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By comparing the influence of the solvent polarity, in the fluorescence experiment, for PTCP and PPCP, the bathochromic shifts are attributed to the locally excited process.

通过考察溶剂极性对该类D-π-A分子光物理性能(来源:A28BC论a5文网www.abclunwen.com)的影响,发现当共轭体系较小时,PTCP和PPCP发射的是本体荧光,即源于局部激发态LE态。

Whereas the absorption spectrum undergoes minor change with increasing polarity of the solvents, the fluorescence spectrum experiences a distinct bathochromic shift in the band position and the fluorescence quantum yield increases reaching a maximum before decrease with increasing the solvent polarity.

第三章:本章采用紫外可见和荧光分光光度法研究了一种新型的分子内电荷转移荧光探针1-酮-2--四氢萘在不同极性有机溶剂中的发光行为和光物理性质。

According to these reaction conditions, a low aqueous organic biphase system for the continuous production of Naproxen was developed.

反应在一个具有回路的连续流搅拌反应器中进行,反应器中添加有采用吸附法固定化的脂肪酶,载体为一种弱极性的合成载体,水相连同固定化酶颗粒一起永久保持在反应器中,有机流动相带入底物,带出产物。

Intraoperative injection of anhydrous alcohol in inoperable pancreatic cancer;2. The long term results of injection anhydrous alcohol to treat bromidrosis and its standard protocol;3. Accordingly, it becomes the best choice in the production of anhydrous alcohol .

分子筛的晶体结构不同于硅胶、活性炭等,具有高吸附性,对H2O ,NH3,H2S,CO2 等高极性分子具有很高的亲和力,在相对湿度小于30 %时,分子筛的吸水量比硅胶和氧化铝都高得多,用其生产无水酒精是最佳方案,工艺流程分为:(1)两塔蒸馏加分子筛;(2)分子筛处理后在蒸馏塔回收;(3)分子筛处理后送专用塔浓缩。

The modified QCM sensors were used to recognize the butylamine isomers in gas. The results showed that the QCM coated with both compounds had preferential affinity to n -butylamine, then i -butylamine, t -butylamine in the range of low concentrations, indicating that in the recognition process, the steric hindrance effect played an important role when forming complex with guest molecules.

修饰的QCM传感器用于识别气相中不同的丁胺异构体,结果发现,在小浓度范围之内上述两种化合物修饰的QCM均优先吸附正丁胺,之后依次为异丁胺和叔丁胺,表明在形成主客体化合物的识别过程中,空间位阻效应是一个重要因素;当分析物浓度增大时,丁胺的极性和磁性成为分子识别的主要因素。

The C3A spheroids displayed multilayer cell morphology, characterized by a large number of tight junctions, polar cells, and bile canaliculi, similar to spheroids of primary hepatocytes.

这个C3A球形体显示出多层细胞的形态学特征,包括有大量的紧密连接、极性细胞及胆小管,这与原代肝细胞球形体相似。

By the testing means of electron-spectroscopy for chemical analysis , thermogravimetric analysis , differential scanning calorimetry , transmission electronmicroscopy , the results have shown that the emulsion polymerization in situ in the presence of nano-particle of calcium carbonate can happen smoothly and successfully and the surface of nano-particle of calcium carbonate have been capsulated by polymer of acrylates, which prevent from the agglomerating of nano-particles of calcium carbonate. Because the copolymer of acrylate has good compatibility with some plastics such as PVC, ABS, AS and so on, so the dispersion of nano-scale calcium carbonate as nanometer size in these plastics can be reached more easily and the effects of nanometer can happen.

通过X射线光电子能谱、热失重分析、动态扫描量热分析、透射电子显微镜等手段,证实在纳米碳酸钙原生粒子存在下,可以进行丙烯酸酯类的原位乳液聚合,乳液聚合顺利,纳米碳酸钙表面被丙烯酸酯类聚合物所包覆,使纳米碳酸钙粒子间的团聚不易发生,同时由于丙烯酸酯类聚合物与PVC、ABS、AS等极性聚合物具有较好的相容性,从而使纳米碳酸钙在聚合物基体中能达到纳米状态分散,从而发挥纳米效应。

Carbonium ions in solution derive much of their stability from solvation effects and are formed more easily in more polar media.

正碳离子在溶液中由溶剂效应获得更高的稳定性,而且在极性较高的介质中更容易形成。

The research indicated that the main electric particles forming guiding discharge channel were the electrons released from the process of the breaking up of the negative ions. During 10 microseconds after the laser pulse, the electrode also could guide discharge effectively; and it suggested the new conception of the electrode erosion, and developed new-type running disk electrode, which could discharge for a million times in atmosphere. It also suggested methods of the texturing roller of besmearing with oil film and cathodal discharge in processing. The research of the texturing roller indicated that roughness of 14 microns and the intensified depth of over 200 microns could be got.

研究表明:形成诱导放电通道的带电粒子主要是负离子解离过程释放的电子,在激光脉冲结束后10微秒内,电极都能有效诱导放电;提出了电极损耗的新概念,并研制了新型转动圆盘电极,可在大气中完成上百万次放电,提出了加工过程中负极性放电、工件表面涂介质薄膜放电的毛化工艺方法;并用之对轧辊试件进行了毛化工艺研究,毛化粗糙度可达14微米,强化深度大于200微米。

In some plants, lycolipids constitute the major polar lipids in ceil membranes.

在有些植物中糖脂是细胞膜中主要的极性油脂。

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