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In this paper, a series of 4,5-dithiacrown ether annulated 1,3-dithiole-2-thiones 8a~8d were prepared via condensing 4,5-bis-1,3-dithiole-2-thione (7) with 1,ω-dimercapto polyglycol derivatives in high dilution. The obvious template effect was found during the synthesis of 8c-8d.

在高度稀释条件下,经4,5-二溴甲基-1,3-二硫杂环戊烯-2-硫酮(7)和多缩乙二醇的1,ω-二巯基衍生物的缩合反应,方便地合成了4,5-位带二硫杂冠醚残基的2-硫代-1,3-二硫杂环戊烯的衍生物8a~8d,中间体硫杂冠醚8c~8d的合成中有明显的&模板效应&。

In this paper, a series of 4,5-dithiacrown ether annulated 1,3-dithiole-2-thiones 8a~8d were prepared via condensing 4,5-bis-1,3-dithiole-2-thione (7) with 1,ω-dimercapto polyglycol derivatives in high dilution. The obvious template effect was found during the synthesis of 8c-8d.

在高度稀释条件下,经4,5-二溴甲基-1,3-二硫杂环戊烯-2-硫酮(7)和多缩乙二醇的1,ω-二巰基衍生物的缩合反应,方便地合成了4,5-位带二硫杂冠醚残基的2-硫代-1,3-二硫杂环戊烯的衍生物8a~8d,中间体硫杂冠醚8c~8d的合成中有明显的&模板效应&。

Our idea of easy dimensional driving includes mainiy:(1) a driving mechanism of construction constraints and dimensional constraints,(2) automatic graphic recognition of constraints,(3) a bothway cross dimensional linked list for storing dimension sparse matrices and for recalling them,(4) a reasonable method of constraint consistence checking,(5) the linking of movement of 2D views,(6) a method for creating a sequence graphic library.

随着二维与三维设计技术的交叉发展,目前的参数化设计主要有两个分支:①面向纯二维的图形参数化,其特点是二维图形为多拓扑环的复杂图形;②面向三维的基于CSG特征造型的参数化,用于拉伸扫描的单拓扑环的二维图形参数化及空间任意曲面的参数化是其特点。

For example, to CaSiO〓, wallastonite and cyclowallastonite could be found simultaneously in glazes between the temperature range of 1125℃±10℃, only wallastonite came out below the range, and only cyclowallastonite appeared above the range. Similarly, melilite structure and clinopyroxene structure connected with crystallization temperature. Usually, higher crystallization temperature contributes to forming melilite with simple structure and lower crystallization temperature contributes to clinopyroxene with complex structure.

如钙的偏硅酸盐,硅灰石、环硅灰石的转变温度区域为1125℃±10℃,组分适当的特定釉熔体,高于此温度出现环硅灰石,低于此温度出现硅灰石晶体结构;同样的,黄长石、辉石的出现也与温度有密切的联系,通常,晶体生长的温度较高有利于晶体结构简单的黄长石出现,晶体生长时温度较低有利于稍复杂的辉石结构的出现。

EM analysis the worn surface morphology shows the following results: elastic deformation and fatigue are the main wear mechanisms of SMCC when impacted with lower erodent velocity, while the dominant mechanisms change into microcutting and microploughing with the increment erodent velocity.The slurry erosion behaviors of ceramic particles reinforced epoxy matrix composite coating were explored using a self-designed slurry pot tester.

首次采用自制的模拟罐式泥浆冲蚀试验机对环氧基复合涂料的泥浆冲蚀磨损性能进行了研究,通过调整固化剂聚酰胺与环氧的质量比,设计出最佳的基体组成;尽管涂层的铅笔硬度对其抗冲蚀性能有一定的影响,但起决定性作用的因素是涂层的韧性和硬度有机结合。

The macrocyclic polyamines are a kind of excellent ligands and have a substantially high binding affinity with transition metal ions. Macrocyclic polyamine metal complexes as enzyme models are widely used in chemical biology, medicine and gene therapy. 1, 4, 7, 10-tetrazacyclododecane is a representative macrocyclic polyamines compound and shows high binding affinity with transition metal ions, such as Zn, Cu and Co. Their metal complexes especially multinuclear complexes were widely used in DNA, RNA recognition.

