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松香酸

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The developing principle of MB gypsum fine foamer which takes compound honey-locust abietic acid anionic surfactant as principal composition,is analyzed in theory.

从理论上分析了以复合型皂角松香酸类阴离子表面活性剂为主要成分的MB石膏微发泡剂的研制原理,详细研究了MB微发泡剂在石膏料浆中的起泡条件、起泡性能及其对硬化后的建筑石膏物理力学性能的影响,MB微发泡剂与现有发泡剂的性能比较,MB微发泡剂在纸面石膏板中的应

Part III, 12-benzyl dehydroabietyl thioisocyanate was synthesized from methyl 12-benzyl dehydroabietic acid, by hydrolysis, chloride, Curtius reaction to give isocyanate which was hydr- olysied to amine under acidic condition, and with the method of CS2 at last, the maximal excitat- ion wavelength was bathochromic shifted 14nm compared to DDHA-NCS.

第三部分,从12-苯甲酰基脱氢松香酸甲酯出发,经过水解,酰氯化、Curtius reaction得到异氰酸酯,在酸性条件下水解成胺,最后由二硫化碳法得到一种新的荧光衍生试剂12-苯甲酰基脱氢松香酸异硫氰酸甲酯,与DDHA-NCS相比,最大激发波长红移了14nm。

DFA-PEG polyester was synthesized with DFA and PEG 400 at first, and then bysulfating DFA-PEG polyester with NH_2SO_3H or terminating DFA-EG polyester withrosin acid, two derivant, these are sulfated DFA-PEG polyester and terminateDFA-PEG polyester, were synthesized. The reaction conditions of synthesis wereoptimized by orthogonal experiments.The molecular weight of product was analyzed by GPC.

5以二聚脂肪酸和聚乙二醇400为原料,首先合成了DFA-PEG聚酯,再以DFA-PEG聚酯为衍生体,硫酸化或用松香封端,合成了两种DFA-PEG聚酯衍生物——DFA-PEG聚酯硫酸酯盐和松香酸封端DFA-PEG聚酯,通过正交试验,对合成的条件进行了优化。

Twenty-seven compounds were isolated from the methanol extract of the stems of Pinus massoniana by means of chromatographic methods, and their structures were elucidated as 8(14),15-Pimaradien-19-oic acid (1), Pimaric (2), Podocarpic acid (3), 12-Hydroxydehydroabietic acid (4), Dehydroabietic acid (5), 15-Hydroxydehydroabietic (6), 3β-Methoxyserrat-14-en-21-one (7), 3β-Hydroxy- serrat- 14-en-21-one (8), 3β-Methoxyserrat-14-en-21-one-30-al (9),(24R)-Stigmst- 4-ene-3-one (10),β-sitosterol (11),-3-Hydroxy-5-methoxy-stilbene(12), 4-Hydroxy-3- methoxycinnamaldehyde (13),-Ferulic acidtetracosyl ester (14), Alkylferulates (15), Pinocembin (16), Coniferaldehyde (17), Matairesinol (18),-Nortrachelogenin (19), Balanophonin (20), Cedrusin (21),-Pinoresinol (22), Tanegoside (23), 1,2-Bis-(4-hydroxy-3- methoxyphenyl)-propane-1,3-diol (24),(1S*, 2S*)-1-(4- Hydroxyphenyl) glyceri...

同时对马尾松枝条的甲醇提取物利用各种色谱技术进行了分离纯化,并利用现波谱技术鉴定了27个化合物的结构,分别为:8(14),15-Pimaradien-19-oic acid (1)、海松酸(2)、罗汉松酸(3)、12-羟基脱氢松香酸(4)、脱氢松香酸(5)、15-羟基-脱氢松香酯(6)、3β-甲氧基-锯齿石松-14-烯-21-酮(7)、3β-Hydroxyserrat-14-en-21-one (8)、3β-Methoxyserrat-14-en-21– one-30-al (9)、(24R)-豆甾-4-烯-3-酮(10)、-3-羟基-5-甲氧基-二苯乙烯(12)、4-Hydroxy-3-methoxycinnamaldehyde (13)、-Ferulic acidtetracosyl ester (14)、Alkylferulates (15)、Pinocembin (16)、Coniferaldehyde (17)、罗汉松树脂酚(18)、 Balanophonin (20)、tanegoside (23)、1,2-Bis-(4-hydroxy- 3-methoxyphenyl)-propane- 1,3-diol (24)、(1S*,2S*)- 1-(4-hydroxyphenyl)glycerins (25)、(1R*,2R*)-1-(4-hydroxy- phenyl)gly-cerins (26)和赤松素(27)。

The combined acids , LHZZS,XDZZS and SLZZS, one of four fractions in montan resins from montan waxes from Liaohu, Xundian and Shulan brown coal respectively, were derived by CH 2N 2 to methyl esters and their chemical constituents and structural characteristic were studied on GC-MS.

