气成的

Hydrocyanic acid and water proceed via a five-centred transition states then transformed by its exterior hydrogen-bond; The results show that the activation energy of the isomerizing reaction in the aqueous phase is lower than that in the gas phase. It is likely that the hydrogen bonds formed in the complexes and the solvent effect play an important role.

计算结果表明，在水相中异构化过程的活化能比在气相中低，无论在气相还是在水相中异氢氰酸通过水氢键转化成氢氰酸容易些，而氢氰酸由水氢键转化成异氢氰酸相对要困难些，分子间氢键和溶剂化效应在异构化反应过程中起到重要的作用。

The outgas types and amount of different gas resource varied with the different geological conditions and evolution processes. There are four outgas models including the model in which inorganic gas directly overflows from mantle matter through lithospheric fracture,the model of heat flow piercement outgas,the model of volcano-magma outgas,and the model of carbonate rock outgas due to heat metamorphism.

对气藏成藏条件和深部壳幔结构的研究表明，松辽盆地存在多种类型无机"气源"，由于赋存的地质条件和演化过程不同，不同气源脱气的方式、脱出气体的类型、脱气量也大不相同，共有4种主要的模式：地幔物质沿超岩石圈断裂直接脱气模式；热流底辟体脱气模式；火山—岩浆成因模式；碳酸盐岩热变质成因模式。

An advanced non-destructive measurement technique was applied for the first time in the research of two-phase transport of gas-water in coal seam. The home-made triaxial osmoscope which is made up of non-magnetic polycarbonate material and can change confining pressure, axial pressure and pore pressure, was placed into the magnetic cavity of NMRI instrument.

首次将先进的无损检测NMRI成像技术引入煤层中气水两相运移的研究领域，将自主设计研制的、可同时改变围压、轴压和孔隙压的、非磁性聚碳酸酯材料制成的三轴渗透仪置于NMRI成像仪磁体腔中，通过气驱水和水驱气NMRI试验实时观测了气水流动规律。

Through the tests on gas driving water and water driving gas, the flow law of gas and water was real-time observed. Mainly based on the test of water driving gas as an example, the development of molding coal sample and NMR triaxial osmoscope was demonstrated. The experiment process of water driving gas and parameters were demonstrated. NMRI images of molding sample in horizontal cross-section along the driving direction were obtained by NMRI instrument. The results from images were analyzed and compared. Some novel laws were obtained as the following:(1) the leading edge of water driving has inconsistency. This certified the important previous conclusion that the storage of methane mainly was absorbed in inner surface of pore from NMRI technique;(2) the existence of dominant driving pathway was tested and the way kept almost fixed. The pathway is apt to exist in the edge of coal samples where pore and fracture fully develop;(3) the variation of water flow determines the transport velocity of leading edge of water driving and it has lag effect;(4) the effectiveness of the first driving is better than the second driving;and (5) the subsequence of water driving gas are from trunk fractures to branch fractures, then to branch pores.

主要以水驱气NMRI试验为例，详细介绍了核磁共振三轴渗透仪和型煤试件的研制，并重点阐述了水驱气试验过程和相关参数，利用NMRI技术实时观测得到了不同时间沿驱替方向型煤试件水平剖面的NMRI成像图，最后对试验结果进行了比较分析，揭示了一些新的规律认识：(1)水驱替前缘具有不一致性，从NMRI试验角度验证了前人甲烷类气体赋存形式主要以吸附在孔隙内表面为主的重要结论；(2)煤试件存在优势驱替路径，且这种优势路径在驱替过程中基本保持不变，水驱气的优势驱替路径易产生在煤试件边缘，即煤孔隙裂隙发育区；(3)水驱流量变化决定了水驱前缘的运移速度，且对水驱气效果具有滞后效应；(4)水驱气初次驱替效果好于二次驱替效果；(5)水驱替气的顺序为：主要大裂隙—周边裂隙—周边孔隙。

Three periods petroleum accumulation exists in South-of-fifth-area oil field, the first period oil and gas is the Jiamuhe group mature and high mature hydrocarbon and the Fengcheng group mature hydrocarbon in late Permian to early Triassic, was destroyed in the Indo-Chinese movement intermediate stage, but some still is conserved in good conserved condition, which is one of exploration objects. The second period is the Fengcheng group high mature hydrocarbon in late Triassic to early Jurassic, which is the important exploration target. The third period is the Jiamuhe group overmature dry gas in the late Jurassic Period to the early Cretaceous.

