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Pillared montmorillonite, as a representative of Sandwich like pillared interlayered clays ,caught many scientist"s attention not only because of its special structure of two-dimensional sheets but also its excellent activity of catalysis and adsorption. It is well documented that the method to prepare PILM, ion-exchanging, needed a long periods and was affected by many factors, and that the product had low thermal stability especially hydro-thermal stability which was the primary obstruction of its using in large-scale production. At the same time, PILM was well documented prepared with Na-montmorillonite, while there were a few documents about PILM prepared with Ca-montmorillonite. The large cost of remodel of Ca-montmorillonite to Na-montmorillonite was another obstacle of the application of PILM, while Ca-montmorillonite was widely distributed in nature, as a result, to prepare PILM with Ca-montmorillonite has practical significance. What"s more, PILM was mainly studied as a catalyst in oil refining process till now, but rarely documented in other catalysis reactions, especially in coal liquification filed which also needed high activity catalyst.

以柱撑蒙脱石为代表的具有&三明治&结构的柱撑粘土矿物因其特殊的二维孔道结构和优良的催化和吸附性能近年来成为国内外广泛关注和研究的热点,但是目前国内外大量报道的PILM制备大多采用离子交换法,生产周期很长,影响因素很多,并且产物热稳定性不够高,特别是水热稳定性较差,这是其不能在实际中大规模生产和应用的主要障碍,因此制备一种高稳定性的PILM意义非常;文献中大量报道的都是钠基蒙脱石合成的柱撑粘土矿物,传统的离子交换法必须将钙基蒙脱石钠化改型,其成本相当高,而自然界中大量存在的却是钙基蒙脱石,直接用钙基蒙脱石合成柱撑粘土矿物有很现实的意义,但目前这方面的报道却很少见;另外,迄今为止,PILM作为催化剂的研究领域主要在石油的炼制中应用,而在煤炭的液化中却鲜有报道,如果能在煤炭转化领域应用这一成果,其影响也将是相当大的。

Pillared montmorillonite, as a representative of Sandwich like pillared interlayered clays ,caught many scientist's attention not only because of its special structure of two-dimensional sheets but also its excellent activity of catalysis and adsorption. It is well documented that the method to prepare PILM, ion-exchanging, needed a long periods and was affected by many factors, and that the product had low thermal stability especially hydro-thermal stability which was the primary obstruction of its using in large-scale production. At the same time, PILM was well documented prepared with Na-montmorillonite, while there were a few documents about PILM prepared with Ca-montmorillonite. The large cost of remodel of Ca-montmorillonite to Na-montmorillonite was another obstacle of the application of PILM, while Ca-montmorillonite was widely distributed in nature, as a result, to prepare PILM with Ca-montmorillonite has practical significance. What's more, PILM was mainly studied as a catalyst in oil refinin g process till now, but rarely documented in other catalysis reactions, especially in coal liquification filed which also needed high activity catalyst.

以柱撑蒙脱石为代表的具有&三明治&结构的柱撑粘土矿物因其特殊的二维孔道结构和优良的催化和吸附性能近年来成为国内外广泛关注和研究的热点,但是目前国内外大量报道的PILM制备大多采用离子交换法,生产周期很长,影响因素很多,并且产物热稳定性不够高,特别是水热稳定性较差,这是其不能在实际中大规模生产和应用的主要障碍,因此制备一种高稳定性的PILM意义非常;文献中大量报道的都是钠基蒙脱石合成的柱撑粘土矿物,传统的离子交换法必须将钙基蒙脱石钠化改型,其成本相当高,而自然界中大量存在的却是钙基蒙脱石,直接用钙基蒙脱石合成柱撑粘土矿物有很现实的意义,但目前这方面的报道却很少见;另外,迄今为止,PILM作为催化剂的研究领域主要在石油的炼制中应用,而在煤炭的液化中却鲜有报道,如果能在煤炭转化领域应用这一成果,其影响也将是相当大的。

