晶内的

The results showed that the TiN andN films are polycrystalline phase. The properties and structure of TiN films are mainly determined by the N2 mass flow rate, and as the N2 mass flow rate increases, the structure of the TiN films transforms to f.c.c. type leading to better the properties of films. The presence of negative bias voltage can optimize the grain of TiN films, lower the defect proportion and denser the films, which improves the hardness of films. The TiN films conform to the free carrier absorption mechanism and there are many of free electrons with lower N content in TiN films. With the increase of N content, the quantity of free electrons and reflectivity of films decrease, and the plasma frequence shifts to the lower energy, which leads to the regular change of colors of films from silver, yellowy, golden to yellow-red, meanwhile the lightness of films decreases. The goldenN film consists of TiN and ZrN phase, but belongs to a sigle f.c.c. structure with (111) preferred orientation. The Zr-doping dosen't change the position of the valance band, conduction band and forbidden band ofN film, but leads to the presence of new energy levels, which is the reason thatN film remains golden. The transparent hard films with good corrosion resistance and high hardness have been prepared and the further reseachs showed that the grain size of those films is by far smaller than the wave length and the width of forbidden band of those films is very broad, is the reasons that those films are transparent.

研究表明：氮化钛和N 薄膜为多晶态，氮流量决定了氮化钛薄膜的结构和性能，增加氮流量能使氮化钛薄膜的结构向面心立方结构转变，从而得到性能良好的氮化钛薄膜；施加负偏压能优化氮化钛晶粒和减少薄膜中的缺陷，使膜层变得更致密，从而提高薄膜硬度；氮化钛主要遵循自由载流子光吸收，氮含量较少时薄膜中的自由电子数目较多，随着氮含量的增加，薄膜中的自由电子数目不断减少，反射率逐渐降低，等离子体频率向低能端移动，从而使薄膜颜色出现规律变化，由金属色银白色到淡黄、金黄再到红黄，并且薄膜亮度呈下降趋势；金黄色的N 薄膜中存在TiN 和ZrN 的分离相，但其为单一的面心立方结构并具有(111)面择优取向；相对于TiN 薄膜，Zr 掺杂后，并没有使薄膜的导带、价带和禁带发生变化，只是在TiN 禁带内增加了新能级，这也正是掺杂Zr 后，薄膜仍

Low temperature ordering of FePt thin films has been achieved by using a thin equiatomic AuCu underlayer.

提出并利用相干生长的多层膜中有序－无序转变过程的彼此关联作用，借助AuCu缓冲层的低温有序化，降低FePt薄膜的有序转变温度200℃以上，为FePt薄膜的低温有序化开劈了一条新途径；制备多层膜，退火形成有序相FePt纳米颗粒分散在Ag基体的复合结构，比FePt/Ag共溅射或合金多层膜方法的退火温度明显降低；通过缓冲层Ta控制FePt的粗糙度和晶界密度，同时界面附近Ta、Pt发生化学反应，两者共同促进薄膜内Pt原子的有效迁移，从而加速FePt有序化；进一步，在Ta和FePt之间插入Bi薄层，强化Ta、Pt的扩散，在更低温度下形成高矫顽力的有序化FePt薄膜且FePt晶粒之间交换作用大大减弱；发现MgO薄膜作底层，可控制与MgO晶粒尺寸大致相当的临界厚度以下的FePt有序化薄膜的（001）取向，同时，MgO和FePt的相对厚度显著影响（001）取向FePt的有序化。

The results showed that (1) The grain size of nanometer YiO_2 was40～80nm.The wavelength corresponding to the maximum absorbency values were observedin the 200～320nm range.The crystal structure of carbon doped TiO_2 photocatalyst is primarilyanatase(22.43% rutile), and the content of carbon is about 4.6%.(2) The relative humidityvaring from 8% to 80%, the photocatalytic degradation degree of benzene increased withincreasing relative humidity; and to toluene, degradation rate was hanced by relative humidityup to 60%, and more or less inhibited above 60%.(3) Scheme and results of orthogonal testswere used by evaluating the photocatalytic performance of the gas phase methanol, acetoneand 1-heptane.The results revealed that their degradation degree reached 84.5%, 93.39% and93.45%, respectively.(4) The 254nm UV lamp showed higher photocatalytic degradation rate.For methanol, acetone and 1-heptane, it was found that photocatalytic degradation reactionoccurs with the light strength of daylight lamp.(5) Under the the same conditions, 15%degradation degree has been obtained for benzene, whilst about 10% degradation degree wasattained by Degussa P25; During the initial phases, the toluene revealed higher photocatalyticactivity, comparing with Degussa P25, the degradation degree of methanol, acetone and1-heptane were slightly lower.

