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Nd and Y showed more evident effects than Gd and La due to lower temperature of eutectic reaction with aluminum. In order to investigate mechanism of the formation of the intercellular dispersoid which is being in debate and possibility of suppressing the dispersoid, a nucleation kinetic model which including unsteady nucleation and effect of alloy element was established.

Al-Fe-Mo-Si-Zr-Ti合金粉末具有四种凝固组织,初生Al〓〓,α-Al与Al〓共晶,胞晶及显微胞晶,合金元素Mo的加入,显著提高合金粉末凝固前的过冷度,使10~40μm粉末的凝固机制发生了变化,由导热控制型转变成溶质扩散控制型,从而基本上消除了该尺寸范围内粉末凝固组织中共晶成分和初生相,但对大于40μm的粉末,因共晶区富Zr核心的优先形成而使Mo的作用效果不明显。

The apatite with end-member cations, the apatite solid solutions [M-M1 AP] withdivalent cations substitution, the fluorapatite and the chlorapatite with end-memberations, the apatite solid solutions [Xi-X2 AP] with column-ions substitution were synthesizedthrough " solid-phase reaction method" in inert gas.

对不同Ca/P摩尔比HAP来说,在1.2≤R≤2.3范围内,随R值偏离正常配比程度的增大,其比表面积增大、晶粒尺寸ΓA,Γ(221,ΓR减小、晶形指数降低、结晶度减小、晶格缺陷度增大;当R=2.5时,晶粒尺寸和结晶度反而增大,出现反常,但晶格缺陷度却保持有规律增加。

Through the analysis of characteristics in curve of deformation tests on the four kinds of rockmasses such as claystone, siltstone, feldspar-quartz sandstone and lithic sandstone underlain the dam foundation of Tingzikou Hydropower Station, it is thought that: the test deformation of thick lithic sandstone is mainly caused by slippage deformation of rock crystal lattice ; the test deformation of feldspar-quartz sandstone is mainly from small crevices in rock, compressive deformation of rock small holes and slippage deformation of rock crystal lattice; and the test deformation of thin layer claystone in which horizontal layer is developed and siltstone is mainly from compression deformation in interlayer, small crevices in rock, compression deformation of rock small holes and slippage deformation of rock crystal lattice.

通过对亭子口水利枢纽工程坝基下卧的黏土岩、粉砂岩、长石石英砂岩和岩屑砂岩等 4 种主要岩性的岩体变形试验曲线特征进行分析,认为:厚层岩屑砂岩的试验变形量主要来自于岩石晶格错动变形,长石石英砂岩的试验变形量主要为岩石内孔隙和空隙变形以及岩石晶格错动产生的变形,而层理较发育的薄层黏土岩和粉砂岩的试验变形量主要由层间压缩变形、岩石内孔隙和空隙变形以及岩石晶格错动产生的变形共同组成。

By adding ZrO2(4Y) to the thermit,the influences of centrifugal force and eutectic composition on the microstructure,mechanical properties, strengthening and toughening of ceramics lining are researched.

基于燃烧合成理论,在铝热剂中添加ZrO2(4Y)粉末,采用离心技术制备出了高强度、高韧性的Al2O3/YSZ共晶系陶瓷内衬复合管,并研究了离心力、共晶成分对陶瓷内衬显微结构、力学性能及强韧化本质的影响。

The results show that the effect of addition or no-addition of degasser on grain refinement of Al-5.0%Si alloy ingot is...

结果表明,除气剂的添加与否对Al-5%Si合金铸锭组织的细化没有影响,铸锭由粗大的柱状晶组织构成;采用合适的超声波处理时间,Al-5%Si合金铸锭的等轴晶获得率大幅度提高,可使整个铸锭组织变为细化的等轴晶组织;超声波振动时间过长将导致铸锭内气孔的增加;根据克劳修斯-克拉柏龙方程,某一强度的超声波引起的压力冲击波作用,导致液相转变为固相,引起了超声波的细晶作用。

Heat flows derived from garnet, chromite/chromium-spinel and pyroxene of xenoliths, xenocrysts in Mengyin and Fuxian kimberlites are higher than 40mW/m〓 calculated from the pyroxene inclusions in diamonds, and the range of pressure is 20~40kb (equivalent to 65~130km). Metasomatism (as indicated by yimengite and lindsleyite in Mengyin) is very strong in this depth range. Lherzolite, wehrlite, and diamond-free high-Ca harzburigite around the world are derived from this depth also. The observation suggests that the low-Ca harzburigitic environment for diamond stability had been changed significantly when the kimberlitic magmas erupted. This resulted from fluid interaction with harzburigite. The geotherm of the Cenozoic lithospheric mantle beneath Eastern-North China platform is higher than oceanic one. The temperature from the interior of the Tan-Lu faults is higher than that from apart off the fault.

