有机硅的

The comparison of hydrolysis-polycondensation reaction and microstructure of ORMOSILs derived by TEOS, MTES, VTES, ETES confirms that the influence of organic group such as methyl, vinyl, ethyl and ethoxyl on the hydrolysis and polycondensation reaction rate depends on several factors including electron-donating capability, size and number of ethoxyl group which can participates polycondensation reaction.

确认甲基、乙烯基和乙基和乙氧基等改性基团对硅醇盐水解-缩聚反应速度的影响是取决于有机改性基团的电负性、尺寸和可水解的-OR基团数目等因素综合作用的结果，其水解速度依MTES＞TEOS＞VTES＞ETES的顺序递减。由于Si原子上可聚合的基团数目减少，导致MTES、VTES和ETES的聚合反应速度降低，而与水解速率失配。

Monomers A monomer is the basic building block of polymers.The word mer (from the Greek meros,meaning part) indicates the smallest repetitive unit,similar to the term unit cell in crystal structures.Thus,polymer means many mers or units.Monomers are organic materials.They include carbon atoms joined in covalent bonds with other atoms such as hudrogen,oxygen,nitrogen,fluorine,chlorine,silicon,and sulfur.

单体 单体是基本积木的polymers.the字经（从希腊美罗斯，这意味着部分）显示，最小的重复单位，类似的任期股细胞在晶体structures.thus ，高分子意味着许多市场汇率或units.monomers是有机materials.they包括碳原子加入共价键，与其他原子如hudrogen ，氧气，氮气，氟，氯，硅，硫。

Based on the molecular mechanisms guiding the biosilicification in marine organisms such as diatoms and sponges, cell wall template-mediated self assembly of nanostructured silica in plants and related morphogenesis, structures and functions of phytogenic silica are discussed. Understanding the templating and organic-inorganic bicomponent cooperation effects not only offers the clue for constructing silicon-based structures, but also recognizes the anomaly of silicon in plant biology, esp. in stress physiology.

借助海洋生物如硅藻和海绵的生物硅化机制，从植物体矿化纳米结构SiO〓的形态发生、结构和功能分析入手，运用植物营养学、植物病理学、纳米化学、生物矿化的原理和技术，重点研究了以植物细胞壁为模板构筑有机／无机二元协同纳米结构SiO〓，以及它们具有的特殊结构所赋予植物抵抗各种环境胁迫的可能作用，获得的主要结果如下

We screened a set of Lewis base organocatalysts derived from chiral pipecolinic acid and tert-butanesulfinamide for the reduction of-N-Cbz-1- phenylpropenamine, including newly designed ones and some of those previously developed in our lab. However, only moderate stereoselectivities, albeit high yields were obtained.

在本课题组前期研究的基础上，我们筛选并设计了一系列以手性哌啶酸和叔丁基亚磺酰胺为母体的有机小分子路易斯碱催化剂，它们能催化三氯氢硅对-N-苄氧羰基-1-苯基丙烯胺的不对称还原，获得很高的收率和中等的对映选择性，并且具有很好的底物普适性。

Starting from chiral proline, pipecolinic acid, piperazine-2-carboxylic acid and 1,2-diphenyl amino alcohol, a series of structurally simple and easily prepared amides were developed as highly effective Lewis basic organocatalysts for the asymmetric reduction of imines with trichlorosilane as the reducing agent, which promoted the reduction of N-aryl imines with high yields and excellent enantioselectivities with an unprecedented substrate spectrum.

本文分别由手性脯氨酸、哌啶酸、哌嗪酸以及氨基醇出发，设计和合成了一系列结构新颖、合成简便、性能优良的酰胺类有机小分子路易斯碱催化剂，以廉价的三氯氢硅为氢源，用这些催化剂催化亚胺不对称还原，得到了非常优良的收率、对映选择性和前所未有的底物普适性。

