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枞酸酯

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It was found that ARA was composed of esterification products of (2-HEA)-ester with pimaric acid, dehydroabietic acid, abietic acid and two isomers of acrylpimaric acid. ARA is a good crosslinking agent which can copolymerize with most vinyl monomers. The properties of solvent-resistance and heat resistance of the copolymer were improved considerably by the use of ARA.

实验结果表明:ARA主要由海松酸、脱氢枞酸、枞酸和丙烯海松酸的二种异构体的丙烯酸-2-羟基乙基酯的酯化产物组成,ARA是一种良好的交联剂,可与大多数乙烯基单体共聚合,其与MMA的共聚物的耐溶剂性和耐热性均得到了较大幅度的提高。

Thecompositions of raw material and products were identified with GC-MS, the results indicatedthat the products were composed of (β-acryloxyl ethyl) esters of dihydropimaric acid anddehydrogenated abietic acid, and their relative amounts was consistent with the amount ofdihydropimaric acid and dehydrogenated abietic acid in the disproportionated rosin.

论文还采用GC-MS对原料和产物的组分进行了鉴别,结果表明酯化产物由二氢海松酸酯和脱氢枞酸酯组成,且其相对含量与歧化松香中二氢海松酸和脱氢枞酸组成基本一致。

In this paper,firstly a series of acryloxyl derivatives were synthesized from the dehydrogenated abietic acid,a main composition of disproportionated rosin, through acyl chloridation and esterification.The derivatives included the (β-acryloxyl ethyl) esters of dehydrogenated abietie acid,(β-methacryloxyl ethyl) esters of dehydrogenated abietic acid and (β-methacryloxyl propyl)esters of dehydrogenated abietic acid.

论文首先以歧化松香中的主要成分脱氢枞酸为模型化合物,采用酰氯化、酯化手段合成了它的一系列丙烯酰氧基衍生物,包括脱氢枞酸酯、脱氢枞酸(β-甲基丙烯酰氧基乙基)酯和脱氢枞酸(β-甲基丙烯酰氧基丙基)酯。

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这两个团体间的分歧难以掩饰。

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这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

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