五区南油气藏存在三期成藏，第一期是佳木河组过成熟干气和风城组成熟油气，成藏期在晚二叠世到早三叠世，在印支运动中期被破坏了，但是在保存条件好的地区仍存在这一期油气藏，它是勘探的对象之一；第二期是风城组高成熟油气，成藏期在晚三叠世到早侏罗世，也是勘探的对象之一；第三期是佳木河组过成熟干气，成藏期在侏罗纪到早白垩世。

In combination with seismic reflection features and probable gas resource discussion, it is concluded that there probably exist two kinds of reservoir models in the X Block. In the areas where faults or collapse structures develop, the gas resource is probably composed of thermogenic gas, gas hydrate is characterized by multilayer distribution, while in the inactive areas the gas resource is probably composed of biogenic gas, and gas hydrate is characterized by monolayer, which mainly distributes in a narrow zone on the surface of BSR (bottom-simulating seismic reflector).

结合地震反射特征和可能的气源讨论初步认为，X区块天然气水合物的成藏模式主要有两种类型：在断裂或滑塌构造发育区，水合物的气源以热解成因气为主，水合物呈多层分布；在构造平缓地区，水合物的气源以生物成因气为主，水合物呈单层分布，且主要分布在似海底反射之上一个狭窄的范围内。

Lithologies are mostly sand and carbonate rocks, caps are mud rock, shale and magmatite. Entrap types are anticline, fault block rebuilt by breaking and the screened entrap diapered rock mass. The composition is CO_2, N_2, CH_4, C_2H_6 and He etc. It is magma air source body and its geologic fashions are intrusion and buried volcanic conduit. The relations between gas reservoirs and gas source bodies have three types: magma intrusion-breaking-communicated gas reservoir, magma intrusion-contacted CO_2 reservoir and buried volcanic conduit-contacted gas reservoir. The CO_2 migration in magma intrusion is consisted of fusing and crystallizing phases;it in volcanic conduit is consisted of near-surface effusion and crystallizing phases.The buoyancy of CO_2 in water far more than migration resistance in breaking or chink, CO_2 is easy float upward, the floating can results in differentiation of different density gases and concentration of sealed gas. The gas in sand reservoir firstly migrate into the higher porosity and coefficient of permeability sand, and along with the pressure going up it migrate into the lower. In magma intrusion-breaking-reservoir migration, CO_2 firstly migrate into watered breaking, began gravity differentiation and concentrate, the gas pressure time and again go up, CO_2 migrate into reservoir and concentrate under expansibility as the pressure reach upward a given extend. The CO_2 in reservoir experience four breaking modes: chemistry deposition, dissolution, diffusion and mechanic breaking, the pressure balance can be broken by faulting and the CO_2 will further migrate and form new reservoir.

