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Kinetics characteristics of α- pinene isomerization catalyzed by activated carbon supported phosphotungstic acid was studied .

研究了活性炭固载磷钨酸催化α-蒎烯的异化反应的动力学特征,研究表明,以环己烷作溶剂,α-蒎烯在活性炭固载磷钨酸上的异化服从准一级动力学模型,其反应的表观活化能为100。

The population relaxation dynamics and cis/trans photoisomerization process were carefully examined by the isotropic transient study.

藉由分析等方向性的瞬时行为及瞬时光谱的演变过程,我们得知各异物分子在激发态的能量弛豫及顺-反异化的过程。

Finally, a comprehensive model was proposed to elucidate the main characteristics and essential time constants of the cis/trans photoisomerization processes among the three 1,4-distyrylbenzene isomers.

最后,我们提出一套完整的动力学模型来描述对-二苯乙烯基苯的顺-反异化的特徵及其异化的速率。

The obtained potential energy curves disclosed that a four-state cycle existed in the ground and excited states. It was also found that the activation energy for the methyl transfer was higher compared to the phenyl transfer, which was consistent to the experimental results that the photoisomerization of the phenyl substituted derivative was more rapid than the methyl substituted derivatives.

对反应势能面的研究发现,在光异化反应中化合物M21和M21、M31的基态和激发态虽然都可以成四能级反应过程,但由于M21异化过程的活化能较高,使其所成的四能级反应难以进行,这就从理论上解释了迁移基团为甲基的M21变色性能低于迁移基团为苯基的M31的实验结果。

The photoresponsive properties of the azobenzene polymers are based on the photoinduced fast and reversible isomerization between the trans and cis isomers of azobenzene upon exposure to UV or visible light, which triggers significant changes in the physicochemical properties of polymer materials. Recent years have witnessed a rapidly increasing interest in azo-containing polymers due to their potential in various optical and optoelectronic applications such as optical data storage, liquid-crystal displays, molecular switches, nonlinear optical devices, photomechanical systems and so on.

偶氮分子在光照下能够发生可逆顺反异,从而引起偶氮聚合物发生分子取向以及象转变,使得偶氮聚合物具有优越的光学活性,同时偶氮聚合物结合了偶氮单体的光学活性和高分子材料优异的力学性能和加工性能,在光信息存储材料、非线性光学材料、液晶材料等领域都有重要的应用价值。

The law of thermo isomeric changes of the pimaric,ellioti pimaric, levopimaric,longifolic,dehydropimaric,abietic and neoabietic acids in the oleoresin of Pinus elliottii were studied in a comparison with those of resin acids in the oleoresin of Pinus massoniana .

本文研究湿地松松脂中海松酸、湿地松酸、左旋海松酸、长叶松酸、去氢枞酸、枞酸、新枞酸受热异变化规律,并与马尾松松脂中的树脂酸热异变化进行对比,为湿地松松脂的生产提供理论依据。

It was found that La〓 does not affect the binding affinity between calmodulin and Polistes Mastoparan, a known calmodulin binding peptide, neither the conformation of the ternary complex. Excessive amount of La〓 result in the decrease of the binding constant and the disrupted conformation. The binding affinity of La〓 to calmodulin increased in the ternary complex (La〓-CaM-Mas/Mas X), which suggested the coordination between the two global domains. The binding priority between the two global domains is also changed: La〓 more is likely to bind to the C-terminal of calmodulin than to N-terminal, thus facilitates the binding of Mas/Mas X to the C-terminal of calmodulin as the first step of the Mas/Mas X binding.

在以钙调蛋白结合肽—Polistes Mastoparan和Mastoparan X为对象的研究中,我们发现,除非过量,否则La〓的存在不影响钙调蛋白与Mas间的结合常数以及象;过量的La〓(La〓/CaM摩尔比>4)将引起钙调蛋白结合功能的下降,同时明显改变金属-钙调蛋白-Mas三元复合物的象;La〓对Ca〓CaM-Mas的N末端表现高度选择性,显示了在三元复合物中两种离子间的协同效应;在三元体系中,La〓与钙调蛋白的亲和力明显上升,而且亲和力上升的程度因钙调蛋白结合肽的不同而有明显差异,显示了作用的选择性;Mas和MasX的存在改变了La〓在钙调蛋白上的结合顺序,La〓很可能优先与C末端结合,从而使Mas/Mas X首先与C末端结合,该顺序与钙离子相同;La〓的参与使三元复合物在动力学上更加稳定。

He adsorption behavior of polydisperse polymers at solid-liquid interfaces is studied by the method of Monte Carlo simulations based on the lattice model, and effects of the polymer chain length in systems of both average and normal distributions on the polymer conformation (tails, trains and loops distribution) are evaluated.

在格子模型基础上用Monte Carlo方法模拟研究了多分散高分子在固液界面的吸附行为,重点考察了平均分布和正态分布两种不同链长分布形式的高分子在固液界面吸附型的分布规律。发现高分子不同的链长分布形式,对高分子吸附型的性质影响较大。

The structure of "ai v bu v" happens deviation in different language environment, which is resulted in the constructive polysemant.

爱V不V&式在不同的语境中发生语义偏移,是式多义性的表现。&

The need of a local prestrain on SMA is proposed in order to realize local active control of intelligent structures.

上述SMA本关系式还被用来推导了SMA混杂复合材料单层板的本关系。

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However, as the name(read-only memory)implies, CD disks cannot be written onorchanged in any way.

然而,正如其名字所指出的那样,CD盘不能写,也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口,替代木托盘,免薰蒸,符合欧盟、北美各国对出口货物包装材料的法令要求;喷涂钢托盘适用于重载上货架之用,托盘表面根据需要制作成平板状、波纹状及间隔形式,满足不同的使用要求。

A single payment file can be uploaded from an ERP system to effect all pan-China RMB payments and overseas payments in all currencies.

付款指令文件可从您的 ERP 系统上传到我们的电子银行系统来只是国内及对海外各种币种付款。