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松香酸

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A new method for synthesizing rosin allyl alcohol ester was studied. p-Toluenesulfonic acid allyl alcohol ester was first synthesized by O-acylation of allyl alcohol with p-toluene sulfonyl chloride, using NaOH as catalyst. Then rosin allyl alcohol ester was synthesized from sodium resinate and p-toluenesulfonic acid allyl alcohol ester.

探索了一种两步合成松香烯丙醇酯的新方法,即先以烯丙醇和时甲苯磺酰氯为原料,以NaOH为催化剂,通过O-酰化反应合成中间体对甲笨磺酸烯丙醇酯,再与松香钠皂发生亲核取代反应合成目标产物松香烯丙醇酯。

Polymerized rosin is a modified products of gum rosin, contains abietic type acids.

聚合松香是松香的改性产品,含枞酸型树脂二聚体。

Thecompositions of raw material and products were identified with GC-MS, the results indicatedthat the products were composed of (β-acryloxyl ethyl) esters of dihydropimaric acid anddehydrogenated abietic acid, and their relative amounts was consistent with the amount ofdihydropimaric acid and dehydrogenated abietic acid in the disproportionated rosin.

论文还采用GC-MS对原料和产物的组分进行了鉴别,结果表明酯化产物由二氢海松酸酯和脱氢枞酸酯组成,且其相对含量与歧化松香中二氢海松酸和脱氢枞酸组成基本一致。

In this paper,firstly a series of acryloxyl derivatives were synthesized from the dehydrogenated abietic acid,a main composition of disproportionated rosin, through acyl chloridation and esterification.The derivatives included the (β-acryloxyl ethyl) esters of dehydrogenated abietie acid,(β-methacryloxyl ethyl) esters of dehydrogenated abietic acid and (β-methacryloxyl propyl)esters of dehydrogenated abietic acid.

论文首先以歧化松香中的主要成分脱氢枞酸为模型化合物,采用酰氯化、酯化手段合成了它的一系列丙烯酰氧基衍生物,包括脱氢枞酸酯、脱氢枞酸(β-甲基丙烯酰氧基乙基)酯和脱氢枞酸(β-甲基丙烯酰氧基丙基)酯。

The sodium sulphonate of ethoxylated acrylic modified rosin can be obtained from acrylic modified rosin after the reaction with ethylene oxide and then be sulphonated with chlorosulphonic acid.

以松香为原料,用丙烯酸进行改性后再与环氧乙烷聚合,然后用氯磺酸进行磺化处理制得丙烯酸改性松香聚氧乙烯醚磺酸钠阴离子表面活性剂。

Effects of the amount of fumaric acid, temperature and reaction time on the reaction were investigated. Fumaropimaric acid was purified by potassium-salt method.

分别考察了富马酸加入量、反应温度及反应时间时富马松香制备的影响,并使用钾盐法对制备的富马松香进行纯化得到富马海松酸。

As results, the contents of three original pimaric-type resin acids, namely pimaric, isopimaric and sandaracopimaric acids, generally decreased, the higher the initial content with the higher the temperature and longer time, the faster the content declined.

结果表明,脂松香中原有的3种海松酸型树脂酸即海松酸、异海松酸、山达海松酸的含量总体呈下降趋势,初始含量越高、热处理温度越高、时间越长,其含量下降幅度越大。

The morphological variation characteristics of resin acid ,as well as titration correction of the unsaponifiable matter during rosin saponification were discussed theoretically.

研究了在脂松香分析测定过程中影响松香不皂化物含量测定的关键因素及其影响机理,讨论了树脂酸在皂化过程中的形态变化特征及其导致不皂化物需要进行树脂酸校正操作和计算的理论依据。

The gas chromatography quantitative analysis conditions of gum rosin were studied by selection of chromatographic columns and chromatographic resolution conditions with the pure rosin sample of P.

用纯思茅松松香样品,通过选择色谱柱和色谱分离条件,研究确定了脂松香气相色谱定量分析的条件,定量分析了松香树脂酸的相对百分含量;定量分析数据通过统计学中的Grubb′s检验法进行误差检验,在确定的条件下脂松香气相色谱定量分析结果具有稳定性、准确性和复现性结果;对马尾松、湿地松松香定量分析也取得同样结果。

The main component dehydroabietic acid and little component abietic acid, neoabietic acid, levopimaric acid and pulustic acid of a few types disproportionated rosin were determinated quantitatively by selecting the proper order of derivative, differential wavelength difference, scanning rate and quantitative method.

通过选择合适的求导阶数、微分波长差、扫描速度和定量方法,对不同批号的歧化松香中的主成分脱氢枞酸和微量组分枞酸、新枞酸、左旋海松酸及长叶松酸进行了测定(其中左旋海松酸和长叶松酸测定的是合量),实验结果令人满意。

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