Since H〓S and SO〓 adsorbed on TiO〓 could react with each other and TiO〓 is the medium of their electron transfer, thus SO〓 could not be adsorbed quite strong on the active site of TiO〓, which makes it more resistant to sulfating and increase the stability of catalyst. Finally, the model and mechanism of the reduction of SO〓 by NH〓 to elemental sulfur is advanced as follows: on the sulfide catalyst, ammonia is decomposed to N〓 and H〓, and H〓 reacts with SO〓 to form the intermedium of H〓S; then H〓S and SO〓 react as Claus reaction on TiO〓 catalyst.

反应系统中过量水蒸气的存在使催化剂表面某些活性位被水蒸气抑制使活性和选择性有较大幅度降低,但这种影响是可逆的,不会造成催化剂永久性中毒;另外当单质硫和水蒸气同时存在时,在〓催化剂上能够生成硫化氢和二氧化硫,而且由于硫化氢和二氧化硫化学吸附能力不同而导致它们的脱附顺序不同,硫化氢的生成温度总是低于二氧化硫的生成温度,说明过量水蒸气的存在会导致氧化物催化剂上逆克劳斯反应的发生;而在硫化物催化剂上几乎没有硫化氢和二氧化硫生成,说明硫化物催化剂能够抑制逆克劳斯反应的发生。

On the bases of absorption spectra measurements, it is shown that stabilizer is beneficial to the stability of J-aggregate of sensitizing dye Results of reflection spectra and spectral-exposure experiments demonstrate that spectra absorbance are greatly affected by the adding order of stabilizer and sensitizing dye and only stabilizer added after dye can advantage for J-aggregate of sensitizing dye neatly forming on the surface of silver chloride grain and its absorbance be available ESR experiments show that the addition of stabilizers can decrease the number of dye positive hole and accelerate the decay of it Then desensitization aroused by the recombination of dye positive hole with photoelectron and/or latent image center, was reduced at the presence of the stabilizers

通过溶液光谱实验说明稳定剂有利于染料J聚集体的稳定性;反射光谱实验和光谱曝光实验证明稳定剂与染料的添加次序对乳剂的光吸收有很大的影响,只有稳定剂在染料之后加才有利于染料在AgCl颗粒上排列整齐形成J聚集态及其光吸收;ESR实验结果说明稳定剂的加入可以降低染料正空穴的浓度及其衰减速率,使乳剂中染料正空穴减少,从而抑制了染料正空穴引起的减感作用。因此可以认为稳定剂的超增感作用:一是有利于染料形成J聚集态及乳剂的光吸收;二是降低染料正空穴的浓度,从而抑制染料的减感。同时还提出了染料与稳定剂的增感吸附模型。

Obviousfeatures for semi-fluorinated surfactant syntheses of ordered mesoporous silicamaterials are as follows:(1) Tailorable pore size from 1.6 to 4.0 nm, estimatedby BJH and TEM methods;(2) pH value for synthetic system is extended toneutral condition;(3) Thicker porous walls, showing high hydrothermal andmechanical stability.

进一步的研究表明这些材料有以下特点:(1)根据N2吸附BJH计算方法和TEM的判断,孔径可以控制在 1.6 到 4.0nm之间;(2)合成体系的pH可以延伸到中性,而这在以往的报导中是很少见的;(3)较厚的孔壁,表现处很好的水热稳定性和机械稳定性,特别是JLU-14 比在相同条件下合成的SBA-15 和MCM-41 的机械稳定性要高很多;(4)非常大的表面积,例如JLU-1560的表面积高达

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However, as the name(read-only memory)implies, CD disks cannot be written onorchanged in any way.

然而,正如其名字所指出的那样,CD盘不能写,也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

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A single payment file can be uploaded from an ERP system to effect all pan-China RMB payments and overseas payments in all currencies.

付款指令文件可从您的 ERP 系统上传到我们的电子银行系统来只是国内及对海外各种币种付款。