济阳坳陷已发现的八里泊、阳25、平方王、平南、高青、花17 CO_2气藏主要储集层位有奥陶系、中生界、沙四段、沙三段、沙一段、馆陶组和明化镇组，储集层岩性以砂岩和碳酸盐岩为主，盖层以泥质岩、页岩和岩浆岩为主。；圈闭类型主要为受断裂改造的背斜、断块及刺穿岩体遮挡圈闭。；气体成分主要有CO_2、N_2、CH_4、C_2H_6、He等。；主要气源体为岩浆气源体，气源体的主要地质形式为侵入体和埋藏的火山通道。；气藏和气源体的空间关系有岩浆侵入体一断裂一气藏沟通型、岩浆侵入体-CO_2气储集层接触型和埋藏火山通道-气储集层接触型三种类型。；岩浆侵入体CO_2气运移分为熔融运移阶段和结晶运移阶段，火山通道中CO_2气运移分成近地表喷发阶段和结晶运移阶段。；断裂中，CO_2在水中的浮力远大于运移阻力，CO_2气容易上浮，CO_2在断裂中的易浮性导致不同密度气体的分异和走向上封闭的断裂气体相对富集。；气体在砂岩储集层运移聚集具有选择性，会优先进入孔隙度和渗透率较高的砂岩，随着压力增加，才会进入孔隙度和渗透率较低的砂岩；在岩浆气源体-断裂-储集层空间输导格架下，CO_2气在膨胀力的驱动下，首先进入含水的断裂并重力分异而聚集，气体压力会不断增高，当压力增至一定程度，CO_2气会向高孔隙度、渗透率的储集层运移并聚集。；在岩浆气源体-储集层接触空间输导格架下，CO_2气受膨胀力的驱动直接向储集层运移并聚集。；成藏的CO_2气会经历化学沉淀、溶解、扩散和机械破坏四种破坏方式，会受断裂切割而打破压力平衡，沿断裂进一步运移和聚集成藏。

In first, a new short time formula of one dimension heat conduction differential equation, based on the theory of one dimension transient method, is presented for thermophysical property measurement of wood. The result of testing on red pine and larch wood arc satisfied by new method.In succession, the relationship between heat conductivity of wood and moisture, density, porosity, temperature and grain is studied experimentally in the range from 25 to 100℃. The result shows that, the heat conductivity is in direct proportion to density. but in inverse proportion to porosity. The heat conductivity of air-dried wood increased probably linear with the temperature rising. And that heat conductivity along the grain of wood is higher than that cross the grain. The former is 1.8 or 2 times of the latter.

文中研究了25～100℃范围内，气干木材的导热系数与含水率、密度、孔隙率、温度及热流方向的关系，研究表明：木材导热系数与密度成正比关系，与孔隙率成反比关系：对于针叶材，导热系数与密度及孔隙率成线性变化关系，而对于阔叶材其变化关系近似成二次曲线；气干木材的导热系数随着温度的升高近似呈线性增加：热流平行于纹理方向的导热系数大于垂直于纹理方向的导热系数，两者的比值大约在1.8～2之间。

The outgas types and amount of different gas resource varied with the different geological conditions and evolution processes. There are four outgas models including the model in which inorganic gas directly overflows from mantle matter through lithospheric fracture,the model of heat flow piercement outgas,the model of volcano-magma outgas,and the model of carbonate rock outgas due to heat metamorphism.

对气藏成藏条件和深部壳幔结构的研究表明，松辽盆地存在多种类型无机&气源&，由于赋存的地质条件和演化过程不同，不同气源脱气的方式、脱出气体的类型、脱气量也大不相同，共有4种主要的模式：地幔物质沿超岩石圈断裂直接脱气模式；热流底辟体脱气模式；火山—岩浆成因模式；碳酸盐岩热变质成因模式。

On the basis of the masteries for the aluminum oxide ore pulp drying and calcination, a mathematical model was developed for simulating the process of heat transfer and the calcination of two-phase flow in a new type furnace designed by Zhongzhou Branch Company, China Aluminium Corporation Limited. The fields of velocity, temperature and pressure of the two-phase flow and the reaction time were gained by optimizing calculation under the condition of different operational parameters and geometric parameters. The effect of vent position velocity and atomization particle diameter on the drying and calcination technology of aluminum oxide ore pulp was discussed.

在了解氧化铝矿浆干燥、烧成工艺及设备的基础上，针对中国铝业股份有限公司中州分公司开发的一种新的氧化铝矿浆干燥和烧成炉，建立了矿浆干燥、烧成炉内气固两相流的流动传热以及烧成过程的数学模型，就干燥、烧成炉运行参数及各几何参数进行优化计算，得出了炉内气固两相流动的速度场、温度场、压力场以及颗粒干燥和烧成反应时间，并分析讨论了喷口位置、喷口速度、颗粒雾化粒径等参数对氧化铝矿浆干燥、烧成工艺的影响。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。