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Theoretical studies on various geometrical structures of Hypophosphorous acid were carried out using DFT theoretical methods, at the B3LYP/6-311 ++ G(superscript **) level. Intramolecular proton transfer isomerization has also been studied using the intrinsic reaction coordinate.

采用量子化学密度泛函B3LYP方法,在6-311++G基组水平上全优化得到了硫代次磷酸的硫酮式和硫醇式两种构型异构体以及相应的对映异构体,同时对分子内质子转移异构化反应微观机理进行了理论分析。

The phosphine was quickly oxidized by triplet oxygen to phosphineoxide with a free radical chain reaction at relatively low temperature; while at high temperature, the phosphine react with singlet oxygen through a three member ring intermediate to form phosphineoxide and phosphinate as the product.

在相对较低温度时,膦化物与基态氧发生自由基链反应,膦化物很快被氧化为氧化膦;在相对较高的温度,膦化物与激发态氧直接作用,通过三元环状中间体而最终生成氧化膦和次磷酸酯。

Poly/montmorillonite/2-Carboxyethyl phosphinic acid (PET/MMT/CEPP) nanocomposites were prepared through direct-esterification process by adding reactive flame retardant before esterification, and organic MMT was added before polycondensation.

采用直接酯化法,将共聚型阻燃剂羧乙基苯基次磷酸和对苯二甲酸以及乙二醇混合后酯化,在酯化产物中加入经过有机改性的蒙脱土,缩聚制备了阻燃聚酯/蒙脱土纳米复合材料(PET/MMT/CEPP)。

And In the 60% concentration of sulphuric acid solution, the dosage of thiourea is 0.1%, while hexamethyl tetramine is not suitable for use.

5浓磷酸溶液中硫脲缓蚀剂用量为0.2%,六次甲基四胺缓蚀剂的用量为0.07%。

Thioamide was refluxed with sodium hypophosphite and ppt-Ni prepared beforehand from NiCl〓·6H〓O and Zn powder in a mixture of dioxane and water to give amines in 60-98% yields (12 examples).

催化剂Ni-Zn是用氯化镍和锌粉反应制成,为合金型固体粉末,次磷酸钠作为氢供体,对12种硫代酰胺进行脱硫还原,收率60-98%。

Concentrate consisting of corn, 51%, wheat bran 8%, cake 23%, 10% alfalfa meal, bone meal 3%, salt 2%, DCP 3%, make up the amount of normal daily Each 0.5kg-0.7kg, morning and evening hours twice a supplementary feeding, and give the right amount of high-quality forage.

集中组成的玉米,51%,麸皮8%,蛋糕23%,10%苜蓿粉,骨粉3%,食盐2%,磷酸氢钙3%,弥补前仔细观察情况,日常每0.5公斤,0.7公斤,早晨和傍晚时分两次补充营养餐,并给出了高品质的饲料适量。

Optimal pretreatment conditions of electroless nickel plating for magnesium were decided by many experiments. Phosphoric acid technology was used to instead of acid processing by chromium trioxide and ferric chloride, and excellent coating was obtained by using dipped zinc, cyanide copper, nickel as medium.

通过多次试验确定了镁及镁合金的前处理方案,以磷酸洗的方法代替传统的铬酐加三氯化铁酸洗浸蚀的前处理工艺,配置简单,操作方便,以浸锌层、氰化铜层和中性镍层作为化学镀中间层,得到了结合力良好的化学镀镍层,获得了镁合金表面处理的新突破。

Keywords sodium hypophosphite;venturi-duct;wet dust collector;cyclone separator;PH3 tail gas

次磷酸钠;文氏管;湿式除尘器;旋风分离器;磷化氢尾气

In the paper the main topics are:(1) to analyze the chemistry composition, the X-ray diffraction, the DTA, and the functions of all raw materials;(2) to define the best direction for producing glass and foam glass, and the best burning technical process;(3) to characterize the unit weight and thermal conductivity of foam glass;(4) to analyze the reason of bubbling up, including the influence factor of temperature, time and so on;(5) to discuss the reasons of leading to shortcomings.There is high content quartz (SiO2) in the two gangues from gold mine and potassium feldspar mine respectively. They can be used to prepare glass, because the quartz (SiO2) is the main raw material.

论文的主要内容包括:1、对矿山尾矿的湿化学分析,粒度、X射线衍射和热稳定性的分析,以及硼砂、碳酸钙及制备泡沫玻璃的玻璃粉、磷酸钠实验原料在实验中的作用进行分析;2、确定尾矿烧结成玻璃体和利用玻璃体烧结泡沫玻璃的最佳配方以及两次烧结的最佳烧成工艺条件;3、泡沫玻璃制品的体积密度和导热系数等物理性能的测定;4、泡沫玻璃的发泡机理分析,包括发泡温度、发泡时间、发泡剂的用量、稳定剂的用量及其它因素对发泡作用的影响;5、讨论造成泡沫玻璃成品各种缺陷的原因及其解决方法。

From the sample volume and the distances to the first and second equivalence points, calculate the MOLARITIES of hydrochloric and phosphoric acids in the sample.

从样品的体积以及第一次和第二次等当点的差异,计算样品中氢氯酸和磷酸的莫耳浓度。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。