板钛矿

In addition, the effects of transition-metal-doping and mixed crystalline effect are discussed in detail. Two worthy problems which are the photocatalytic activity of brookite and the Ti-doping TiO2 are put forward.

此外，本文对混晶效应和过渡金属离子掺杂的影响也作了较详细的探讨，提出了两个值得进一步深究的问题：板钛矿型TiO2的光催化活性以及Ti4+的掺杂。

We used ITO glass substrate and high purity（99.99%） titanium , put to use sputtering process, add to high purity O2 make it complete the best structure film and the thickness about 1400 . By way of 500℃ anneal could got a better anatase phase, this result could easy reaction with electrolyte to increase electron-transferred. Used as spin casting covering PR on ITO substrate, transferring patterns of array circular shapes on a mask to photography, used optimize temperature and time to hard bake. Finally used HCl to etching underexposed TiO2 area, and acetone to tripper top PR, make it to accomplish pillars shape TiO2 electrode.

本研究使用ITO玻璃基板为底材在以高纯度钛(99.99%)为靶材，利用溅镀方式通入纯氧使其行成高纯度TiO2镀於ITO基板上行成厚度约1400的薄膜，且经500℃高温烧结使其行成最强的锐钛矿结晶相，此晶相有利於与电解液反应进而增加电子的转移，提升太阳能电池最佳的效率，在以旋转涂布方式铺上光阻，以矩阵排列的圆孔光罩曝光、最佳的温度及时间来烘烤、显影后；使用盐酸以等向性湿蚀刻方式蚀刻未曝光之TiO2区域，最后利用鈵铜将最上层光阻去除，使其行成柱状TiO2的电极。

The results show that α-Al2O3 in the two kind s of coatings decreases while the γ-Al2O3 increases after spraying. Rutile-TiO2 transforms to brookite-TiO2 and the inners tress of coating was increased so as to aggravate the expansion of cracking. The pores are small but dense in the conventional coating while bigger but loose in the nano-structured coating. The pores in the nano-structured coating exist almost inside the partially melted region. The pores generated during spraying and the cracks generated during the course of thermal oxidization because of thermal stress are the direct reasons why coatings fail.

结果表明：2种粉末在喷涂之后，涂层中的α-A12O3均有所减少，生成了γ-Al2O3，金红石TiO2相转变成了板钛矿型TiO2相，增加了涂层的内应力，加剧了裂纹的扩展；常规微米涂层中的孔洞细小但密集，纳米涂层中的孔洞较大但不密集，且大部分的气孔都存在于部分熔化区的内部；涂层在喷涂过程中所生成的气孔以及热氧化过程中由于热应力而产生的裂纹是造成涂层失效的直接原因。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。