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And the lattice distance expands anomalously with decreasing particle size. Using the model of long-range interaction and its cooperative phenomena altered by particle size, the size-induced cubic-tetragonal phase transition, the anomalous lattice expansion, and the change in chemical bonding characters have been well understood.

采用长程相互作用的晶粒尺寸效应模型,对钛酸钡纳米晶结构相变、晶格间距异常增加、价键性质变化等实验现象给出了合理的统一的解释;并把该模型扩展到解释与钛酸钡晶体具有不同共价性成分的氮化镓等纳米体系的相变以及晶格结构变化现象。

The apatite with end-member cations, the apatite solid solutions [M-M1 AP] withdivalent cations substitution, the fluorapatite and the chlorapatite with end-memberations, the apatite solid solutions [Xi-X2 AP] with column-ions substitution were synthesizedthrough " solid-phase reaction method" in inert gas.

对不同Ca/P摩尔比HAP来说,在1.2≤R≤2.3范围内,随R值偏离正常配比程度的增大,其比表面积增大、晶粒尺寸ΓA,Γ(221,ΓR减小、晶形指数降低、结晶度减小、晶格缺陷度增大;当R=2.5时,晶粒尺寸和结晶度反而增大,出现反常,但晶格缺陷度却保持有规律增加。

Consisting of the protracting graph of hydrogen-like atom"s angle distributing, computer simulation of the symmetry of molecular orbital and chemical reaction mechanism, showing the molecular point group and symmetry element, computer simulation of molecular vibration, Bravias"s crystal lattice and their transforming, extracting of plane periodic lattice, extracting of solid periodic lattice, close packing of isometrical pellet and the structure of simple mental substance, close packing of unequal pellet and crystal structure of representative ionic crystal, Computer Simulation of Phase Analysis by X-ray Diffraction.

内容包括类氢原子角度分布图的绘制,分子轨道对称性和反应机理的微机模拟,分子点群和对称元素显示,分子振动运动的微机模拟,布拉维晶格晶格转化,平面点阵抽取,立体点阵抽取,等径网球的密堆积和金属单质结构,不等径圆球密堆积和典型离子晶体结构,X射线多晶衍射的微机模拟十个子模块。

The calculated results show that the total energy of one unit increased with increasing of hydrostatic pressure,while the lattice constant decreased.

计算表明单位晶胞总能量和晶格常数随水静压的增大而增大,晶格常数随水静压的增大而减小。

The results show that the interplanar crystal spacing and lattice index of Al-rich α phase reduce gradually with increasing pressure. When the pressure reaches from common pressure to 5 GPa , Al-rich α phase lies on the (200) and (220) crystal faces, the interplanar crystal spacing are reduced by 1.07% and 1.15%. From common pressure to 3 GPa , the microstructure of ZA27 alloy changes from thick dendrites to fine dendrites, and finally to granular. According to the effect of solute diffusion coefficient under super high pressure and the calculation of Scherrer formula, it can be seen that the crystal organization is fine within the bounds of certain pressure. This conclusion is consistent with the experiment results.

结果表明:随着压力的增加,晶面间距和晶格常数都逐渐减小,当压力达到5 GPa时,富铝α相在(200)与(220)晶面处,晶面间距较常压力时的分别减小1.07%和1.15%;在常压至3 GPa范围内,晶粒由粗大的树枝晶→细小的树枝晶→粒状、椭球状枝晶转变的趋势,通过压力对合金凝固溶质扩散系数的影响结合Scherrer公式计算分析其组织变化原因,得出在一定的压力范围内,随着压力的增大,晶粒尺寸逐渐变小,这一结论与实验结果相符。

For spin-3/2 Isingmodel with transverse crystal field,the tricritical phenomena havebeen observed for the square and simple cubic lattice,but there isno tricritical point for the honeycomb lattice.

横向晶场中自旋为3/2的Ising模型中,对于蜂窝点阵晶格来说,系统相变没有三相点,而正方点阵、简立方点阵晶格却有三相点的存在。

The structure of ITO films prepared on flexible substrate for different concentration of SnO2 is polycrystalline bixbyite, the crystal lattice parameter of films increases and distortion of crystal lattice is more obvious with the increasing of SnO2 concentration.

用不同掺杂比例的靶材制备的薄膜均为多晶纤锌矿结构,掺杂比例增大,样品的晶格常数变大,晶格畸变明显。

What makes minerals special is the way that the atoms of those elements are arranged in lattices which create unique crystalline structures and shapes.

矿物质的特别之处在于这些元素中的原子形成的晶格,而晶格创造了独特的晶状结构和形状。

What makes minerals special is the way that the atoms of those elements are arranged in lattices which create unique crystalline structures and shapes.

使矿物特别的是那些元素原子按晶格排列的方式,晶格创造了独特的晶状结构和形状。

Results show that when the thickness is less than 0.7 nm, Si3N4, normally amorphous in deposition state, could form a NaCl-type pseduocrystal structure due to the template effect of TiN crystal layer. Crystallized Si3N4 layers and TiN template layers grow coherently into columnar crystals with (111) preferred orientation. Correspondingly, the hardness of the films was enhanced to a maxim value of 38.5 GPa, showing a superhardness effect.

结果表明,在TiN调制层晶体结构的模板作用下,溅射态以非晶存在的Si3N4层在其厚度小于0.7 nm时被强制晶化为NaCl结构的赝晶体,多层膜形成共格外延生长的(111)择优取向超晶格柱状晶,并相应产生硬度显著升高的超硬效应,最高硬度达到38.5 GPa。

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