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First, a chlorinator was self-designed in this paper, and dichloride of 2-methyl-1-propene was synthesized by 2-methyl-1-propene reacted with chlorine fast in this reactor. By means of the Orthogonal Experiments design and single factor experiments, the influence of several reaction variables on the yield were examined and the optimum reaction conditions under the intervallic operation were obtained, the yield and selectivity of dichloride of 2-methyl-1-prop-ene were more than 65% and 80% respectively. Second, the preparation of 2-methylene-1, 3-propanediol, which dichloride of 2-methyl-1-propene reacted with alkali was investigated. By means of the Orthogonal Experiments design and single factor experiments, the influence of several reaction variables on the yield were examined and the optimum reaction conditions under the intervallic operation were obtained, the conversion of dichloride of 2-methyl-1-propene was 100%. Moreover the preparation of MPO, which 2-methylene-1, 3-propanediol reacted with hydrogen, in presence of Al_2O_3-Pd catalyst, was gotten, and the product was appraised.

本文在氯化反应过程中,自行设计制作出了氯化管式反应器,在该反应器中异丁烯和氯气迅速混合反应生成二氯异丁烯,根据该氯化反应特征利用正交试验和单因素试验考察了有关因素的影响并优化得到了最佳工艺条件,二氯异丁烯的总收率达65%以上,选择性达80%;接着,对二氯异丁烯进行水解反应制得了2-甲烯-1,3-丙二醇,讨论了相关因素对水解反应的影响,并通过正交试验和单因素试验得到了较佳工艺条件,二氯异丁烯的转化率达100%;同时还对制备的2-甲烯-1,3-丙二醇在常压下采用三氧化二铝负载钯催化剂催化加氢得目的产物MPO,并对产品进行了鉴定,从而打通了整个工艺路线。

The effects of five factors on residue rate during the liquefaction of branches of Fraxinus chinensis Roxb. in tetralin-phenol hydrogen-donor solvents were investigated by orthogonal test.

通过正交试验考察了白蜡枝桠材在四氢萘与苯酚混合供氢溶剂中液化过程的5个因素对残渣率的影响。

Hydroisomerization of n hexadecane on zeolite catalysts was studied and the reaction mechanism was discussed, which may provide new clues to developing hydroisomerization catalysts with high selectivity.

对分子筛催化剂上正十六烷的临氢异构化反应进行了研究,考察了不同分子筛催化剂的活性和选择性,并对临氢异构化反应的产物分布进行了分析。

Both niobic acid and niobium oxide can be used as either catalyst,promoter or support in the heterogeneous catalytic reactions,such as selective oxidation,hydration,hydrolysis,alkylation,dehydrogenation and hydrogenation,because of their acidic and redox properties.

作为一种新型的催化材料,铌酸-氧化铌由于其独特的酸性和氧化还原性正受到越来越多人的关注。它可以作为催化剂的活性组分、助剂或载体使用,在烃类转化、选择性氧化、水解、水合、缩合、加氢脱氢等若干酸碱和氧化还原反应中得到广泛的应用。

For the metastable Beta and near Beta phase alloys, with the increasing of hydrogen amounts, the flow peak stresses gradually increase; the elongations for fracture go down through minima and then go up to return or surpass the levels for the uncharging alloys.

由于在高温时氢致弱键机构相对说来不再重要,在正应力高的区域富集的倾向亦大为减小,钛合金在高达上万个PPm的含H量时仍具有相当好的塑性,表现出对氢有巨大的容忍力。

The application of the alloy that can effectively reduce the release of hydrogen, the special technique in manufacturing grid, and the appropriate match of active materials of both negative plates and positive plates, all these enable spiral valve-regulated sealed lead-acid battery, greatly restrain the release of hydrogen from negative plates, at the same time the generated oxygen, due to overcharge of positive plates, arrive at negative plates through the diaphragm and compose with lead in the negative, thus enable the recombination of gas inside of the battery and prevent the case of water loss so that water addition is free.

