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This thesis demonstrates the pre-polymers in a polymer-dispersed cholesteric liquid crystals can be polymerized into a polymer film, which can eliminate the aligning capability of the homogeneous alignment layer. Thereafter, the textures of the cholesteric liquid crystals in UV-cured region can be changed from reflective planar texture to the scattered focal conic one. Additionally, the clearing temperature of the liquid crystals can be reduced by doping with chiral dopant or monomers. The cause is the increase of the impurity concentration in LCs. In other words, if the monomers are polymerized, the clearing temperature of LCs in that region should increase due to the decrease of the impurity concentration. Therefore, impurities associated with doping with monomeric and chiral dopants cause the clearing temperature of LCs in cured region to differ from that in uncured region.

本文中,我们提出在高分子聚合物薄膜之胆固醇液晶(polymer-dispersed cholesteric liquid crystals,简称PDCLCs)中,利用紫外光使PDCLC中的单体聚合成薄膜,此即为光引致聚合反应,而该薄膜将原本在表面所作的配向膜覆盖且破坏其配向能力,使胆固醇液晶由原本反射的planar结构转换成散射的focal conic结构;另外,有关液晶材料的相变温度会由於掺杂手性分子或单体而降低,此因液晶材料内『杂质』浓度增加,而造成的液晶材料之不纯度增加,最终导致相变温度降低,若搭配上述光引致聚合反应,则由於光照区之单体聚合,使该区域单体占总材料之比例下降,即不纯度降低,进而使液晶材料之相变温度上升,该区域之相变温度与未照光区有所不同。

The results indicate that rare earth cerium ion dopants do not affect the structure of the material but considerably improves its capacity delivery and cycle performance, which is ascribed to the enhancement of the electronic inductivity and reducing crystal size to nanoscale by ion doping.

研究表明,少量Ce3+的掺杂未影响到LiFePO4的晶体结构,但显著改变了粉体的微观形貌,降低颗粒粒径至纳米级,改善了可逆容量和循环性能。得到的最佳配比正极材料Li0.9975Ce0.0025FePO4,在0.1C的充放电速率下,其初始可逆放电容量达到116 mAh/g。

The study of vertical channel with high field effect mobility by Ni induced lateral crystallization, which can form larger grains on channel regions and reduce grain boundary defects. We detect the method of Ni induced lateral crystallization through high field effective mobility, but that accumulates too much Ni on floating N+ region and causes defects and metal contamination. As Ni is used to form silicde and then proceed to low temperature annealing, we can observe the floating region that has no Ni acumination regions or contaminations. This aids us in obtaining good electronic performance of this device, not only the remote field effective mobility but also the vast improvement of sub-threshold swing and on/off currents.

接著,是延续垂直通道的研究,希望能有效的提升电子迁移率,因此以镍金属诱导横向结晶的方式使通道形成较大的结晶,减少矽晶粒之间的缺陷,而在初步的研究,发现以镍金属直接诱导横向结晶的方式,经由低温长时间回火之后,由於镍金属扩散的关系,完成诱导结晶之后,有过多的镍金属聚集在顶部参杂的中间区域,而造成过多的缺陷累积,虽然电子迁移率有效的提升,但整体的电性并不如预期,因此提出先形成镍金属矽化物后,将未反应的镍金属或金属氧化物去除之后,再进行镍金属矽化物诱导横向结晶处理,经由结果观察得知在顶部掺杂区域部分没有明显的镍金属累积或污染,并且得到很好的整体电性,除了电子迁移率有效提升之外,次临界特性以及导通电流都能有效改善。

The results indicate that Zr-doping materials have better electrochemical performance and weaker electrode polarization and no passivating film can be found over the electrode, and among which the sample with the Zr∶Ti=1∶10 is the best.

实验结果表明:锆的掺杂在一定程度上改善了锂钛氧化合物的电化学性能,降低了电极极化,在电极表面未形成钝化膜。

Simultaneously, the exports of ionization rate and nonionzed concentration are set up as a powerful tool for studying thoroughly the freeze-out effect. dN〓/dp and dN〓/dn are neglected in the linearized equation system of the iteration methods of Newton and Gummel, due to having lower 15 orders or more than dN〓/dn and dN〓/dp, thus the computing effort is cut down with no effect on precision. A new cut-off technique is adopted to accelerate the convergence speed, about twice reduced for Newton iteration method and six times or so for Gummel iteration method. The approximate formulae of Fermi-Dirac statistics are also put forward with simpler form and higher precision. 3. A term dependent on time is added to the electron and hole current succession equations respectively. It is only this model that conservation of charge in transient analysis and alternating small-signal analysis at low temperature can be kept by. 4. The performance of SE-PISCES is explained by the simulation example of PISCES-2B, diode.

研究了低温半导体器件模拟的数值方法:对载流子浓度进行了新的归一化;编制了不考虑掺杂所引进的内建电场时的电离率计算程序;由于低温杂质电离率随偏压状态而变化,为此编制了每次求解迭代时的电离浓度计算程序,并将其插入到求解迭代程序中;同时,设置了杂质电离率和未电离杂质浓度的出口点,为更深入地研究冻析效应提供了有力工具;在Newton迭代法和Gummel迭代法的线性化方程组中忽略了dN〓/dp、dN〓/dn,是因为它们比dN〓/dn、dN〓/dp低15个数量级以上,这样减小了计算量又不影响模拟精度;对Newton迭代法和Gummel迭代法采取了新的截断技术,提高了收敛速度,Newton法迭代法和两次左右,Gummel法减少六次左右;给出了表达式更简单而精度更高的Fermi-Dirac积分近似计算公式。

The grain shape of in-situ polymerization PAN in 10 T is open-ramified rod-like pattern with the diameter of 50nm and that of sccondary doped PAN in 10T change to spherical structure about 20-30nm, which are obvious differcnt from irrcgular reef-like particle shape of doped PAN in 0 T.

强磁场作用下的原位聚合聚苯胺颗粒呈现大约50nm的棒状,而对本征态聚苯胺在强磁场下再掺杂得到20~30nm的球状颗粒,与未加强磁场作用下的礁石状颗粒有明显区别。

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With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务,乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐,因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。

Closes the eye, the deep breathing, all no longer are the dreams as if......

关闭眼睛,深呼吸,一切不再是梦想,犹如。。。。。。