结果表明：(1)CVD法制备的纳米TiO_2光催化剂，颗粒球形度好、粒径在40～80nm之间；最大吸光度值所对应的波长为200～320nm；含碳量约为4.6％；晶型组成主要为锐钛矿型，金红石的含量约为22.43％；(2)在相对湿度为8％～80％范围内，苯的光催化降解率随着相对湿度的增大而增大；甲苯在相对湿度为60％时达到最好降解效果，当相对湿度增大到80％时光催化效果降低；(3)将正交实验设计及实验方案应用于气相甲醇、丙酮和正庚烷光催化降解研究，实验结果表明：三者最高降解率分别为84.5％、93.39％和93.45％；(4)有254nm紫外灯参与的光催化实验可以大大提高有机气体的光催化降解率；在日光灯的照射下，掺碳纳米TiO_2对气相甲醇、丙酮和正庚烷具有一定的光催化氧化能力；(5)较P25粉，在相同的光催化操作条件下：气相苯的平均降解率达15％，高于P25粉10％的降解率；气相甲苯在初始阶段具有较高的反应速率；气相甲醇、丙酮和正庚烷的降解率略低于P25粉。

Capillary phenomena was studied and discussed by the scholars about 200 years ago, but the progress was slow due to the limited equipments and manufacture precision of the microchannel.In recent years, because of the rapid development of MEMS and micromachining, many applications of the capillary flow is widely developing in some modern processes, such as underfilling of flip chip, flow in microfluidic chip or biochip, and a variety of other fields.

摘要 毛细现象大约在200年前便断断续续被欧美学者所研究讨论，但由於当时微细加工受到仪器设备和制造精度的限制，因此发展极为缓慢；近年来由於微机电系统与微细加工之精进，许多具有微流道的应用设备，陆续被制作问世，加上光学显微镜与影像撷取设备的普遍，对於研究此课题的推展极有助益；且随著微生医、覆晶底胶充填与微流体系统等领域之受到重视，毛细现象导致的充填问题、驱动原理及液体流动的控制，都变得相当的重要；本研究基於如此的动机与目的，进行微流道内液体之毛细流动现象及时间的探讨。

To provide for the punishment of counterfeiting the securities and current coin of the United States; To establish post offices and post roads; To promote the progress of science and useful arts, by securing for limited times to authors and inventors the exclusive right to their respective writings and discoveries; To constitute tribunals inferior to the Supreme Court; To define and punish piracies and felonies committed on the high seas, and offenses against the law of nations; To declare war, grant letters of marque and reprisal, and make rules concerning captures on land and water; To raise and support armies, but no appropriation of money to that use shall be for a longer term than two years; To provide and maintain a navy; To make rules for the government and regulation of the land and naval forces; To provide for calling forth the militia to execute the laws of the union, suppress insurrections and repel invasions; To provide for organizing, arming, and disciplining, the militia, and for governing such part of them as may be employed in the service of the United States, reserving to the states respectively, the appointment of the officers, and the authority of training the militia according to the discipline prescribed by Congress

制定对伪造合众国证券和货币的惩罚条例；设立邮政局及延造驿路；为促进科学和实用技艺的进步，对作家和发明家的著作和发明，在一定期限内给予专利权的保障；设置最高法院以下的各级法院；界定并惩罚海盗罪、在公海所犯的重罪和违背国际公法的罪行；宣战，对民用船苹颁发捕押敌船及采取报复行动的特许证，制定在陆地和海面虏获战利晶的规则；募集和维持陆军，但每次拨充该项费用的款项，其有效期不得超过两年；配备和保持海军；制定有开管理和控制陆海军队的各种条例；制定召集民兵的条例，以便执行联邦法律，镇压叛乱和击退侵略；规定民兵的组织、装备和训练，以及民兵为合众国服务时的管理办法，但各州保留其军官任命权，和依照国会规定的条例训练其民团的权力

In range of 300℃～900℃, all the transition metal oxide catalysts could get high ammonia conversion, during the initial stages of the reaction, the SO〓 conversion is relatively low since the catalysts have not been sulfureted, but it increases gradually and attain constant with rising temperature and time continuance,〓 is better than other catalysts in reactivity and elemental sulfur selectivity; XRD indicates that, in the SO〓-SCR process, stable transition metal sulfide is generated which is very important to SO〓 reduction and transition metal sulfide probably is the active phase of catalyst, further the reduction of SO〓 by H〓 to H〓S is the limiting step of all process, then the activity is somewhat related to its lattice oxygen yet not so notable; XPS indicates that little sulfur on surface exists as S〓 in sulfate, showing that TiO〓 could restrain the generation of sulfate.

对于过渡金属氧化物催化剂的研究发现，在300℃～900℃范围内，不同的催化剂均可获得很高的NH〓转化率，反应初期由于催化剂还未硫化，所以SO〓的转化率较低，随着温度升高和反应时间的延续，SO〓的转化率逐渐升高并达到了稳定值；七种过渡金属氧化物中，以〓对于NH〓还原SO〓反应的活性和选择性最好；XRD结果表明在NH〓-SO〓反应后生成了稳定的硫化物相，硫化物对SO〓的还原过程具有重要作用，催化剂的活性相可能是过渡金属硫化物，而且在硫化物催化剂上进行的H〓还原SO〓生成H〓S的反应是整个过程的速率控制步骤，所以催化剂的活性与其自身的晶格氧的氧化还原能力有一定的联系，但关系不明显；XPS结果表明催化剂表面的硫大部分以过渡金属硫化物的形式存在，只生成少量的S〓，说明TiO〓催化剂能够较好的抑制硫酸盐的生成。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了