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Based on the physical meaning of each term in the linear parameter log I (a constant correlating the affinity of solut e t o stationary phase) of stoichiometric displacement model for retention o f solute, the thermodynamic characteristics of log I of solute in revers ed-phase liquid chromatography were investigated theoretically. This poi nt was tested by experimental data with two linear relationships:(1) plot of log I vs 1/T with apolar, polar small solut es and proteins;(2) plot of log I vs log Po/w (partition co effi cient of solute between n-octanol and water) with apolar and polar smal l solutes.

依据液相色谱中溶质计量置换保留模型及线性参数log I(与1 mol溶质对固定相的亲和势大小有关的常数),通过作图得知非极性和极性小分子溶质及生物大分子的log I与绝对温度的倒数1/T,以及小分子溶质的log I与其在正辛醇-水中分配系数的对数log Po/w呈线性关系,从两方面进一步证明了log I具有热力学平衡常数的性质。

The relation of the chromatographic retention indices of alkene to topological index,double bond atomic hybridization state index,polarizability effect index of branched chain to double bond atomic,immobile liquid polarity values and column temperatureat different temperatures on different stationary phases was studied.

通过对部分烯烃在不同固定相不同柱温下的1031个样本集的气相色谱保留指数值与其部分参数关系的研究,发现RI与拓扑指数、双键原子杂化状态指数、支链对双键的极化效应指数、固定液极性值及柱温的关系可表示为:^RI=-58.138+57.7460Q-8.2591Q+0.120T+0.807CP+36.460PBD+7.919DHSI(R=0.9989)继以留一法(Leave-one-out,LOO)进行交互检验,相关系数RCV=0.9977,说明所建模型具有良好的稳定性和预测能力,较好地揭示了烯烃类化合物气相色谱保留指数RI随固定相极性、柱温的改变而变化的规律

It includes the definition of two basic operations, logical functions expansion and matrix formulation in OR-Coincidence algebra system, and the introduction of map expression--dj map, the complete research of the relations among CRM expansion^ maxteim expansion and RM expansion, iiamely tie relations among dj map, K-map and bj map, also includes the minimization of CRM expansion in fixed and mixed polarities-Meanwhile this dissertation points out the form and properties of basic symmetric function, simple symmetric function and basic CRM symmetric function in OR-Coincidence algebra system, discusses the relations and transform methods among the coefficients of the three kinds of symmetric functions.

包括连和与加合两种基本运算的定义,逻辑函数在或、符合代数系统里的展开式及矩阵表示式,展开式图形表示--d_i图的引入,对CRM展开式和最大项展开式、RM展开式,d_i图和K图、b_i图之间的关系及转换方法进行了较为全面的研究,以及CRM展开式在固定极性和混合极性下的最小化问题。

The problem of slow TPH degradation found to be related to the polar fractions accumulation. Increase of fungi community diversity was found helpful in decomposition of the polar fractions. The symbiotic environment between bacteria and fungi was beneficial to the 2nd –stage TPH biodegradation.

至於各组降解迟滞的问题则与污染物三成份中极性物质的累积有关,在累积过程中真菌类多样性的增加,有助於极性物质的去除,最后细菌类与真菌类共生的环境能使污染物产生第二阶段的降解反应,因此污染物能持续降解。

For example ,the non- polar materials like hydrocarbons are heavy and draggy as compared to polar emollients,isoparaffins are light and smooth,the polar esters were significantly lighter and smoother,the branched chain and unsaturated esters were exceptionally light and smooth,in the case of straight chain esters,as the emollients become smoother and lighter ,the oiliness increases,in the case of unsaturated and branched chain esters,the emollient becomes lighter ,as well as less oily,when the alcohol chain length is decreased.

