杂原子

Generally speaking, the reaction types involvingα-oxoketene--acetals mainly include the regioselective addition-aromatization with organometallic reagents, conjugate addition-cyclization with nitrogen nucleophilicspecies, nucleophilic reactions ofα-carbon, acting as odorless dithiol equivalentsin thioacetalization, Michael additions and [5+1] annulation, as well as the synthetic applications based on the above reactions.

一般来说，基于α-羰基二硫缩烯酮化学的反应主要为：与金属有机试剂的选择性加成反应，与氮亲核体的共轭加成反应，α-碳原子的亲核性及相关反应，烷硫基作为硫醇的替代试剂的应用，α-羰基二硫缩烯酮在碳环、杂环化合物合成中的应用等。

It is shown that, as a result of the interstitial impurities, the number of atomic states increases, bond structures become seriously anisotropic,β→α transformation becomes hindered, and the phase transformation in the intermediate content becomes very complex.

表明，间隙杂质提高了合金元素的原子杂阶，引起键结构呈严重的各向异性，阻碍了β→α相转变，导致中间成分相变的复杂性。

The relation of the chromatographic retention indices of alkene to topological index,double bond atomic hybridization state index,polarizability effect index of branched chain to double bond atomic,immobile liquid polarity values and column temperatureat different temperatures on different stationary phases was studied.

通过对部分烯烃在不同固定相不同柱温下的1031个样本集的气相色谱保留指数值与其部分参数关系的研究，发现RI与拓扑指数、双键原子杂化状态指数、支链对双键的极化效应指数、固定液极性值及柱温的关系可表示为：^RI=-58.138+57.7460Q-8.2591Q+0.120T+0.807CP+36.460PBD+7.919DHSI(R=0.9989)继以留一法(Leave-one-out，LOO)进行交互检验，相关系数RCV=0.9977，说明所建模型具有良好的稳定性和预测能力，较好地揭示了烯烃类化合物气相色谱保留指数RI随固定相极性、柱温的改变而变化的规律

A large number of bond-type complexes, as long as the hydrogen of the molecules covalently coupled to the molecular approach in an electronegative atom up, that constitutes a hydrogen bond, there are intramolecular hydrogen bonds and intermolecular hydrogen bonds of the points, will affect the formation of complex reaction carried out, such as in solution adding dioxa cyclohexane, or tetrahydrofuran, will reduce the alkylation reaction rate.

氢键型络合物为数众多，只要含氢的分子以共价键方式耦合到分子中一个电负性原子上去，即构成氢键，有分子内氢键和分子间氢键之分，络合物的形成将会影响反应的进行，如在溶液中加入二氧杂环己烷或四氢呋喃，都会降低烷基化反应速率。

And the Randic-Kier index,χ, is defined as,χ=∑C, whereC, and δ is the calculated valence delta for the carbon atom or heteroatom.

上标 mχ定义为χ∑C，子图项，δ为碳原子或杂原子价点价。

The luminescent property of these materials was relative to the twisted angle between two benzene rings of the bridged biphenyl. The crystal structures of a series of seven-member heterocycle bridged biphenyls were determined by X-ray diffraction.

利用X射线单晶衍射仪确定了系列功能的七元杂环桥联联苯化合物的晶体结构，比较了桥联原子，6，6位取代基及分子间弱氢键对这类桥联联苯扭曲构象的影响。

It is the hotspot research in the field of synthesis of functional macromolecule materials at present.

利用咪唑啉含有两个氮原子的五元杂环化合物特殊结构，在其合成过程中对官能团"枝接"其他功能基团，使之成为具有特殊功能的化学品，是目前国际上合成功能高分子材料研究的热点。

The effect of hybridization between N-2p and Fe-3dwave functions,and of lattice expansion on the magnetic moment of Fewas discussed.

主要讨论N-2p和Fe-3d波函数之间的杂化以及晶格伸长对Fe原子磁矩的影响。

Chemical bonds and structural theory of organic chemistry 6 class hoursKnow the history of organic chemistry; Grasp the basic theory of organicchemistry, such as structural theory, chemical bonds, resonance theory, atomic andmolecular orbital theory, and valence bond theory; understand polar and non-polarcompounds, dipole moment and know how to express the structures of organiccompounds with different molecular formulas.

了解有机化学发展简史；掌握有机化学结构理论、化学键理论、共振理论、原子和分子轨道理论和杂化轨道理论；了解极性和非极性分子并掌握有机化合物结构的表示法。

Numerous examples illustrating a wide variety of physical phenomena such as magnetism, polyatomic gases, thermal radiation, electrons in solids, and noise in electronic devices.

并举了大量的例子来说明各种各样的物理现象：如磁力，多原子气体，热辐射，固体中的电子，电子设备中的杂讯。

The labia have now been sutured together almost completely.The drains and the Foley catheter come out at the top.

此刻阴唇已经几乎完全的缝在一起了，排除多余淤血体液的管子和Foley导管从顶端冒出来。

To get the business done, I suggest we split the difference in price.

为了做成这笔生意，我建议我们在价格上大家各让一半。