结果显示,树脂结合酸均以正构烷酸为主要成份,其分布为C1 2 ~C2 8,高含量的正构烷酸集中在低碳数一端,C2 0 含量最高,其次为C1 6 ,而舒兰结合酸中,正构烷酸占绝对优势,且C1 6 为最高含量的化合物;去氢松香酸在每一个样品中含量较低,其它三环二萜酸,如松脂酸、三达松脂酸等异构体或立体异构体含量也非常低;具有五环三萜骨架的酸性物质,在潦浒、舒兰结合酸中比较丰富,其含量超过寻甸结合酸;在低碳数一端,存在着各种支链烷酸及苯甲酸、苯酚及取代物。

To study the relationship between the "tail" structure and the characteristics of Gemini surfactants, a new gemini surfactant CH(subscript 2s)-αω-Bis (dehydroabietyihydroxypropyltetramethylethyldiammonium Chloride) here s=2, has been synthesized. Dehydrogenated rosin as hydrophobic "tails" in the structure. The affections of reacttants ratio, reaction temperature and time on the yield of aimed compound have been discussed.

研究了Gemini表面活性剂中疏水&尾巴&结构对性质的影响,以脱氢松香酸和环氧氯丙烷为原料合成了中间体3-脱氢松香酰氧-2-羟丙基氯,再与四甲基乙二胺反应,得到1种以脱氢松香酰基为疏水链&尾巴&的对称Gemini型双季铵盐阳离子表面活性剂:二氯化-N,N'-二(3-脱氢松香酰氧-2-羟丙基)四甲基乙二胺。

To study the relationship between the hydrophobic "tail" structure and thecharacterizations of Gemini surfactants, a new gemini surfactant CsH2s-α,ω-bis(dehydroabietylhydroxypropylteteramethylethylammonium Chloride),here s=2, wassynthesized. Dehydrogenated rosin as hydrophobic "tails" in the structure. The impact factorsin the two steps are discussed.

为研究gemini表面活性剂中疏水&尾巴&结构对性质的影响,本论文以脱氢松香酸和环氧氯丙烷为原料合成了中间体3-脱氢松香酰氧-2-羟丙基氯,再与四甲基乙二胺反应,得到一种以脱氢松香酰基为疏水链&尾巴&的对称gemini型双季铵盐阳离子表面活性剂:二氯化-N,N′-二(3-脱氢松香酰氧-2-羟丙基)四甲基乙二胺。

Part I, the Friedel-Crafts acylation on DAA and methyl dehydroabietic acid was carried out with acetyl chloride, benzoyl chloride or phthalic anhydride as acylating regents, anh- ydrous aluminum chloride as catalyst and with different solvents to compare with, we have got t- hree new compounds.

第一部分,分别以脱氢松香酸和脱氢松香酸甲酯为底物,乙酰氯、苯甲酰氯、邻苯二甲酸酐为酰化试剂,无水三氯化铝作催化剂,采用不同的溶剂及反应条件进行傅克酰基化反应,得到3个新化合物。

That polyring aromatised hydrocarbons, dehydroabietic acid, other tricyclic diterpanoic acids and pentacyclic triterpanoic acids are not existed or in a much low amount in Zhaotong brown coal resin is distinguished from those resins isolated in Xundian, Liaohu, Shulan brown coal waxes in China.

稠环芳烃、松香酸、去氢松香等环状化合物含量很低或不存在,是昭通褐煤蜡与国内其它褐煤蜡组成的重大差别。

The oxidations of-abietic acid by 〓,〓 and 〓 under various reaction conditions and its addition reaction withdichlorocarbene were investigated.

本文首先从广西产松香中分离纯化得到松香酸,然后探讨了不同条件下〓等氧化剂对其共轭双键的氧化反应以及二氧卡宾对其共轭双键的加成反应。

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起初我只晓得布鲁克雷德丝是美国少男少女崇拜的偶像,后来回台湾,甚至去年在北京,居然也四处看见她的海报,才惊讶她的魅力之大。

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