有机化学

The clinical application of technetium in nuclear medicine will parallel with the development of technetium chemistry in organic-analytical-medical- and biochemistry, and it is likely that useful new Tc-99m radiopharmaceuticals will rapidly make world-wide progress in the future years.

未来鎝-99m在核子医学临床上的应用将并行於鎝化学在有机化学、分析化学、医学化学及生物化学的发展。同时，新的、有实用性的鎝-99放射药物将在世界各地继续研究发展。

This paper is a generalization and summation of some new progress in marine chemistry in the recent decade. The principal contents consist of seven parts:1. Oceanological survey. The oceanological survey covered the China Seas, the Pacific Ocean and the Antarctic Ocean.2. Interaction of minor elements and suspended matter in seawater and the theory of in-terfacial stepwise ion/coordination partical exchange.3. Effect of organic matters on the liquid-solid interfacial exchange and the rule of left-righ...

本文对近十年来海洋化学的若干新进展作了总结，主要包括下述7方面：(1)海洋调查，包括中国近海、太平洋和南极等；(2)海水中微量元素-固体粒子的相互作用和界面分级离子/配位子交换理论；(3)有机物对液-固界面交换的影响和S-型曲线左右移动规律；(4)海水化学模型发展的三个新趋势；(5)海水中金属的络合容量和金属-天然有机配位体络合物的条件稳定常数；(6)海洋有机化学和海洋生物化学；(7)结论，对海洋化学发展的四个特点作了分析和讨论。

All the compounds were isolated and identified from the bituminous coals for the first time, bis(2-ethylheptyl) terephthalate and 18-ethyl-17-(hexan-2\'-yl) docosanoic acid are new compounds.Further more, a Colourless Oil Liquid, a white acerate crystals containing some alkanes, a white tabular crystals consisting of some fatty acid esters and a white powder crystals in which some fatty acids exist were isolated and analysed by GC/MS for the first time.Through this research, a study method of"classification extract of bituminous coal- separation with silica-gel and gelatin column chromatographies- identification of the isolated compounds by FTIR, GC/MS, LC/MS, 1H NMR and 13C NMR analyses"was established and proved to be a practical approach toward separable and non-destructive identification of some organic compounds in bituminous coals for coal chemistry research.

本研究建立了&原煤分级萃取-硅胶与凝胶柱层析分离与纯化-GC/MS或LC/MS检测-FTIR、MS、1H NMR和13C NMR波谱解析&这一煤中有机化学成分的非破坏性分离与分析的研究方法，并验证该研究方法有效可行。

This paper contains three parts: 1 Synthesis of novel titanium complexes; 2 Polymerization behaviors of alkoxyl substituted Cp Titanocenes as catalysts for styrene syndiotactic polymerization; 3 Polymerization behaviors of alkenyl substituted Cp Lanthanocenes as Methyl Methacrylate polymerization catalysts.

中文题名新型茂钛、噁唑啉钛络合物的合成、表征以及茂钛、茂稀土络合物催化性能的研究副题名外文题名 Synthesis，characterization of novel Cp，oxazoline titanium complexes and polymerization behaviors of titanocenes and lanthanocenes 论文作者张浩导师钱延龙黄吉玲学科专业应用化学研究领域\研究方向金属有机与均相催化学位级别博士学位授予单位华东理工大学学位授予日期2003 论文页码总数148页关键词金属有机化学稀土络合物噁唑啉类钛络合物茂钛络合物馆藏号BSLW /2003 /O627 /27 本论文包括三部分内容：1）有机金属钛络合物的合成；2）烷氧基取代茂钛络合物催化苯乙烯间规聚合的研究；3）烯基取代茂稀土络合物催化甲基丙烯酸甲酯聚合的研究。

The palladium-catalyzed allylation is a powerful tool for C-C, C-N, and C-O bond formation, which has been widely applied to organic chemistry.

藉由钯催化烯丙基化反应合成碳—碳键、碳—氮键和碳—氧键是非常有利的方法，主要是因为它在有机化学上广泛的应用性。

The palladium-catalyzed allylation is a powerful tool for C-C, C-N, and C-O bond formation, which has been widely applied to organic chemistry.

而利用金属钯当作催化剂来进行烯丙基化反应，形成碳-碳键，碳-氮键和碳-氧键，在有机化学中是很广泛的合成方法。

Benzenoid system and coronoid system s are the natural representations of the skeletons of molecules of benzenoid hydrocarbons and coronoid hydrocarbons in the field of organic chemistry.

六角系统和冠状系统分别是有机化学领域中的苯碳氢化合物和冠状碳氢化合物的分子结构的自然体现。

The invention belongs to the technical field of organic chemistry, in particular to a benzothiazole compounds and a preparation method for the compounds.

本发明属于有机化学技术领域，具体为一种苯并噻嗪类化合物及其制备方法。

Starting from 2-naphthylamine,2,2′-diamino-1,1′-binaphthyl was obtained via oxidation,coupling reaction and rearrangement.

&配体催化合成&是有机化学研究领域中的前沿和热点，它是化学领域的一门交叉学科。

With the development of life science and biological engineering, chiral separation and recognition have been payed close attention universally ,which have important significance in organic chemis- try, life science and medicinal chemistry.

随着生命科学和生物工程的发展，手性拆分和手性识别引起了人们的普遍关注，研究对映体拆分与识别对有机化学、生命科学和医药工业均具有十分重要的意义。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。