双登卷绕式阀控密封铅酸蓄电池通过采用具有极高析氢过电位的合金通过特殊工艺制造板栅,同时对正负极活性物质量的合理匹配等工艺措施,使得负极上发生的析氢过程得以最大限度地受到抑制,同时正极因过充电所产生的氧气通过隔膜到达负极,并与负极上的铅发生反应,生成水,这样便使得电池内部气体的再复合,防止失水,实现免维护。

The application of the alloy that can effectively reduce the release of hydrogen, the special technique in manufacturing grid, and the appropriate match of active materials of both negative plates and positive plates, all these enable spiral valve-regulated sealed lead-acid battery, greatly restrain the release of hydrogen from negative plates, at the same time the generated oxygen, due to overcharge of positive plates, arrive at negative plates through the diaphragm and compose with lead in the negative, thus enable the recombination of gas inside of the battery and prevent the case of water loss so that water addition is free.

卷绕式阀控密封铅酸蓄电池通过采用具有极高析氢过电位的合金通过特殊工艺制造板栅,同时对正负极活性物质量的合理匹配等工艺措施,使得负极上发生的析氢过程得以最大限度地受到抑制,同时正极因过充电所产生的氧气通过隔膜到达负极,并与负极上的铅发生反应,生成水,这样便使得电池内部气体的再复合,防止失水,实现免维护。

The application of the alloy that can effectively reduce the release of hydrogen, the special technique in manufacturing grid, and the appropriate match of active materials of both negative plates and positive plates, all these enable spiral valve-regulated sealed lead-acid battery, greatly restrain the release of hydrogen from negative plates, at the same time the generated oxygen, due to overcharge of positive plates, arrive at negative plates through the diaphragm and compose with lead in the negative, thus enable the recombination of gas inside of the battery and prevent the case of water loss so that water addition is free.

选择特点:有较高的放电电压曲线,使用环境宽松,能完全释放能量,适用于1min以内的支撑时间,与GCplus15配合使用,可保障变频器恒定的直流电压。卷绕式阀控密封铅酸蓄电池通过采用具有极高析氢过电位的合金通过特殊工艺制造板栅,同时对正负极活性物质量的合理匹配等工艺措施,使得负极上发生的析氢过程得以最大限度地受到抑制,同时正极因过充电所产生的氧气通过隔膜到达负极,并与负极上的铅发生反应,生成水,这样便使得电池内部气体的再复合,防止失水,实现免维护。

The application of the alloy that can effectively reduce the release of hydrogen, the special technique in manufacturing grid, and the appropriate match of active materials of both negative plates and positive plates, all these enable spiral valve-regulated sealed lead-acid battery , greatly restrain the release of hydrogen from negative plates, at the same time the generated oxygen, due to overcharge of positive plates, arrive at negative plates through the diaphragm and compose with lead in the negative, thus enable the recombination of gas inside of the battery and prevent the case of water loss so that water addition is free.

外型尺寸参考具体型号产品认证 ISO9001,CE,UL卷绕式阀控密封铅酸蓄电池通过采用具有极高析氢过电位的合金通过特殊工艺制造板栅,同时对正负极活性物质量的合理匹配等工艺措施,使得负极上发生的析氢过程得以最大限度地受到抑制,同时正极因过充电所产生的氧气通过隔膜到达负极,并与负极上的铅发生反应,生成水,这样便使得电池内部气体的再复合,防止失水,实现免维护。

One of the main reasons is the influence of hydrogen bonds, such as glycollic and benezene and alkanones, and benezene volatile rate is 2 times the ethanol, butanol alkanones than n-butyl acetate low and volatile rate is also low, from here discernthat chemonucleolysis dosage form hydrogen bonds to limit business card printing and membership card making ink ink film volatile plays an important role to play.

主要原因之一是氢键的影响,如乙醇和苯的沸点接近,而苯的挥发速率为乙醇的2 倍,丁醇的沸点比醋酸正丁酯低,而挥发速率也低,从这里看出氢键对限制溶解剂型制卡和会员卡制作油墨的墨膜挥发起着重要的作用。

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