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Based on the QSAR equation for MDR modulators, a new type of MDR modulators was designed with benzimidazole moiety as their parent nucleus, and four compounds of this type were synthesized and characterized.

在MDR逆转剂构效关系的理论指导下,选定苯并咪唑为母核,设计了一类新的MDR逆转剂候选化合物,合成了4个这种类型的新化合物。

The process of beta decay increases or decreases the positive charge of the original nucleus by one unit without changing the mass number.

衰变过程使母核增加或减少一个单位的正电荷而不改变它的质量数。

As a result, not only 3-ene isomer of cephem nucleus producing was avoided, but also the cost was reduced.

这样既降低了成本,又避免了碱性反应条件下头孢菌素母核3-烯异构体的生成。

Ion pairs with different structure of either dye anion or onium cation have different properties.

染料母核和碘翁阳离子的结构均对离子对体系的性质有影响。

What is the parent nucleus ?

母核是什么?

The results showed that the biological activities are closely related to the steric conformation and distribution of electrostatic potential of carboxyl group: The coplanatity between the group of C-3 position and the parent nucleus and the coplanatity between the group of C-3 position and C-4 keto group are very important for biological activities.

结果发现该类药物的抗菌活性与C 3位的空间构象和静电势分布有着紧密的联系。C-3位羧基与C-4位酮基共面性、以及它和母核共面性对抗菌活性十分重要,C-3位两个氧原子周围较强的负静电势也是影响活性的重要因素。

The present paper take the purine synonym kui zuo lin as a parent nucleus, separately in its 4 and 7 introduction structure diverse substituted benzene amino and the flexible side chain, designed a series of 4- substitution anilino-- 6- methoxy - 7-(2- hydroxyl to substitute for third oxygen radical) kui zuo lin a kind of compound.

本论文以嘌呤类似物喹唑啉为母核,分别在其4位和7位引入结构多样的取代苯氨基和柔性侧链,设计了一系列4-取代苯胺基-6-甲氧基-7-(2-羟基取代丙氧基)喹唑啉类化合物。

Synthesis of target compounds namely: to vanillic acid as the starting material with methanol under reflux conditions for 4 - hydroxy -3 - p-methyl, then ether, and nitration, reduction, cyclization reaction 6 - methoxy -7 - benzyloxy-quinazoline -4 - one, and then by the chloride in place of aniline, benzyloxy-off, such as etherification reaction of the target compounds; target compounds with the second and third occurrence of substitution reactions of amines by the TM1, that is, 4 - amino-benzene -6 - methoxy -7 - [2 - hydroxy -3 -(N, N-diethyl amino) oxy c] quinazoline; with ether occurred Ornidazole reaction of TM2, namely, 4 - amino-benzene -6 - methoxy -7 - [2 - hydroxy -3 -(2 - methyl -5 - nitroimidazole) C oxy] quinazoline.

本论文以嘌呤类似物喹唑啉为母核,分别在其4位和7位引入结构多样的取代苯氨基和柔性侧链,设计了一系列4-取代苯胺基-6-甲氧基-7-(2-羟基取代丙氧基)喹唑啉类化合物。目标化合物的合成即:以香草酸为起始原料,与甲醇回流条件下得到4-羟基-3-甲氧基苯甲酸甲酯,然后经过醚化、硝化、还原、环合反应得到6-甲氧基-7-苄氧基喹唑啉-4-酮,然后再经氯化、取代苯胺、脱苄氧基、醚化等反应得到目标化合物;目标化合物与二乙胺发生胺取代反应得到了TM1,即4-苯氨基-6-甲氧基-7-[2-羟基-3-丙氧基]喹唑啉;通过与奥硝唑发生醚化反应得到TM2,即4-苯氨基-6-甲氧基-7-[2-羟基-3-(2-甲基-5-硝基咪唑)丙氧基]喹唑啉。

The rules of photo bioactivities are: Without illumination, the tested xanthene derivatives showed almost the same level of inherent toxicity to the same organism, which showed the inherent toxicity of xanthene derivatives were primarily dependent on the structure of parent molecule. Upon illumination, the photosensitizers showed obvious phototoxicity to all organisms. The xanthene derivatives showed stronger phototoxicity to Gram-positive bacteria. With the increasing number of halogen substituents, the singlet oxygen yields increased and the phototoxic activity increased too.

呫吨类化合物的生物活性的变化规律为:未经光照的条件下,呫吨类化合物的对同种待测微生物的固有生物活性基本相同,说明固有毒性可能主要决定于化合物分子的母核结构,其卤素取代基团对其影响较小;经实验光源照射下,所测MLC值明显低于未经光照条件下的值,表明呫吨类化合物对三种微生物的光敏活性明显强于对其相应的固有活性;呫吨类化合物对革兰氏阳性菌能发挥较大的光敏活性。

Results The five purified ginkgolic acid monomers were GA13:0.,GA15:0.,GA15:1 ,GA17:1 and GA17:2 ,with a side chain of 13,15,17 alkyl or ethylenic radicals respectively on their benzene loop.

结果纯化的银杏酸5个同系物单体为GA13:0、GA15:1、GA15:0、GA17:1和GA17:2,其母核苯环上分别有1个13、15及17烷基或烯基的侧链。

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