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The results showed that (1) The grain size of nanometer YiO_2 was40~80nm.The wavelength corresponding to the maximum absorbency values were observedin the 200~320nm range.The crystal structure of carbon doped TiO_2 photocatalyst is primarilyanatase(22.43% rutile), and the content of carbon is about 4.6%.(2) The relative humidityvaring from 8% to 80%, the photocatalytic degradation degree of benzene increased withincreasing relative humidity; and to toluene, degradation rate was hanced by relative humidityup to 60%, and more or less inhibited above 60%.(3) Scheme and results of orthogonal testswere used by evaluating the photocatalytic performance of the gas phase methanol, acetoneand 1-heptane.The results revealed that their degradation degree reached 84.5%, 93.39% and93.45%, respectively.(4) The 254nm UV lamp showed higher photocatalytic degradation rate.For methanol, acetone and 1-heptane, it was found that photocatalytic degradation reactionoccurs with the light strength of daylight lamp.(5) Under the the same conditions, 15%degradation degree has been obtained for benzene, whilst about 10% degradation degree wasattained by Degussa P25; During the initial phases, the toluene revealed higher photocatalyticactivity, comparing with Degussa P25, the degradation degree of methanol, acetone and1-heptane were slightly lower.

结果表明:(1)CVD法制备的纳米TiO_2光催化剂,颗粒球形度好、粒径在40~80nm之间;最大吸光度值所对应的波长为200~320nm;含碳量约为4.6%;晶型组成主要为锐钛矿型,金红石的含量约为22.43%;(2)在相对湿度为8%~80%范围内,苯的光催化降解率随着相对湿度的增大而增大;甲苯在相对湿度为60%时达到最好降解效果,当相对湿度增大到80%时光催化效果降低;(3)将正交实验设计及实验方案应用于气相甲醇、丙酮和正庚烷光催化降解研究,实验结果表明:三者最高降解率分别为84.5%、93.39%和93.45%;(4)有254nm紫外灯参与的光催化实验可以大大提高有机气体的光催化降解率;在日光灯的照射下,掺碳纳米TiO_2对气相甲醇、丙酮和正庚烷具有一定的光催化氧化能力;(5)较P25粉,在相同的光催化操作条件下:气相苯的平均降解率达15%,高于P25粉10%的降解率;气相甲苯在初始阶段具有较高的反应速率;气相甲醇、丙酮和正庚烷的降解率略低于P25粉。

Doped AgBr emulsion had an optimal amount with AgBr to silver stearate of 1∶4 in PTG materials.

由Zou以及Sahyun[1]等人在早期报道的,粘合剂采用溶剂型聚乙烯醇缩丁醛,卤化银采用原位法合成时的PTG材料的化学增感无效,照相速度的提高总伴随着灰雾的增加;他们认为当卤化银颗粒与羧酸银有界面存在时,传统化学增感的效果不明显;由Yamane[2]等人于近期报道的

This paper introduces the studies of Gerhard Ertl, who is awarded the Nobel Prize in Chemistry 2007, in adsorption of hydrogen on metal surfaces, the mechanism of catalytic reaction in Haber- Bosch process for synthesis of ammonia, and the process of catalytic oxidation of CO.

格哈德·埃特尔的重要贡献主要有3方面:(1)解决了氢原子是如何在Pd、Pt和Ni等金属表面组织排列的问题;(2)对哈伯一博施法合成氨反应催化机理的研究;(3)对C催化氧化的研究及非线性动力学理论的建立。1 氢在金属表面吸附的研究萨巴蒂埃因发现精细金属颗粒催化有机物加氢的方法而获1912年度诺贝尔化学奖。

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