研究结果表明,物理化学特性明显影响润肤剂的轻柔感和油亮感,例如类似碳氢化合物的非极性物质相对于极性物质要粘稠些,异构烷烃则轻柔和光滑,带分支链的不饱和酯特别具有轻柔感和光滑感,带分支的不饱和酯相对直链饱和酯在油亮感方面有着特别的不同,直链酯随着产品光滑感和轻柔感的增加,油亮感也增加,对于带分支的不饱和酯而言,产品变得更轻柔,油亮感下降。

The Anthraquinone element in Morinda officinalis How aids in the proliferation of BMSCs regardless of the polarity of the compound. Though the other compounds of Morinda officinalis How has a certain impact on the proliferation of BMSCs as well, it is of no statistical values. However, the result will be better for the Anthraquinone in Butyl alcohol as the polarity is wider.

巴戟天中的蒽醌苷类成分对促进BMSCs的增殖有效,而其他成分对促进BMSCs的增殖有一定的影响,但无统计学意义;且巴戟天蒽醌苷类成分无论极性大小,对促进BMSCs的增殖都有效,而正丁醇中极性较大的蒽醌苷类成分效果更好一些。

A formula was derived and given to calculate the Shupe effect in the quadrupolar winding including the effects of the midpoint deviation and the fiber diameter. This formula, compared with that considering only the ideal situation, can not only be used to account the thermally induced nonreciprocal phase shift under different midpoint deviations and fiber diameters, but also indicate the effects of the fiber coil's structure when there exist nonideal factors.

本文分析了中点偏差、光纤直径尺寸对四极性绕法中相向传输光对称性的破坏,推导给出了包括中点偏差和光纤直径尺寸影响的四极性绕法热致非互易相移的计算公式,该公式相对于只考虑理想情况的计算公式,不仅能计算不同中点偏差和光纤直径情况下的热致非互易相移,而且揭示了存在非理想因素时,光纤环结构对热致非互易性的影响。

The frequency of particular amino acids in signal peptides by statistical approach was 48.54% for hydrophobic, 18.67% for uncharged, 24.54% for negative and 8.00% for positive amino acids. The most frequent amino acid was alanine, and the least was isoleucine. Three classes of signal peptides were found in the genome of P. syringae pv. tomato, 501 ORFs belong to secretary signal peptides, 36 ORFs belong to twin-arginine signal peptides, and 15 ORFs belong to lipoprotein signal peptides. Type IV pilin signal peptide and bacteriocins and pheronones signal peptide was not found in the genome.

同时,对组成信号肽的氨基酸种类作了系统的分析,发现组成信号肽的氨基酸中非极性氨基酸占48.54%,极性氨基酸占18.67%,带负电荷氨基酸占24.54%,带正电荷氨基酸仅占8.00%,出现最多的3种氨基酸依次为亮氨酸、丙氨酸和丝氨酸,最少的氨基酸是异亮氨酸,在切割位点-1端的氨基酸中83.21%均为丙氨酸,在切割位点后3位的氨基酸中最多的氨基酸也是丙氨酸。

The photoinduced cis-trans isomerization reaction occurs after photo-irradiation of this compound, and the rate of conversion depends strongly on the polarity of solvents used.

八 研究了C5位联有含氮茋的三芳基-2-吡唑啉化合物(TPP15)的光物理行为,发现:该化合物在不同极性溶剂中的荧光量子产率值呈倒钟形状,这与在不同极性溶剂中邻近效应的大小以及吡唑啉环和含氮芪基团间的电子转移的难易程度有关。

Such compositions comprise at least one textile-cleaning surfactant; droplets of miscible silicones comprising both a polarly-functionalized, preferably nitrogen-containing amino or ammonium functionalized, polysiloxane component and a nitrogen-free non-functionalized or non-polarly-functionalized polysiloxane component; and a perfume component comprising fragrant aldehydes and/or ketones or a pro-perfume capable of providing such aldheyde and/or ketone perfume materials in situ.

这些组合物包含至少一种纺织品清洁表面活性剂;可混溶硅氧烷液滴,所述可混溶硅氧烷液滴不仅包含极性官能化的聚硅氧烷组分,优选含氮的氨基或铵官能化的聚硅氧烷组分,而且还包含不含氮的非官能化的或非极性官能化的聚硅氧烷组分;和包含芳香醛和/或酮的香料组分或能够就地提供这些醛和/或酮香料物质的前香料。

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