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Based on the similarity of structure between the antifluoride and alkali antimonide, the possible transitions taking place in the Brillouin zone corresponding to the structure in the optical spectra are identified for Na_2KSb,Css_3Sb and K_2CsSb cathode.

利用反荧石结构和其结构的相似性,确定了Na2KSb、Cs3Sb和K2CsSb阴极在光谱结构上对应布里渊区中发生的光学跃迁,发现多碱阴极的跃迁更接近晶态,而Cs3Sb和K2CsSb阴极和非晶态的非常类似,在Na2KSb中出现的来自Δ、Σ方向跃迁形成的极大峰并不出现在Cs3Sb和K2CsSb。

Based on the petrological and geochronological study of metamorphic complexes from the Grove Mountains, the following conclusions are reached.(1)Exsolution texture is widely found in clinopyroxene in mafic granulites. A peak metamorphic temperature of 850 C was obtained from the reintegrated compositions of exsolved clinopyroxene. The preservation of augite megacrysts suggests a single episode of high-grade metamorphism for the Grove Mountains.(2)The compositional comparison of garnet from pegmatites with that from country rocks demonstrates that garnet in pegmatites is of xenocryst origin, and late amphibolite facies metamorphism does not occur in this area.(3)The Pan-African charnockite and post-tectonic sheet-like granite were first recognized in East Antarctica. Their occurrences suggest a collisional orogeny during the Pan-African time.(4)The SHRIMP U-Pb zircon dating on various rock types indicates that the major metamorphism in the Grove Mountains occurs at c. 550 Ma, and the tectonothermal evolution terminated at c. 500 Ma. The Grenvillian granulite facies metamorphism did not develop in the studied area.(5)The Prydz belt, the second Pan-African suture within the Gondwana suppercontinent, was further comfirmed based on this study. The Gondwana suppercontinent was not formed by the simply juxtaposition of East and West Gondwana, but by the collision of several blocks during the Pan-African time.

本项目通过格罗夫山地区高级变质杂岩的变质岩石学和同位素年代学研究,获得如下重要认识:(1)发现辉石出溶结构,由此获得峰期变质温度为850 C,并根据火成普通辉石的识别确定该区只存在单相麻粒岩相变质;(2)通过伟晶岩中石榴石斑晶与围岩中石榴石的对比研究提出了石榴石的捕虏晶成因,进而确定该区不存在晚期角闪岩相变质作用;(3)在东南极首次识别出泛非期紫苏花岗岩和后构造层状花岗岩,为泛非构造热事件的碰撞造山成因提供了重要佐证;(4)对不同岩石类型的锆石SHRIMP定年精确地限定了格罗夫山地区主期变质作用发生于泛非期,~550 Ma,热事件结束于~500 Ma,年代学数据没有揭示在该区存在格林威尔期麻粒岩相变质作用的迹象;(5)进一步确认了东南极内部普里兹带的存在,它属于冈瓦纳超大陆内部的第二条泛非期缝合带,据此认为冈瓦纳超大陆并不是由东、西冈瓦纳陆块的简单拼合而成,而是多个不同块体拼合的结果。

The study shows that almost all the feldspar in the alkali-granite is perthite, the host-crystal is microcline, the chadcrystal could be either albiter or oligoclase. The Alkali-amphibole is either manganese-magnesia-arfvedsonite or arfvedsonite, and all the alkali-pyroxene is aegirine.

结果表明,该区富碱花岗岩几乎所有的长石均为条纹长石,主晶为微斜长石或高微斜长石,客晶为钠长石或更长石,碱性角闪石为含锰镁质钠铁闪石或钠闪石,碱性辉石均为霓石。

It is feasible to overgrow mesoporous MCM-41 on the rough surfaces of the grains. The obtained samples possess the ordered hexagonal mesoporous structure of MCM-41-type molecular sieves. Mesoporous molecular sieves (denoted as MZ-B) with ordered hexagonal structure have been successfully synthesized by the assembly of the precursors from filtrate of alkali-treated ZSM-5 zeolite with CTMABr surfactant micelles in alkaline media based on S+I– static electricity route.

