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The prepared powders were characterized by XRD, UV-Vis, FTIR, N_2 adsorption, Fluorescence spectroscopy, etc. N-doped TiO_2 evidently shows its absorbance shoulder shift into visible light region. Moreover, N-doping retards the transition of TiO_2 from anatase to rutile type as well as restrains the growth of the crystal size which leads to less decrease of surface area. These characteristics are considered to benefit the photoactivity of TiO_2; When all the samples were applied to the photodecomposition of Methylene Blue under visible light(λ>400 nm), the N-doped TiO_2 show an obvious superiority when compared to the undoped TiO_2, the active hydroxyl groups are found to play a important role in this high photoactivity; When the same experiment was performed under UV light, all the samples show the consistent sequence of photoactivity as in the visible light.

通过UV-Vis、XRD、BET、IR、FL等表征手段测试表明:掺氮不仅使TiO_2的光吸收区域拓展到可见光区,而且有利于延缓TiO_2晶相的转换,从而抑止了高温煅烧下所引起的晶粒增大以及比表面积的降低,且氮源浓度越高,此现象越明显,这些特征都有利于催化剂光催化活性的提高;在主波长大于400nm的可见光催化亚甲基蓝实验当中,掺氮TiO_2的光催化活性明显优越于未掺氮样品,亚甲基蓝在90min内达到88%的脱色率。

The results show that dynamic softening is easy to occur in these ingots and flow stress becomes steady finally; the material constants of hot deformation are procedural parameters that stress-level coefficient α, strain rate sensibility exponent m and deformation activation energy Q are all increased with strain increasing, while stress exponent n is decreased gradually; the values α and m of the alloy homogenized are the biggest and the value n is the smallest, dynamic softening effect of the alloy is the most obvious, which can deform evenly; influence of strain on the value Q of the alloy homogenized is a little and the average value of Q is only 176.5kJ/mol, so the alloy is easy to deform; the alloy matrix shows the regular recrystallization grains when the strain is 50%; dislocation cell structure re-formed in the grains with increase of strain.

结果表明:经不同处理的Al-1Mn-1Mg合金均易发生动态软化并最终呈现稳态流变特征;热变形材料常数是过程量,随应变量的增加,应力水平参数α、应变速率敏感性指数m和热变形激活能 Q 随之增大,而应力指数 n 则逐渐减小;均匀化退火后,铝合金的α和m值最大而n值最小,动态软化效果最明显且变形均匀,在该状态下,铝合金的 Q 值受变形量影响小,平均仅为176.5kJ/mol,易进行热变形;当应变量为0.7时,基体呈现规则的再结晶晶粒组织,随着应变量的增加,晶内重新形成了位错胞结构。

Numerical simulations show that this self-adjusting algorithm is more flexible and effective than other existing algorithms, and more ideal results can be gained in a much shorter time.

数值模拟结果表明,自调整方法是一种高效灵活的专用于设计一维光学超晶格的优化算法,与其他优化算法相比,自调整方法能在更短的时间内搜索出更理想的优化结果。

Otherwise, in this paper, the random walk of particles is processed on lattices of graphite in a layer i.e. hexangular lattices, which makes our study have some physical background. Thus our results have some instructional function theoretically on the study of graphite and benzenoid hydrocarbon.

另外,在本论文中,我们所研究的粒子是在石墨一层内的晶格即六角格子上的行走,这就使本文的研究具有一定的物理背景,从而对石墨和苯型烃的研究工作具有一定的理论指导作用和意义。

The results indicate that the pillaring process and crystal growing of anatase can be more easily realized by increasing the acid-base ratio of pillaring agents, raising the pillaring temperature and adding proper quantities of alkali. The calcination of Ti-pillared precursor brings the growth of TiO2 grain, at the same time the layer distance is declined. In order to obtain ideal products, the right pillaring conditions are: the acid-base ratio of pillaring agents of 13, pillaring temperature of 65 ℃ and the volume of alkali (2 mol/L) in pillaring liquid of 6 mL.

结果表明:在一定范围内增大柱撑剂酸碱比、提高柱撑温度以及加入适量碱,有利于插层复合反应的进行和锐钛晶型的生长;柱撑前驱物焙烧后TiO2晶粒长大,同时焙烧引起的脱水导致膨润土层间距的下降;为获得较理想的产物,合适的柱化条件为:柱撑剂酸碱比 n n (HNO3)为13、柱撑温度65 ℃和柱撑液加碱量为(2 mol/L NaOH) 6 mL。

Compared to the sample without ultrasonic treatment, it was found that, for AZ31 magnesium melt alloy treated by ultrasonic, the refined grain size and the inproved distribution of grain with its shape of oval-shaped or spherical can be obtained, and the precipitation inside Al matrix was inhibited The Mg17 Al12 precipitates distributed mainly along the grain boundary and hardness was improved remarkedly.

通过对铁合金AZ31进行熔体超声处理发现,处理后试样的晶粒较未进行超声处理的试样有明显细化,分布均匀程度提高,形状呈椭圆状或球状,合金元素Al在晶粒内的析出被抑制,Mg17Al12第二相的析出主要集中于晶界,硬度有明显提高,并且通过试验确定出了最佳处理功率和时间,为超声波在铸造生产中的应用提供了依据。

The characterization of the coked catalyst shows that the deactivation of catalysts is caused by a jam of bulkier molecules, which are the alkylbenzenes from both reactants and products, so the deactivation cannot be avoided.

苯与长链烯烃的烷基化反应过程中,β沸石催化剂的失活是由于产品直链烷基苯本身和原料中带入的杂质芳烃逐渐堵塞孔道、阻止了反应物分子接近活性中心引起的,是由晶内开始逐渐向外发展的。

Acicular ferrite microstructure in micro-alloyed steels, which nucleates around non-metallic inclusions, especially oxide inclusions, has high strength and good toughness and possesses strong grain-refining ability by itself. The ultra-fine grained steel with excellent weldability is likely to be produced by forming in materials a great number of fine and dispersive micro-inclusions which is helpful to induce AF to nucleate around them through oxide metallurgy technology.

微合金钢针状铁素体组织强度高、韧性好,在奥氏体晶内非金属夹杂物上诱导形核,具有很强的自身细化晶粒的能力,通过氧化物冶金技术控制钢铁材料形成大量细小、弥散,具有诱导AF形核能力的有益微夹杂物,有望获得焊接性能优良的超细晶粒钢。

For thin polycrystalline films, especially those with columnar structure, once the diameter of grains on the film surface is larger than the film thickness, the total area of above and under basal planes (film-substrate interface) will be larger than that of side plane. And if the film precipitates on the substrate with thermal expansion coefficient different from that of the film, great thermal stress will be introduced during annealing.

对于薄膜特别是柱状晶薄膜,当晶粒在膜平面内的尺寸大于膜厚时,柱状晶粒的上底面和下底面的面积将大于侧面的面积,如果薄膜还附着在与其热胀系数不同的基体上并在不同于沉积温度的条件下退火时,膜中将存在较大的热应力。

The calculational results show that on one hand,the phosphorus atom only affect the bondings of a few atoms of its vicinity,the conductivity increases as the doped concentration increases; while on the other hand ,the doped concentration is higher,the integrity of the diamond lattices are much worse.

计算的结果表明,一方面,磷原子只对它附近的几个原子内的成键有影响,电导率随着掺杂浓度的增加而增加;而另一方面,金刚石晶格的完整性则随着掺杂浓度的增加而降低。

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