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In this thesis, we developed chiral proton N-O type ligands and employed them in the enantioselective addition of diethylzinc to N-diphenylphosphinoyl imines. The relationship between the structure of the ligands and the enantioselectivity was systematically studied. Furthermore, enantioselective butylation of N-diphenylphosphinoyl imines withBu〓Zn and enantioselective diphenylzinc addition to imine were also examined.

本文致力于亚胺的不对称催化有机锌试剂加成反应的研究:以手性质子型N-O配体为促进剂,对N-二苯基次膦酰亚胺进行不对称乙基锌加成反应而展开研究工作,系统地考查了手性配体的结构对反应的影响;另外,对N-二苯基次膦酰亚胺的不对称催化丁基锌加成进行了研究,并首次对亚胺的不对称苯基锌加成反应进行了初步探索。

WHMM is a statistical model in wavelet domain of stochastic signals, which integrates wavelet transform into hidden markov models . According to the locality, multiscality of wavelet transform and context-sensitive property of HMM, WHMM can not only characterize precisely the local feature of object multiscally, but also reflect accurately the full structure information of object. So it is a powerful tool which deals with noise, shape similarity and part occlusion in ATR, and finds its full application in recognition system of moving vehicle.

小波隐马尔可夫模型是小波变换与隐马尔可夫模型相结合的一种小波域随机信号的统计模型,它有机地融合了小波变换的局部分析性、多尺度性和隐马尔可夫模型的上下文相关性,不仅能多尺度地精确刻画目标的局部特征,还能准确地反映目标的整体分布信息,从而成为解决目标识别中受噪声、形状相似、部分遮挡等问题的最有力的工具之一。

In this paper,the authors put forward the view that it is necessary to change the present all-inclusive compiling mode of medical jurisprudence courses.

有必要改革传统医药法类课程体系"大而全"以及机械地以部门法为教学单元的编排模式,应注重课程体系与教学内容的系统性、有机性和理论性。

The organic/inorganic composites, as new materials that combine the inorganic phase"s rigidity,stability and the organic phase"s toughness and workability, have important theoretical and realisticsignificance in materials science. C_(60) is a brand-new holosymmetry spherical molecule with theunique physical and chemical property, displaying wide implications and applications of physics,chemistry, biology, materials science, medicine, electronics, and so on.

有机/无机复合材料集无机相的刚性、稳定性和有机相的韧性、加工性等诸多特性于一体的一类新型材料,具有重要的理论和现实意义。C_(60)是一个全新的全对称球形分子,具有独特的物理、化学性能,已广泛地影响和应用到物理、化学、生物学、材料学、医学、电子学等许多领域。

Different from the conventional catalyst immobilization methods, the self-supporting strategy utilizes homochiral metal-organic coordination polymers generated by self-assembly of chiral multitopic ligands with metal ions without using any support.

与传统的负载模式不同,手性自负载催化剂通过含双或多官能团的手性配体与金属通过自组装形成一类有机-无机聚合物,因此无需使用任何载体,即能够有效地实现手性催化剂的回收和再利用。

This paper reviewed the research on dynamic and balance of soil nutrient pool under long-term fertilization conditions,mainly about some active aspects which included dynamic variations of total nitrogen,available N,total phosphorus,available P,total potassium,available K,and organic carbon in soil; dynamic variations of ammonium N,amino acid N,amino sugar N,unknown N,non hydrolyzable N and microbiomass N in soil nutrient pool; changes of Ca2-P,Ca8-P,Al-P,Fe-P,O-P,labile organic P,moderately labile organic P,moderately stable P,highly stable P and microbiomass P in soil; changes of loosely,stably and tightly combined humus,humic and fulvic acids in soil carbon pool; effects of long-term fertilization on organic-mineral complex status in soil; nutrients cycling and balance of agricultural soil nutrients pool.

扼要地概述了国内外近年来关于长期施肥条件下土壤养分库的动态与平衡方面的研究成果。主要介绍并讨论了土壤氮、磷、钾养分全量及有效量的动态变化,土壤有机碳含量的动态变化;铵态氮、氨基酸态氮、氨基糖态氮、酸解未知态氮、非水解残渣氮及微生物体氮在土壤氮库中的动态变化;Ca2 P、Ca8 P、Al P、Fe P、闭蓄态磷,活性有机磷、中度活性有机磷、中稳性有机磷、高稳性有机磷及微生物体磷在土壤磷库中的动态变化;土壤碳库中松结态腐殖质、稳结态腐殖质、紧结态腐殖质以及富里酸和胡敏酸的动态变化;长期施肥对土壤有机无机复合状况的影响;农田土壤养分库的养分循环与养分平衡。

The effect of silicon atom in substrate on the reaction rate and the stereoselectivity of enzymatic reactions was revealed by comparison of horse liver alcohol dehydrogenase-catalyzed stereoselective dehydrogenation of the three isomers of acetyltrimethyl propanone and their carbon analogues in aqueous/organic biphasic systems.

本项目通过对比在水-有机溶剂两相系统中,马肝醇脱氢酶催化三甲基硅烷丙酮的三个异构体及其碳类似物的光学选择性脱氢反应,揭示了底物中的硅原子对酶反应速度、立体选择性的影响规律,成功地合成了高对映体纯度的手性有机硅醇,并实现了辅酶的再生。

By combing the national character question and its studying origin and development diachronically and synchronically, this article reinterprets the basic meaning of the concept by the principle of history and logic organically unifying; And it systematically summarizes the theoretically cogitating achievement of that on its background, birth, nature, performing and reformation; It gives the corresponding theoretical care for the existing historical omission; Thus it attempts to explain the in-depth value embodied in this question according to the involved main threshold.

本文通过对国民性问题及其研究源流的历时性与共时性梳理,以历史与逻辑有机统一的原则重新阐释了国民性概念蕴涵的基本意义,从背景、生成、性质、表现以及改造等层面较为系统地概述了中国近代国民性问题理论认知的成就,并对其存在的历史缺失给予相应的学理观照,由此依照问题涉及的主要界域,对其内蕴的深层价值进行了尝试性解读。

Enantiopure epoxides are versatile chiral building-blocks in organic synthesis and can be used for convenient synthesis of many bioactive compounds.

手性环氧化物是有机合成中非常重要的手性合成砌块,可以方便地合成许多有生物活性的手性化合物,因而在手性合成和医药工业上具有极其重要的应用价值。

As for the management process, this dissertation integrates mega-events in urban development by combining them with urban management. From the perspective of time, it takes into consideration both the facts that a mega-event is once for all and that a mega-event is a process; from the perspective of development, it takes into consideration both the input influences and the output results of mega-events; from the perspective of systemic development, it takes into consideration both the operationof mega-events and the interactive influence between mega-events and the environment.

在管理过程上,本文将特大活动有机地融入了城市发展,有机地结合了城市管理,从时间发展的角度,既考虑了特大活动的一次性,又考虑了特大活动的过程性;从活动发展的角度,既考虑了特大活动的输入影响,又考虑了特大活动的输出结果;从系统发展的角度,既考虑了特大活动的事件运作,又考虑了特大活动与环境的互动影响。

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With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务,乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐,因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。

Closes the eye, the deep breathing, all no longer are the dreams as if......

关闭眼睛,深呼吸,一切不再是梦想,犹如。。。。。。