歧化

The second kind of adsorption mentioned above was the active adsorption state for amination of fatty alcohols, and the third kind of adsorption was active for the disproportionation of dimethylamine.

上述三种吸附中第二种吸附是脂肪醇催化胺化所需要的吸附，而第三种吸附是二甲胺歧化所需要的吸附状态。

It is very difficult to eliminate these influence factors completely by conventional treatment. Surface properties and surface treatment of ultrafine red phosphorus and MMT and their interface properties with polymer matrices were studied in this thesis. The results were characterized by GC, FTIR, XRD, DTA, TG, XPS, UV, SEM, TEM and other physical and chemical methods. The main contents are as following: 1. The study of factors influencing ultrafine red phosphorus's invariability and phosphine liberation indicated red phosphorus undergone oxidation and dismutation reaction in air, and trace ion of iron, copper and nickel fastened water absorption and oxidation, in which the effect of copper ion was the most, while aluminium and zinc ion could slow down red phosphorus'oxidation, and silver ion had the best effect on red phosphorus moisture absorption. Inhibitors such as aluminium hydroxide, magnesium hydroxide, organic phenol and ferrous potassuim cyanide had a good effect on reducing red phosphorus moisture absorption and restraining phosphine liberation.

本文围绕纳微米材料的表面处理及其在高聚物基体中的应用这一主题，系统地研究了超细红磷和蒙脱土两种常见材料的表面特性、表面处理方法及其与高聚物基体的界面特性，通过气相色谱、红外光谱、X射线衍射、差热、热重、X射线光电子能谱仪、紫外光谱、扫描电镜、透射电镜等现代分析仪器以及其它物理、化学方法对实验结果进行了表征和分析，全文主要内容如下： 1、对影响超细红磷安定性的因素以及磷化氢的缓释研究表明：红磷在空气中发生缓慢氧化、歧化反应，微量的铜、铁、镍等金属离子增加了它的吸水和氧化速度，其中铜离子的作用最为明显，而铝、锌等离子减慢了红磷的氧化速度，银离子对减少红磷的吸湿性效果最好。

The feasibility of recovering low-temperature heat in aromatic fractionator and debottlenecking unit operation through technical revamping is discussed.

通过深入分析后提出了对歧化、异构化和连续重整等芳烃装置进行类热高分改造方案，并对回收低温热的潜力进行科学评估。

Thecompositions of raw material and products were identified with GC-MS, the results indicatedthat the products were composed of (β-acryloxyl ethyl) esters of dihydropimaric acid anddehydrogenated abietic acid, and their relative amounts was consistent with the amount ofdihydropimaric acid and dehydrogenated abietic acid in the disproportionated rosin.

论文还采用GC-MS对原料和产物的组分进行了鉴别，结果表明酯化产物由二氢海松酸酯和脱氢枞酸酯组成，且其相对含量与歧化松香中二氢海松酸和脱氢枞酸组成基本一致。

The desulfurization networks of alkylthiophenes and benzothiophene on OTA catalyst were involving both and direct hydrodesulfurization, but also, containing disproportionation, isomerization.

烷基噻吩和苯并噻吩硫化物在OTA催化剂上脱硫反应网络一方面含有直接加氢脱硫反应，另一方面经历歧化、异构化和裂解等反应。

In this paper,firstly a series of acryloxyl derivatives were synthesized from the dehydrogenated abietic acid,a main composition of disproportionated rosin, through acyl chloridation and esterification.The derivatives included the (β-acryloxyl ethyl) esters of dehydrogenated abietie acid,(β-methacryloxyl ethyl) esters of dehydrogenated abietic acid and (β-methacryloxyl propyl)esters of dehydrogenated abietic acid.

论文首先以歧化松香中的主要成分脱氢枞酸为模型化合物，采用酰氯化、酯化手段合成了它的一系列丙烯酰氧基衍生物，包括脱氢枞酸酯、脱氢枞酸(β-甲基丙烯酰氧基乙基)酯和脱氢枞酸(β-甲基丙烯酰氧基丙基)酯。

When Gluma is applied in vivo, two reactions occur: first, GA reacts with part of the serum albumin in dentinal fluid, which induces a precipitation of serum albumin; and, second, the reaction of GA with serum albumin forms dihydropyridinium, whose disproportionation gives rise to free radicals, and the free radicals induce the polymerization of HEMA.

首次提出Gluma的脱敏机理为：当Gluma涂在过敏的牙本质上时，首先戊二醛交联牙本质液中的血清蛋白并产生沉淀；同时戊二醛与血清蛋白的反应产生二氢吡啶盐，它发生歧化反应，歧化过程中会有自由基产生，从而引发HEMA 聚合，生成另外一部分沉淀，这两部分沉淀共同堵住牙本质小管，起到了脱敏作用。

In the presence of DMAc/LiCl solvent, disproportionated rosin glycide-cassava starch ester was synthesized from cassava starch and modified disproportionated glycide ester under microwave irradiation. The effect of reaction conditions on the degree of substitution has been discussed.

在微波辐照下，以DMAc/L iC l为溶剂体系，歧化松香缩水甘油酯和木薯淀粉亲核开环反应得到歧化松香缩水甘油木薯淀粉酯，探讨了各反应因素对产物取代度的影响。

The justified reform plan of sealing structure of saponified rosin was proposed after the analysis of leak about the filter of saponified rosin,and the leaking question was radical solved.

经过对歧化松香过滤器漏滤问题的分析，提出合理的密封结构改造方案，改造后的过滤器彻底解决了漏滤问题，使用效果良好，既降低了歧化松香液成品成本又节省了维修费

Under atmospheric pressure, binary nanocrystalline sulfides and selenides such as CdS、CdSe、PbS、 PbSe、Cu〓Se、Ag〓S、Ag〓Se、SnSe are obtained at room temperature; nanocrystalline CdTe and PbTe are obtained by heating. Nanocrystalline NiSe〓、CoSe〓 and FeTe〓 are obtained by hydrothermal conditions.

根据硫、硒歧化的碱溶液与碲歧化的碱溶液稳定性的不同，发现在室温条件下可成功获得CdS、CdSe、PbS、PbSe、Cu〓Se、Ag〓S、Ag〓Se、SnSe等二元硫化物与硒化物纳米晶；加热条件下可成功获得CdTe与PbTe纳米晶；而NiSe〓、CoSe〓及FeTe〓的合成则要在水热条件下进行。

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