核配合的

Its zinc complex was applied in asymmetric direct aldol reaction of acetone and p-nitrobenzal...

设计合成了一种NOBIN衍生的手性配体，初步研究了该手性配体的双核锌配合物在对硝基苯甲醛和丙酮的不对称直接醇醛缩合反应中的催化应用，20℃和20mol％催化剂量下，获得了32.5％ee和72％收率的产物。

All the compounds are characterized by IR and elemental analysis.we design and prepare a bipyridinium supramolecular compound and six coordination compounds, which are also characterized by IR, elemental analysis and X-ray structure analysis. According to X-ray structure analysis, hydrogen bonds and n-n stocking interactions participate in the architecture of three-dimensional framework [H2L1 (NO3)2 (H2O)2]n; one-dimensional zigzag coordination polymer [Hgl21.5CH3OH]n; binuclear metallamacrocycle (HgI2L2)2 3H2O; helical double-stranded one-dimensional coordination polymer [Co2(L2)2-2CH3OH]n; double-stranded one-dimensional coordination polymer [Co2(L3)2-CH3OH-CH3CN]n; and three-dimensional compound [Cu(C5H4NCOO)2(H2O)2]-H2O with hydrogen bonds, three-dimensional coordination polymer {[Cd(C5H6NCOO)2H2O]-DMF}n, which are indirectly obtained from the precursor ligand L3 through metal ion induced the hydrolysis of diamide and self-assembled with the hydrolyzate.

我们首次合成了一个双吡啶鎓超分子化合物和六个过渡金属配合物，并通过IR谱，元素分析和X-ray晶体衍射分析对它们进行了表征。X-ray晶体结构分析表明：超分子化合物[H_2L1·(NO_3)_2·(H_2O)_2]_n是由多种氢键和芳香环间的π-π堆积作用构建的三维无限结构；[HgI_2(L1)·1.5CH_3OH]_n是一维锯齿状配位聚合物；(HgI_2L2)_2·3H_2O是双核金属大环化合物；[Co_2(L2)_2·2CH_3OH]_n是具有一维双螺旋结构的配位聚合物；[Co_2(L3)_2·CH_3OH·CH_3CN]_n为一维双链结构的配位聚合物；以及由非直线形配体L3在金属离子Cu和Cd的诱导作用下发生水解，并且金属离子与水解产物——异烟酸根离子自组装，形成了三维氢键超分子化合物[Cu(C_5H_4NCOO)_2(H_2O)_2]·H_2O和三维配位聚合物{[Cd(C_5H_6NCOO)_2H_2O]·DMF}_n。

The design of a nonmental ultrasonic detector was introduced. The detector was based on EP2C20 series FPGA chip,through adding NiosII soft processor and other interfaces to FPGA ,equipped with high precision data collection system and TFT LCD module and so on.The system was constituted.It including ultrasonic eradiating,receive sychronously,audio parameter detecting automatically,data analyse and process,display result timely,data storage and data output circuits.For the developing of imaging,intelligent and automation of ultrasonictesting ,a very good foundation is established by the system.

介绍了非金属超声检测仪的软硬件设计方法该仪器以EP2C20系列FPGA芯片为核心，通过在FPGA中加载NiosII软核处理器和其他外围接口电路，配合高精度数据采集系统TFT液晶显示模块等设计而成该仪器集超声波发射同步接收声参量自动检测数据分析处理结果实时显示数据存储与输出等功能于一身，为数据的进一步分析处理和实现超声检测的图像化智能化自动化奠定了良好的基础

This molecule possesses C~2 point group symmetry. The structures of the complexes B and C are completely same.

配合物B和C具有完全相同的结构，它们是以4个苯甲酸根为桥，2个phen和2个C~6H~5COO^-为端基的中心对称双核分子，其中6个苯甲酸根的成键状态可分为3种状况。

A successful strategy leading to one-, two-, and three-dimensional (1D, 2D, 3D) systems is the using of metal cations of link reactively stable coordination compounds containing potential bridging blocks, i.e.

一种成功的设计具有孤立异金属多核结构、一维、二维和三维超分子结构的方法就是以"配合物为配体"的策略。

Due to their applications in magnetic, optical, electronic and catalyst, polynuclear lanthanide clusters are of importance. In this part, a series of nanowheel-shaped nonanuclear lanthanide clusters,〓〓(Ln=Sm~Tm; BA=benzoylacetone), were prepared and characterized. Each complex can exist in three phases, i. e., cubic, tetragonal and triclinic.

本论文第二部分在醇溶液中以三乙胺调变溶液pH，利用β-二酮配位方式的灵活性成功地构筑了一系列结构稳定、纳米尺度轮状的九核稀土配合物〓〓（Ln=Sm~Tm；BA=苯甲酰丙酮），并在不同溶剂中重结晶分别得到了三斜、四方以及立方三种晶型的晶体。

Some new results are obtained from the studies: 1 a novel thermokinetic research method, the characteristic reduced parameter method, has been proposed, and the kinetics of oxidation of benzoquinone by hydrogen peroxide has also been investigated with this method; 2 the kinetic mathematical models that the metallomicelles made from the mono-nuclear or dinuclear complexes and surfactants catalyze the phenolic derivant oxidation have been established respectively; 3 the feasibility and mechanism that the metallomicelle, a mimetic model of peroxidase, catalyzes the phenolic derivant oxidation has been discussed.

研究得到如下新的结果：(1)提出了一种新的热动力学研究法——特征对比参量法，用该法研究了过氧化氢氧化苯醌反应动力学；(2)分别建立了由单核和双核金属配合物与表面活性剂形成的金属胶束催化酚类氧化反应的动力学数学模型；(3)探讨了金属胶束模拟过氧化物酶催化酚类氧化反应的可行性及其机理。

Four new salicylaldehyde derivatives with a glucose or mannose moiety were synthesized with 2-tert-butylphenol or 4-tert-butylphenol as the starting material, followed by the formylation, chloromethylation, nucleophilic substitution reaction with the desired carbohydrate. The salicylaldehyde derivatives condensed with ethylenediamine to give the Schiff bases, which coordinated with Mn to afford four novel sugar-based Salen Mn complexes.

首先，分别以2-叔丁基苯酚和4-叔丁基苯酚为起始原料，经过甲酰化反应、氯甲基化反应、和糖类衍生物的亲核取代反应制得了四种新型并入葡萄糖基或甘露糖基的水杨醛衍生物，将它们与乙二胺缩合生成希夫碱配体，得到的配体与过渡金属Mn~(3+)配位制备出四种新型含糖基的Salen Mn配合物。

Compound 20 has a two-dimensional hybrid structure on the basis of A-type Anderson polyoxometalates and trinuclear silver coordination complex subunits and sodium dimmers.

化合物20是将A型Anderson多酸与三核的银配合物簇及钠的二聚体形成的2D杂化结构。

In Yunlin Hsinhsing industrial District land reclamation project, sand filled Geotubes are used to form the segmented breakwaters along the district perimeter and stone blocks are used to protect the shoreline and foreshore. This research use computer simulation to analyze the production rate of establishment of Geotubes for the aforementioned project.

因此本研究利用电脑模拟技术运用在砂肠围堤工程，并以新兴工业区为实际模拟案例建立砂肠围堤施工CYCLONE模型，利用模拟分析技术配合COST电脑模拟程式进行模拟分析，再以实际施工历史数据与电脑模拟做相互验证，检核模拟结果是否与现场符合，进而模拟以不同砂肠轮进长度的组合之生产力，比较出最佳砂肠长度的组合。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。