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Aenigmatite , like sodium amphiboles and sodium pyroxenes, is also a kind of alk.

钠铁非石是一种三斜晶系的富钛、铁、铀的单链非辉石类硅酸盐矿物,通常和钠质辉石共生。

Bipyridyl and 1,10-phenanthroline (L3), Cl3SnCH2CH2COORo L (L= L1, a; L2, b; L3, c), formed by low-heating solid-state reaction. The crystal structures of 1 and 2 show that the tin atom adopts a distorted trigonal bipyramid geometry via intramolecular carbonyl oxygen to tin coordination [the distances of Sn-0 bond are 0.2351(6) ran for 1 and 0.2362(3) nm for 2]. Compound 1 belongs to monoclinic with space group P2/c, a = 0.9842(2) nm, b =1. 0923(8) nm, c = 1.23948(11) nm,/?= 93.894(15)°, V= 1.3294(4) ran3, Mr = 366.23, 7 = 4. Compound2 belongs to monoclinic with space group P2{/c, a = 1.04443(9) nm, b = 1.04823(7) nm, c = 1.28113(9) nm,/= 90. 953(8)°, V= 1.40239(19) nm3, Mr = 380.25, Z = 4

利用元素分析、红外光谱、核磁共振对其结构进行了表征,并通过X射线单晶衍射测定了1和2的晶体结构,二者均为具有分子内羰基氧原子配位的畸变三角双锥结构。1属于单斜品系,空间群P21/c, a=0.9842(2)nm,b=1.0923(8)nm,c=1.23948(11)nm,β=93.894(15)°,V=1.3294(4) nm^3,Mr=366.23,Z=4.2属于单斜晶系,空间群P21/c,a=1.04443(9)nm,b=1.04823 (7)nm,c=1.28113(9)nm,β=90.953(8)°,V=1.40239(19)nm^3,Mr=380.25,Z=4。

Initially synthesized In2O3 nanocubes possesses a length between 500-600 nm. Inspected by XRD, ESCA and TEM, the nanocubes are confirmed as bixbyite structure of In2O3, which is a cubic structure system.

初合成的In2O3奈米立方晶体长度大约在500-600nm,透过XRD、ESCA和TEM的仪器检验,证明其确实为氧化铟的立方铁锰矿结构,属於立方晶系结构。

Crystal habit: prismatic crystals elongated on c, often flattened on {100} with deep vertical striations, also can be acicular or in cleavable masses.

晶体结构特征:单斜晶系,柱状晶体,扁平柱状晶体,常有熔蚀现象,并有明显的三角形表面印痕。菱面体样块体结构,常有较深垂直条纹,有时呈针状或者集合状

The crystal is monoclinic,space group 〓, the ligand coordinates to Ni acetate in the enolic form,and produces a square complex.

单晶的结构是:晶体属于单斜晶系,空间群为〓,镍原子位于平面四方形配位中心,配体分子是以内式的烯醇式向镍原子配位的。

Two qina ligands chelate a cobalt ion by 0 and N atoms and two DMSO ligands coordinate a cobalt ion by two O atoms at an axis. The complex formed inerratic octahedron configuration, and π-π stacking weak interaction was observed between the molecules.

配合物为单斜晶系,P2(1)/C空间群,2个qina配体以氮原子和氧原子与Co离子螯合配位,2个DMSO以氧原子与Co离子轴向配位,形成规则的八面体构型配合物,分子之间存在π-π堆积弱相互作用。

The crystals are monoclinic and space group C2/c.

晶体结构均属单斜晶系,空间群为C2/c。

Based on the framework structure of mordenite, another novel structure molecular sieves with extra-large pores is designed.

基于丝光沸石的骨架结构利用Σ变换方法还设计了属正交晶系Cmcm空间群的MCR16超大孔新型分子筛骨架拓扑结构。

The study of crystal structure indicates that the complexes belongs to tetragonal,14(1)/a, a=b=27.047(5) A, c=14.103(3) A, a=b=y =90,V=10317(4)A3, Z=16, Dc=1.071g/cm3, F(000)=3408, R,=0.1395, R2=0.1766 and every unit of the tetranuclear complexes is four-coordinated to tridentate ligand and nitrogen atom in pyrazolone from other ligand. The complexes is slightly deformed square-planar geometry.

晶体结构研究表明,该配合物为四方晶系,空间群I4(1)/a,a=b=27.047(5),c=14.103(3),α=β=γ=90°,V=10317(4),Z=16,Dc=1.071g/cm~3,F(000)=3408,R_1=0.1395,ωR_2=0.1766,其结构单元是由一个三齿配体中的ONO和另一个配体吡唑啉酮环二位上的N配位后形成略微畸变的平面四边形构型,其中Cu的配位数为4。

The results show that single phase of La0.3Ca0.7FeO3 can be obtained at 800℃ for calcining 2 h, and the sample with 17.9 nm belongs to rhombohedral crystal system. Moreover, oxygen electrodes have obviously electrocatalytic activity.

结果表明:800℃焙烧2 h得到完整的晶体,晶体粒子大小均匀,粒径为17.9 nm,为菱形晶系;同时该氧电极具有明显的电催化特性。

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