In this area seven microfacies in the Chuangde Fm. red beds can be separated. They are: 1 reddish foraminifera grainstone; 2 reddish microfossils packstone/wackestone; 3 reddish marlstone with microfossils; 4 reddish marlstone; 5 red to variegated floatstone ; 6 reddish shales; 7 reddish radiolarite/ radiolarian chert.In the Yamudok Cuo area, it can be distinguished six microfacies in the redbeds including 1 reddish foraminifera grainstone; 2 reddish microfossils marlstone; 3 reddish shales; 4 yellow-grayish floatstone ; 5 reddish radiolarian chert; 6 reddish chert with radiolaria. The depositional environment of the Chuangde formation can be interpreted from sediments composition, as is deep oceanic basin adjacent to continental slope/rise. The slope/rise setting is indicated by the occurrence of olistoliths and slumped pelagic/hemipelagic limestone, present near the top of the Chuangde Fm.

进一步资料对比研究表明，全球上白垩统海相红层具有以下特征：a上白垩统红层出现在北大西洋、阿尔卑斯、喀尔巴阡、土耳其，向东一直到特提斯喜马拉雅地区和澳大利亚西北角的Exmouth海底高原，横贯整个特提斯和北大西洋；b沉积环境以外陆棚-斜坡和盆地为主，在斜坡环境下多发育有浊流沉积，如Scaglia Rossa和Nietrental组；c有机碳含量普遍很低，0～0.3％之间；d盆地相仅发育红色泥质岩，而斜坡和远洋环境下不仅发育红色页岩，同时还有红色泥灰岩、红色灰岩和红色硅质岩；e北大西洋和地中海地区在Cenomanian-Turonian界线黑色页岩之后不久的Turonian早期就出现红色沉积，而藏南出现在Santonian早期，Exmouth出现在Campanian早期，红层出现似乎有&西早东晚&的趋势。

In the silicious matter which the water deposits is perhaps the bony system, and in the still finer soil and organic matter the fleshy fibre or cellular tissue.

大约骨骼的系统便是水分和硅所形成的，而在更精细的泥土和有机化合物上，便形成了我们的肌肉纤维或纤维细胞。

On the basis of investigating the developments of inorganic mesoporous material's syntheses and applications, mesostructured tin oxide, bismuth oxychloride, lead sulfide, bismuth sulfide, titanium phosphate and zinc phosphate were synthesized by Sol-Gel and hydrothermal techniques, employing the neutral surfactant organic amine and anion surfactant alkyl sulfonate as templates.

中文题名非硅基介孔材料的合成与表征副题名外文题名论文作者周书喜导师李健民学科专业物理化学研究领域\研究方向学位级别博士学位授予单位中国科学技术大学学位授予日期2003 论文页码总数92页关键词介孔材料介孔分子筛馆藏号BSLW /2003 /O643.3 /50 在对无机介孔材料的合成、应用等方面的发展现状进行了充分调研的基础上，本文运用溶胶一凝胶法、水热法等合成手段，选用中性表面活性剂有机伯胺和阴离子表面活性剂烷基磺酸盐为模板，制备了二氧化锡、氯氧化铋、硫化铅、硫化铋、磷酸钛、磷酸锌等无机介孔材料。

Thirty-one new chiral phosphorus compounds have been synthesized starting from D-camphor,-alpha-phenylethylamine,-Betti base,-1-(4-nitrophenyl)-2-amino- propane-1,3-diol, L-amino acids (such as serine, phenylalanine, proline etc.) and their application as organocatalysts in asymmetric trimethylsilylcyanation of aldehydes and asymmetric borane reduction of prochiral ketones and ketimines were investigated.

该项目从D-樟脑、-alpha-苯乙胺、-Betti碱、-氯酶胺、L-氨基酸（如丝氨酸、苯丙氨酸、脯氨酸等）出发合成了31个新的手性磷化合物，研究了它们作为有机催化剂在醛的不对称硅氰化反应、潜手性酮的不对称硼烷还原反应以及亚胺的不对称硼烷还原反应中的催化效果。

In this paper, the recent progress are presented on the methods, characterizations and applications of silicon surface modified by monolayers' organic molecules.

本文针对有机分子修饰硅表面的方法、单层膜的表征和应用，对近年来的最新研究进展进行了综述，并对该方向的今后的发展进行了展望。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。