而碱处理ZSM-5沸石得到的滤饼为富含超细化颗粒的晶粒,且晶粒粗糙度很高,因此易于附晶生长介孔分子筛,得到的微孔颗粒表面附晶生长的介孔分子筛,具有很好的长程有序度,为六方排列的孔道结构。

The content of the irregular bigger drop phase approached to pyrope. It showed that the crystallization and phase separation mechanics of the glass was the nucleation-and-growth transformation and the crystallization is bulk crystallization. The activation energies of phase separation and crystallization were calculated by the modified Kissinger method, about 310.445 KJ/mol and 249.26 KJ/mol respectively. Using the aluminum hydroxide as the reference, we calibrated the phase separation exothermal enthalpy of the quenched and nucleation treated glass, ca

钠镁侣硅系统徽晶玻瑞快速徽晶化机理的研究利用上式求得混合系统中两相的单位体积相变自由能、两相间的表面能和相互作用参数,分别为刁。6753xlo3了zcm3·、3ss.gozzem3、5.316xlo一JzcmZ和一442 xlol,进而求得球形核的临界半径为nnm,以及一个临界核的成核自由能变化为2石89 x10一14/cm3;成核半径16.5纳米时,球形核稳定存在,实测 1752个球形核中最小核半径为20纳米,与计算结果基本吻合。

The conclusion was drawn by the synthesis of molecular sieve: after mixed soluble glass and aluminium sulfate with proper proportion under room temperature, it was stirred stormily to react. And then we mixed with potassium hydroxide solution after filtrating. At last, the molecular sieves of potassium type was synthesized after the mixture reacted in the oven or autoclave for 24 hours. The molecular sieve was remodeled more than twice with ammonium chloride solution that the concentration was 3mol/L and then remodeled twice with the saturated sodium chloride solution. Finally the molecular sieve was changed into the sodium type. It was named W zeolite.

通过对分子筛的合成得到:以泡花碱、硫酸铝为原料,以硅铝比按一定比例于室温下将二者混合,激烈搅拌,抽滤后与氢氧化钾溶液混合放于烘箱或高压釜中高温晶化24小时,晶化后的分子筛为钾型,先后用3mol/L氯化铵溶液和饱和食盐水各对其改型两次以上,最后改为钠型,可制得W型沸石分子筛。

The results show that underlayer glaze is composed of glass phase, FAP and sphene crystals, and porous bioactive glass_ceramic coating is composed of glass phase, FAP and β-CaSiO3 crystals, a bone boning is gained between the composite coating and natural bone.

结果表明:底釉由玻璃相、FAP和榍石晶相组成﹔多孔生物玻璃陶瓷涂层由玻璃相、FAP和β-CaSiO3晶相组成﹔复合涂层能与骨组织产生骨性结合。

Through theoretical analysis of bischofite's pyrolysis and chemical analysis of intermediate products during different sintering stages, anhydrous magnesium chloride was presumed to be the precursor, which was confirmed by the preparation of MgO whisker from anhydrous magnesium chloride.

通过对水氯镁石热解的理论分析、以及对灼烧各阶段产物的化学分析,确定生成晶须的中间产物为无水氯化镁,然后直接从无水氯化镁制备出MgO 晶须。

There are two kind of zicons in amphibolite from the Haiyangsuo area,eastern Shandong Province:(1)Xenocrysts,they give 207Pb/208Pb age of 2149Ma,which suggests an early proterozoic basement in this area;(2)Magmatic euhedral zircons,they give an upper intercept age of 1784±11Ma and lower intercept age of 448±13Ma.

中文摘要:胶东海阳所胶南群斜长角闪岩中的锆石有2类:(1)捕掳晶锆石,它给出2149Ma 的207Pb/206Pb 年龄,证明该区存在有早元古基底;(2)岩浆结晶锆石,它的不一致线上下交点年龄分别为1784±11Ma和448±13Ma。

TiO2/sepiolite and TiCVzeolite with high photocatalytic activity have been prepared using sepiolite and zeolite minerals as carrier and the industrial metatitanic acid and the industrial sulfate titanium liquid as the raw materials for the first time.

首次采用工业偏钛酸、工业浓钛液为原料,天然海泡石、沸石为载体,制备出具有光催化活性的复合材料;沉积在海泡石或沸石表面的TiO_2粒子晶型为锐钛型;制成的TiO_2/海泡石、TiO_2/沸石复合物比表面积分别达到255m~2/g、161m~2/g; 2。

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