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The reaction has been drawing increased attention in that the reaction permit the use of organoboron compounds that are thermally stable and inert to water and oxygen.In this section microwave promoted Suzuki reaction of Sodium tetraphenylborate (NaBPh4) with carboxylic anhydrides catalyzed by Pd(PPh3)2Cl2 in THF was first reported.

第二章:微波辐射下Pd配合物催化NaBPh_4与羧酸酐的偶联反应研究本章中我们在微波辐射条件下,研究了PdCl_2(PPh_3)_2催化NaBPh_4与羧酸酐偶联反应,合成出了十种不对称芳酮,并分别考察了微波辐射功率、辐射时间、溶剂和原料配比等因素对反应的影响,优选出了较佳的反应条件,并根据文献及实验结果,讨论了可能的反应机理。

The Suzuki reaction, the coupling of organoborate compounds with organic electrophiles catalyzed by Palladium complexes, is a valuable Csp2-Csp bond forming reaction. The reaction has been drawing increased attention in that the reaction permit the use of organoboron compounds that are thermally stable and inert to water and oxygen.In this section microwave promoted Suzuki reaction of phenylboronic acid with benzyl halides catalyzed by Pd(PPh3)2Cl2 DMF/H2O(v/v=10 : 2) was first reported.

第四章:微波辐射下Pd配合物催化端烯与芳卤偶联反应研究本章中我们在微波辐射条件下,研究了PdclZ(P Ph3):催化端烯与芳卤的偶联反应,合成出了七种乙烯基化合物;并分别考察了微波辐射功率、辐射时间、原料配比、和PTc等因素对反应的影响,优选出了较佳的反应条件,并根据文献及实验结果,讨论了可能的反应机理。

The plastic hinge model of perforated liner casing is built up to calculate the collapse pressure according to the strength and deformation behavior of perforated liner casing subjected to external pressure. The calculation equations of collapse pressure of perforated liner casing with initial ovalization are deduced by energy method. The influences of phrase angle, diameter of perforation, shot density, initial ovalization, diameter-thickness ratio and yield stress on the collapse pressure of perforated liner casing are studied. The model and equations are used to calculate the collapse pressure of an actual perforated liner casing as example.

摘摇要:根据煤层气完井筛管受力特点建立了筛管受力的塑性铰模型,利用能量法推导出带有初始椭圆度筛管抗挤强度的计算公式,分析了相位角、射孔直径、射孔密度、初始椭圆度、径厚比和屈服强度等影响因素对筛管抗挤强度的影响规律,并对某煤矿使用的筛管抗挤强度进行了计算,与已有的实验数据和有限元计算结果进行了对比。

The plastic hinge model of perforated liner casing is built up to calculate the collapse pressure according to the strength and deformation behavior of perforated liner casing subjected to external pressure. The calculation equations of collapse pressure of perforated liner casing with initial ovalization are deduced by energy method. The influences of phrase angle, diameter of perforation, shot density, initial ovalization, diameter-thickness ratio and yield stress on the collapse pressure of perforated liner casing are studied. The model and equations are used to calculate the collapse pressure of an actual perforated liner casing as example.

根据煤层气完井筛管受力特点建立了筛管受力的塑性铰模型,利用能量法推导出带有初始椭圆度筛管抗挤强度的计算公式,分析了相位角、射孔直径、射孔密度、初始椭圆度、径厚比和屈服强度等影响因素对筛管抗挤强度的影响规律,并对某煤矿使用的筛管抗挤强度进行了计算,与已有的实验数据和有限元计算结果进行了对比。

According to the fact that the otolith system is overcritically damped and the max- imum displacement of the otolith,δ〓 is independent of the dynamics, the upper limit of the Young's module of the gel layer and the estimated value of the dimensionless parameter εwere given,〓 which provided the theoretical basis for the experimental method and the theoret- ical analysis.

根据耳石层运动高度过阻尼而且最大位移〓与运动模式无关的事实,理论上给出了胶质层的Young's模量的上界估计表达式以及无量纲参数ε的参数估计式为〓从而为实验测量方法和理论分析提供了理论依据。

Based on the studies of specimens, taxonomic revision of the genus Kadsura Jussieu has been finished with special reference to seed morphology. Other information from phytomorphology, phytotomy, phytoembryology, phytocytotaxonomy, molecular systematics and phytochemistry etc.

本文主要根据对世界范围南五味子属Kadsura Jussieu植物标本的研究,结合种子形态方面的实验数据,参考植物形态学、植物解剖学、植物胚胎学、孢粉学、植物细胞分类学、分子系统学和植物化学等方面的资料,对世界性南五味子属植物作出全面的分类学修订。

Considering the current market price of phytohormones, NAA at 1.75mg/L and 3-IBA at 4mg/L are recommended in mass cultivation of H. pluvialis .

根据4 株藻株的实验结果以及综合考虑各激素的市场价格,建议在规模化生产中,采用1.75mg/L NAA 和4mg/L 3-IBA 以提高红球藻的培养效果。

According to the structure and working principle of Pneumatically robotic manipulator with 3-DOF, the joint controller was designed based on LabVIEW real-time control module. The experiments of single joint movement and trajectory tracking with three joints have been carried out.

根据3自由度气动机械手的组成及工作原理构造了基于 LabVIEW 的实时控制系统并进行了单关节控制及空间轨迹跟踪方面的实验研究。

The article bases on the result of elastic-optic experiment and uses the energy method, roll theory and thick tube theory to calculate the contact pressure in ringent and close section.

根据全息光弹实验结果得出的轧辊接触压力的分布规律,进而利用能量方法、轧压理论及厚壁筒理论对开口孔型、闭口孔型的轧辊接触压力进行计算。

Considing the geological setting of the source rocks and the secondary hydrocarbon generation factors of primary maturity, major hydrocarbon generation stage and the organic matter type,two series of samples of humic and sapropelic organic matter had been selected.

根据烃源岩发育的地质背景,综合考虑二次生烃的原始成熟度、主要生烃阶段、有机质类型等因素,用高压釜和热解生烃模拟实验完成人工模拟和自然演化系列的两组样品腐植型和腐泥型共16个。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。