大环多胺化合物是一类性质独特的优秀配体,具有良好的金属配位能力,其金属配合物作为人工酶模型广泛应用于核酸结构及功能研究、基因表达与调控、抗癌药物的研制等生物、化学和医学领域。1,4,7,10-四氮杂十二烷是典型的大环多胺化合物,对过渡金属离子Zn, Cu and Co有良好的配位能力,这些金属配合物特别是多核金属配合物被广泛应用于DNA识别中。

The experimental data demonstrated that there was a nasalward directional preference in oath OKN system under both close loop and open loop conditions, and the nasalward OKN gain evoked by stimulation of nasal retina was much higher than that at temporal retina. ms indicates that OKN nasalward preference is mairily derived from the nasal retina, i. e. the direct path1Vay of OKN dominates the indirect pathway in cat's OKN system. The gains of temporalward and nasalward OKN from temporal retina are much less than those of nasalward OKN from nasal retina. It is suggested that the indirect pathway of OKN in the cat only possesses a supplementary function, Which probably plays an important role in temporalward OKN eye-movments in relation to binocular vision.

实验结果显示:高速度刺激的闭环OKN反应及开环OKN反应均对鼻向运动刺激有明显的方向选择性;半侧视网膜刺激时,鼻侧半视网膜的鼻向OKN增益明显高于颞侧半视网膜的鼻向增益,说明猫的OKN眼动反应以跟踪鼻向运动为主,并且这种对鼻向运动刺激的选择性主要来源于鼻侧半视网膜,亦即来源于OKN直接通路;颞侧半视网膜的鼻、颞向眼动增益均明显低于鼻侧半视网膜的鼻向眼动增益,说明猫的OKN系统的间接通路在OKN眼动控制中起辅助作用,并可能主要对颞向OKN眼动起作用从而与双眼视觉功能相关。

The pieces that lend Stonehenge its distinctive look are remarkable: in their unruined positioning, a horseshoe of five gigantic trilithons surrounded by an immense and precise raised circle of sandstone markers, with the famous Heel stone at the axis point.

构成巨石阵特殊风貌的遗迹有几个著名的部分:在尚存的遗迹中,五个巨大的三石塔围成马蹄形状,外面环绕着由砂岩排成的巨大而精确的圆环。圆环的轴心线顶端还有一块著名的踵形石。

It is found that compared with the untreated glass fiber reinforced unsaturated polyester, the fluoridized FRP"s property of anti-water and anti infirm-acid has enhanced, while theproperty of anti- strong acid, anti-strong alkali and anti-organic solvent hasn"t changed much.The property of anti-acid and anti-alkali of the glass fiber reinforced epoxy resin fluoridizedby 3-(1H, 1H, 5H-Octafluoropentyloxy)-1, 2-Propenoxide has a corresponding increase, but theproperty of anti-organic solvent hasnt changed much.

研究发现,经G-02、G-04处理后的聚酯玻璃钢的与未处理的聚酯玻璃钢相比,其耐水性增强,耐弱酸性也有所增强,但耐强酸性、耐碱性、耐有机溶剂的腐蚀性变化不大;而经环氧丙基八氟戊醚处理后的环氧玻璃钢其耐酸耐碱性都有相应的增强,但是其耐有机溶剂的腐蚀性无太大变化。

Olympic ensign, is white the bottom be limitless, central have 5 a set mutually connect of circle wreath, the color of wreath from left go to right for blue, Huang, black, green and red(can also draw with the monochrome), fasten 1913 according to attend to do obeisance conceive outline of Dan but design creation.1914 is celebration modern Olympic sport instauration 20 anniversary, at Paris hold of Olympic representative conference top first time rise.

奥林匹克旗,为白底无边,中央有五个相互套连的圆环,环的颜色自左至右为蓝、黄、黑、绿、红,系1913年根据顾拜旦的构思而设计制作的。1914年为庆祝现代奥林匹克运动恢复20周年,在巴黎举行的奥林匹克代表大会上首次升起。

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It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发,分析对称连杆曲线上鲍尔点的产生条件,提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品,年生产总值3000万美元,产品价廉物美、选料上乘、质量保证,深受国内外客户的青睐

The eˉtiology of hemospermia is complicate,but almost of hemospermia are benign.

血精的原因很,以良性病变为主。