, the main products of our company is Fluorinated salt such as Potassium Fluoborate, Potassium Fluotitanate, Potassium Fluosilicate, Potassium Fluoroaluminate ,Potassium Fluorozirconate and etc.

公司依托化工集团内部提供的优质氢氟酸，主要生产：氟钛酸钾、氟硼酸钾、氟硅酸钾、氟铝酸钾、氟锆酸钾等氟盐系列产品。

This paper also shows the distribution of the fluorine in sediments of the area is mainly controlled by the chemical composition of the material from the surrounding islands, and the element seems to be incorporated by the hornblende at the most extent, thus the correlation between the element and the hornblende amount in the sediments can be expressed statistically as following: F=217+lnVh.

研究结果表明，测区沉积物中氟含量分布主要受周围岛屿风化基岩的化学成分制约；沉积物中主要含氟矿物：萤石/磷灰石、黄玉、黑云母等含量极低，氟在沉积物中赋存的矿物相主要与角闪石[AX_2Y_5Z_8O_(22)_2]有关。氟含量与碎屑矿物中角闪石的体积比间的关系式可大致表示为：氟含量=217+361nV_H；间隙水中的低氟主要由测区化学风化不发育及氟的钙盐沉积所致。

N,N-dimethyl-N'-(2-trifluorometyl-1-pentafluoroethyl) perfluoro propenyl propane diamine and N,N-dimethyl N'-(2-trifluorometyl-1-pentafluoroethyl) perfluoro propene propane diamine were prepared by the reaction of hexafluoropropene dimer and N,N-dimethyl propanediamine in the molar ratio 1:1.0 at about 35℃for 8h, and the structures of I were identified by IR and NMR spectra.

本文以六氟丙烯二聚体和N，N-二甲基丙二胺为主要原料合成了两种含氟中间体叔胺——N，N-二甲基-N'-(2-三氟甲基-1-五氟乙基)全氟丙烯基丙二胺和N，N-二甲基-N'-(2-三氟甲基-1-五氟乙基)全氟烯丙基丙二胺，用薄层色谱和柱色谱等方法对产品进行分离提纯，并运用红外光谱和核磁共振等分析手段对其结构进行了表征。

A clean production technology for fluorine and silica white is introduced, with fluorine-containing gas raw material directly absorbed by ammonium fluoride, or ammonia to obtain ammonium fluorosilicate ,and to get ammonium fluoride and silica white by ammonization, further to manufacture other fluoride product with high value.

介绍一种利用磷肥生产中的含氟废气生产氟化合物与白炭黑的清洁生产方法：用氟化铵或氨直接吸收含氟气体生成氟硅酸铵，然后氨化得氟化铵与白炭黑(SiO2)，氟化铵可进一步加工为其它高价值氟化物产品。

Tetrachloroterephthalic acid was prepared by chlorinating terephthalic acid, oleumsolvent and iodine catalyst. Tetrachloroterephthalic acid was acylated by sulphurous oxychloride in the presence of DMF to form tetrachloroterephthaloyl chloride. The acyl chloride product was fluorinated by potassium fluoride and esterified by methanol to synthesize dimethyl tetrafluoroterephthalate. The ester was reduced with potassium borohydride and lithium chloride to give tetrafluoroterephthalyl alcohol. The above product was bromated in the hydrobromic acid to obtain 4-bromomethyl-2,3,5,6-tetrafluoro-benzene methanol. 4-Methyl-2,3,5,-6-tetrafluorobenzene ethanol was obtained by reducing the bromide with magnesium. In the exist of DCC and DMAP, tefluthrin was got by the condensation reaction between 4-methyl-2,3,5,6-tetrafluoro-benzene methanol and-(1RS,3RS)- 3-(2- chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl cycolpropanecar-boxylate acid.

对苯二甲酸与氯气在碘存在下以发烟硫酸为溶剂进行氯化制备四氯对苯二甲酸；再以DMF为催化剂与二氯亚砜反应生成四氯对苯二甲酰氯；以氟化钾为氟化剂，环丁砜为溶剂置换氟化，再与甲醇酯化得到四氟对苯二甲酸甲酯；以KBH4-LiCl为还原剂二甲醚为溶剂反应制得四氟对苯二甲基苄醇；以氯苯为溶剂在溴化氢溶液中溴化得到溴化产物；在乙醇溶液中经镁粉还原得到4-甲基-2，3，5，6-四氟苄醇；甲基苄醇与功夫酸在催化剂二环己基碳二亚胺和4-二甲氨基吡啶作用下缩合得到七氟菊酯，总收率达43.6%。

As a useful fluorinated product,hexafluoropropene trimers can be prepared from hexafluoropropene oligomerization by gas phase-and liquid phase-methods,and many fluorocarbon surfactants such as full-fluoride nonene oxygen benzene sodium can be derived from perfluorinated nonene.

六氟丙烯可通过气相和液相法进行聚合制得六氟丙烯三聚物，即全氟壬烯，全氟壬烯可以进一步衍生出如全氟壬烯氧基苯磺酸钠等多种氟碳表面活性剂，是一种比较有用的含氟产品。

PTFE referred to F4, because of its excellent dielectric properties and corrosion-resistant chemical (high temperature of the molten fluoride elements and the state of alkali metal), non-absorbent, non-stick, not conductive, low coefficient of friction and not Ageing properties, and is widely used in chemical, petroleum, textile pharmaceutical, metallurgy, machinery, electronics, electrical appliances, electricity, food and aviation, military and scientific research in all walks of life, I plant the development of metal bellows, compensation , PTFE bellows F4 tetrafluoroethane compensator, F4 metal composite compensation, anti-corrosion steel liner tetrafluoroethane pipe, steel-lined tetrafluoroethane three links, elbow, Stone, the reaction tower, tower chloride, lining tetrafluoroethane valve Doors, tetrafluoroethane pads and steel-lined polypropylene pipes and accessories, and earnestly solve the user in the production process by the various anti-corrosion problems.

聚四氟乙烯简称F4，由于其优异的介电性能与耐化学腐蚀性(高温下的氟元素和熔融状态下的碱金属外)，不吸水、不粘、不导电、摩擦系数低及不老化等性能，而被广泛应用于化工、石油、轻纺制药、冶金、机械、电子、电器、电力、食品及航空、军用与科研等各行各业中，我厂开发的金属波纹管、补偿器，四氟波纹管F4四氟补偿器、F4金属复合补偿器，钢衬四氟防腐管件，钢衬四氟三通、弯头、四通、反应塔、氯化塔、衬四氟阀门，四氟垫片以及钢衬聚丙稀管道及配件，切实解决了用户在生产过程中所遇到的各种防腐问题。

The labia have now been sutured together almost completely.The drains and the Foley catheter come out at the top.

此刻阴唇已经几乎完全的缝在一起了，排除多余淤血体液的管子和Foley导管从顶端冒出来。

To get the business done, I suggest we split the difference in price.

为了做成这笔生意，我建议我们在价格上大家各让一半。