除金刚石中的辉石温压投点落于40m W/m〓占地温线上外,捕虏体及捕虏晶中石榴石,铬尖晶石及单斜辉石的投点均偏离该地温线,显示较高的地温特点,而且捕虏体及捕虏晶的压力范围多在20-40kb(相当于65-130km)间,该深度范围内地幔的交代作用特别发育,如蒙阴大量发育的沂蒙矿、钛钾铬石等就发育于该深度范围,世界范围内不含金刚石的高钙方辉橄榄岩、二辉橄榄岩、异剥橄榄岩也分布于该区中,一方面表明捕虏体的主要取样位置已不在金刚石稳定区中,另一方面也表明金刚石稳定的橄榄岩环境,在金伯利岩侵位并捕虏他们时已发现了明显的改造,这种改造作用主要是通过长期的熔流体与先存的橄榄岩相互作用的结果。

The Changxing Formation reservoirs are mainly a set of reef dolomite, sparry oolitic dolomite, and have moderate to high porosity, moderate to high permeability and good physical properties. The reservoir space types are mainly intercrystalline pore, intercrystalline solution pore, intergranular dissolved pore, intragranular dissolved pore, moldic pore and dissolved expanding pore, and to a lesser extent, crack and suture.

长兴组储层主要为一套礁白云岩、亮晶鲕粒云岩和残余颗粒云岩,以高中孔、中高渗,孔隙型储层为主,储集空间类型以晶间孔、晶间溶孔、粒间溶孔、粒内溶孔、铸模孔以及溶蚀扩大孔为主,裂缝和压溶缝合线次之,具有较好的物性特征。

Furthermore,polarized optical microscopy indicated that SPCL exhibits irregular spherulites with poor morphology and apparently slower crystallization rate,whereas LPCL shows fast crystallization rate and good spherulitic morphology.

POM观察聚己内酯的等温结晶形态,发现星形聚己内酯和相近分子量的线形聚己内酯相比,前者具有不规则的球晶形态和较慢的结晶速度,而后者表现出较快的结晶速度和规则的球晶形态。

Research result indicated that the cooperative effect between swell and precursor is main factor for the nanoparticle loaded in Nafion, and moreover, polarity of solvent and water content in Nafion also affects the load largely. To improve away the surface concentration of CdS nanocrystal on two side of membrane for general preparation, thioacetamide was first used as a precursor instead of inorganic sulfur source(H2S and Na2S) in synthesis of CdS nanocrystal. The assembly mechanism for several sulfur source had been studied, and CdS/Nafion with the character of homogeneous disperse had been prepared, which is fit for mass transmission in photocatalitic reaction. Following the investigation of several crystallizing way, simple and reliable hydrothermal-crystallizing was found. According to this way, maximal TiO2 load in Nafion achieved 43%. Activity of TiO2/Nafion or CdS/Nafion as a photocatalyst was explored initially for disintegrating liquid contamination. Maximal decompose rate achieved 86% under condition of this research.

研究结果表明:Nafion膜对纳米粒子负载量的主要影响因素是溶胀作用与前驱体协同效应,同时溶剂极性和薄膜含水量对负载量也影响相当大;本课题首次使用硫代乙酰胺代替传统无机硫源(H2S、Na2S)合成CdS纳晶,研究了各种硫源的组装机理,克服了常规技术存在的CdS纳晶趋于膜表面富集的缺点,得到了有利于光催化传质需要的体相均匀分布CdS/Nafion;研究了多种Nafion膜内纳米粒子晶化途径,找到了简单可靠的水热晶化法,TiO2纳晶最高负载量达43%;初步探索了TiO2/Nafion、CdS/Nafion作为光催化剂降解水中模拟污染物的活性,在本实验条件下最高降解率达86%。

At 1273K, the density of dislocations were considerably decreased in deformed TiAlMnNb alloy, twinning and 11 superdislocations were hardly observed, but few 1/212 superdislocations and 01 perfect dislocations were found in deformed TiAlMnNb alloy. In high temperature range, brittle-to ductile transition had already occurred in deformed TiAlMnNb alloy, unpinning and climbing were the dominant deformation behavior in TiAlMnNb alloy. In the same way as TiAlMnNb alloy, different distinguishing feature the dislocation configuration at low, intermediate and high temperatures emerged in deformed TiAlMnNbB alloy.

在中温区域,合金中位错组态变化可分为两个小区域,在673K以下,合金的位错组态有孪晶、1/210单位位错和少量的11超点阵位错;这一温度区间内孪晶和位错密度都大大提高,不同系统的孪晶相互交割阻碍了孪生的继续发展,不同方向的位错相互交割阻碍位错进一步滑移,同时孪晶界面也阻碍了位错的运动。

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