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Through studying the variation of lattice constants of Al_2TiO_5 withtemperature, the authors discovered am abnormal phenomenon that lattice constant c of Al_2TiO_5decreases with the increase of temperature.

通过仔细分析钛酸铝的晶格常数随温度变化的特点,发现钛酸铝的晶格常数C随温度升高而降低这一反常现象。

Through studying the variation of lattice constants of Al2TiO5 with temperature, the authors discovered an abnormal phenomenon that lattice constant c of Al2TiO5 decreases with theincrease of temperature.

通过仔细分析钛酸铝的晶格常数随温度变化的特点,发现钛酸铝的晶格常数c随温度升高而降低这一反常现象。

There is an allotropic change temperature (1155K) for pure Ti and it is a hydrogen-absorbing metal for different solubility in a-phase titanium and 3-phase titanium. The hydrogen atom dissolves in lattice and occupies tetrahedron interstitial position, and then forms TiH2 sublattice of face-centered cubic.

钛是-种具有同素异型转变点T(1155K)的吸氢金属,氢在α钛和β钛中有不同的溶解度,在T以下易形成具有面心立方晶格结构的TiH2,氢原子溶解在晶格中,占据四面体间隙位。

Treating the anharmonic terms of potential energy as perturbations,and employing the formulas for atomic displacements and Hamiltonian in phonon occupation number representation ,the formulas for thermal expansion coefficients of crystal nano-wires are derived and the numerical calculations are carried out in this paper.

将原子间相互作用势的非谐项作为微扰,运用声子数表象中的晶格原子振动位移和晶格振动哈密顿公式,推导了纳米晶体线的热膨胀系数公式,并进行了数值计算。

There exists isomorphous replacement in the rutile structure, and the most prominent feature is the average content of oxides, being 1.22%, 0.39%, 0.35% and 0.22% for V 2O 5, Fe 2O 3, ZnO and CuO respectively. They substitute Ti 4+ in octahedra. The valence of V is 5, and its polyhedron is trigonal bipyramid, which causes the lattice distortion, breaks the raw octahedron symmetry into square bipyramid, and produces the microstrains in the structure.

天然含钒金红石平均含V2O5可达1.22%,Fe2O30.39%,ZnO0.35%,CuO0.22%,这些金属离子可替代八面体中Ti^4 。V以5价形式存在,配位多面体呈三方双锥,其在晶格内部对Ti的替代导致晶格畸变,打破了配位多面体原有的八面体对称而呈四方双锥的几何形态,并产生结构微应力。

The experimental results demonstrate that a 2D packing of isodiametric particles leads to distortional flow due to' microcrystallities', while the quasi-two dimensional arrangement (Q2D) with a thickness of several particle diameters and the three dimensional arrangement (3D) effectively avoid the distortion.

结果表明:二维精确等径球颗粒床具有微晶格效应,因此流动是畸变的;半圆柱仓的三维流动不出现畸变;而第3方向取几个球厚度的拟二维流动也避免了微晶格效应和畸变。

It is obvious that, in the interface between substrate and diamond film,there exists the lattice strain effect resulting from lattice misfit because ofthe difference between the lattice constants.The lattice strain effect willcause some nonnegligible influences on the processes of diamond films′growth.

在本论文中,我们首次提出了在异质衬底上研究金刚石薄膜生长机理时必须引入晶格应变效应微扰修正的物理思想,并借鉴固体能带应变微扰理论,首次在分子轨道理论框架下建立起计算晶格应变微扰效应的理论,其中包括提出了计算单个化学键应变张量的方法和由分子轨道波函数计算应变微扰Hamilton矩阵元的方法。

XRD indicated that the replacement of the terephthalate anion by the polytungstate anion had little effect on the structure.

结果表明,经过同多钨酸根阴离子的交换以后,垂直于水滑石层板方向的平行层板方向的晶格参数值变小,平行层板方向的晶格参数值不变,(003)、(006)、(009)衍射峰处的层间距值比为3:2:1;交换过程没有改变水滑石的结构,水滑石原位生长在γ-Al2O3表面及内孔,比表面积由γ-Al2O3载体的219m2/g增加到247m2/g,孔径分布则由原来的2~11nm变化为3~4nm。

XRD indicated that the replacement of the terephthalate anion by the polytungstate anion had little effect on the structure.

结果表明,经过同多钨酸根阴离子的交换以后,垂直于水滑石层板方向的平行层板方向的晶格参数值变小,平行层板方向的晶格参数值不变,(003)、(006)、(009)衍射峰处的层间距值比为3:2:1;交换过程没有改变水滑石的结构,水滑石原位生长在γ-Al2O3表面及内孔,比表面积由γ-Al2O3载体的219平方公尺/g增加到247平方公尺/g,孔径分布则由原来的2~11nm变化为3~4nm。

The results show that the thin film has a pseudocubic perovskite structure and the good the epitaxial direction.

结果表明,薄膜为赝立方钙钛矿结构,晶格常数为3.861 nm,晶格失配度为2.1%,具有良好的单晶外延结构和较光滑的表面,且薄膜中晶粒的生长模式是&柱状&模式。

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