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晶核形成

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The effects of the decarburization of the base metal on bubble formation in enamel coating, the relationship between hardness and firing temperature and time, the effect of crystal nucleus addition and influence of adding adhesive agent .

研究了搪瓷层的硬度与烧结时间和温度的关系,并分析了添加晶核形成剂对搪瓷层硬度的影响,以及搪瓷原料组成中的密着剂对搪瓷层和金属基板密着性能的影响。

When TiO〓 content is increased, the surfacial energy formed by crystals may be reduced, the devitrification degree, strengthened and the content of wollastonite in crystal phase raised; if Cr〓O3〓 content is increased, the crystal size is enlarged, and the content of diopside in crystal phase, raised; if the sulphide content is increased; the reduction atmosphere is heightened and the content of wollastonite become bigger.

晶核剂浓度研究表明,晶核剂浓度不同,对基础玻璃析晶强度,晶相含量和晶体尺寸有一定的影响,当TiO〓含量增加时,可以降低晶体形成的表面能,析晶强度增大,晶相中硅灰石含量增多;Cr〓O〓含量增加,晶体尺寸增大,晶相中透辉石含量增加;硫化物增多,还原气氛增大,同时硅灰石含量增多。

Under the high frequency vibrating action, the crystal grain formed on the surface of the crystal nucleus eradiation equipment would be broken and peeled off, thereby ejected to zinc molten pool continuously and served as crystal nucleus source of equiaxed grain during solidification.

结果表明,当一种带有冷却结构且进行高频振动的晶核发射器插入锌液内时,锌液在晶核发射器表面迅速形核且长大,在高频振动作用下表面形成的晶粒将被折断剥离,从而连续不断地弹射到锌液中,成为凝固过程中形成大量等轴晶的晶核来源;采用带有水冷和气冷结构的晶核发射器对锌液进行振动激发形核处理后,锌凝固组织中的等轴晶率可分别提高到65%和80%。

The sloping plate can provide sufficiently the under-cooling for nucleation and lay a foundation for heterogeneous nucleation to form lots of nuclei of crystal internally and on the sloping plate surface, thus causing the melt to nucleates eruptively. Under the action of both metal flow and vibration, the nuclei formed on the sloping plate surface can move freely and disperse into the melt, and they are able to maintain the direct growth in spherical shape in the homogeneous composition and temperature fields.

倾斜板为形核提供足够大的过冷度和异质形核基础,大量晶核在斜板表面和内部形成,使熔体爆发形核,在流动和振动作用下斜板表面形成的晶核游离,弥散到熔体内部,晶核在均匀的成分场与温度场条件下,可以保持直接球状生长。

The antimony in the lead alloy inhibits significantly the nucleation and growth of lead dioxide crystals.

合金中的锑能使二氧化铅晶核形成和生长速率显著降低。

The combination of these additives can increase the overpotential and nucleation rate of zinc electrodeposition markedly, which gives rise to the grain refinement of zinc deposits.

镀层晶粒细化的主要原因在于混合添加剂可有效提高锌的沉积过电位,使锌沉积过程中的晶核形成速率增大。

Through the experiments on hydration of AH in the following sulphate(Li_2SO_4、MgSO_4 、 Al_2(SO_4)_3 、MnSO_4 、CuSO_4 、CoSO4 、CdSO_4 、ZnSO_4 、NiSO_4 、FeSO_4), dissoluble sulfate hydrate origining from hydration process of AH affects it's hydrous rate, hydrous rate of AH does not connect with Z/R of cation in stimulation, theory that Z/R affect hydrous rate of AH does not exist. Third, hydration of AH in dissoluble sulfate complies with dissolve-nucleate -grow theory, concentration of Ca~2+ from dissolving of CaSO_4 is higher than one of CaSO_4·2H_2O, calcium sulphate dihydrite gets a motivity of crystallization. dissoluble sulfate takes the following function: double-salt or dissoluble sulfate hydrate from hydration of AH in it becomes heterogeneous particle and a kind of nucleation catalyzer, and reduces surface barrier when DH becomes crystal because the crystal of DH precedently appears in uneven place. Results indicate hydration of AH does not conform with double-salt theory, but it conform with this mechanism: dissolve-nucleate-grow, formation of DH is an uneven nucleation and crystalizaion process.

通过对CaSO_4在Na_2SO_4 、K_2SO_4 、Rb_2SO_4 、Cs_2SO_4 、(NH_4)_2SO_4溶液中水化过程,以及CaSO_4·2H_2O、CaSO_4与以上硫酸盐反应速度、产物的研究,说明复盐理论不正确;CaSO_4在(Li_2SO_4、MgSO_4 、 Al_2(SO_4)_3 、MnSO_4 、CuSO_4 、CoSO_4 、CdSO_4 、ZnSO_4 、NiSO_4 、FeSO_4)溶液中水化,水化过程中硫酸盐水合物的析晶影响着无水硫酸钙水化,与激发剂阳离子Z/R值大小无关,阳离子的Z/R参数影响水化率的规律并不存在; 3、无水硫酸钙在可溶性硫酸盐中的水化按照溶解-成核-生长理论进行,CaSO_4达到溶解平衡时Ca~2+的浓度大于CaSO_4·2H_2O溶解平衡的Ca~2+的浓度,CaSO_4·2H_2O获得结晶的驱动力,可溶性硫酸盐起到形成晶核的作用:水化过程与CaSO_4生成复盐或析出水合物所形成的细小物相,作为异质微粒使母相中存在不均匀性,这些不均匀性有效地降低成核时的表面能位垒,使CaSO_4·2H_2O晶核优先地在这些具不均匀性的地方形成,因此这些物质起成核催化剂作用。

Most significantly the site provides a number of slide images on the following subjects: Isograds and chemical reactions in regional metamorphism, chemical reactions in rocks, interplay of nucleation and growth, the origin of porphyroblasts, crystal size distributions, feedback mechanisms, the metamorphic aureole of the Bushveld Complex and reconciling theory and observation, the critical overstep for andalusite growth.

网站还提供了一些重要的幻灯片图片,内容涉及到:等变质级、局部变质化学反应、岩石化学反应、晶核形成与发育的相互关系、斑状变晶起源、晶体大小分类及红柱石发育限度评估。

The formation of the composite microspheres is explained by the nucleation of silver on the surface of the latices followed by growth of the silver shell.

复合微球的形成机理可解释为:Ag纳米微晶首先在共聚物表面形成晶核,随后Ag纳米粒子在晶核表面生长并形成不同厚度的Ag壳层。

The inhibition is due to its participation in the formation of crystal core of calcium carbonate which inhibits the growth of crystal core.

其抑制作用是铜离子参与碳酸钙晶核形成,阻止晶核生长。

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