晶体学

Completely different crystal structures and morphology were shown in the meltdrawn films of two kinds of tacticity of sPP. A continuous conformational transform from the 〓 into the of sPP was induced by further stretching. While the zigzag conformation can retransform back to helical 〓 one after annealing above 80℃, the mechanism of conformation transform has been introduced.

Petermann教授学科专业高分子化学与物理研究领域\研究方向学位级别博士学位授予单位中国科学院长春应用化学研究所学位授予日期2001 论文页码总数114页关键词聚丙烯聚丁烯共聚物聚α-烯烃馆藏号BSLW /2003 /O632 /3 用电子显微学、电子衍射、DSC和FTIR等技术对聚α-烯烃及其共聚物的晶体结构和相转变行为进行了系统地研究，包括间同立构聚丙烯、全同立构和间同立构聚丁烯-1（iPB-1，sPB-1）、以及丙烯-丁烯-1间同立构共聚物。

But the electrochemical results show that complexes exhibitcompletely irreversible redox behaviour which is different from thatfound in diiron proteins. 1.3 To obtain the diiron species which are stable to elec-trochemical reduction, a series of new tetranuclear cage ironspecies containing two 〓 cores, with using hexadentatepolybenzimidazole ligands, were synthesized and characterized by vari-ous spectroscopic methods. Their physical properties have been investi-gated. The crystal structures of 〓〓tetrakis (benzimidazol-2-ylmethyl)-1, 4-diaminobutane and 〓,〓-tetrakis ( N-ethylbenzimidazol-2-ylmethyl )-1, 4-diaminobutane were determined. They contain two 〓 cores which arelinked to each other by -〓-chain in the ligands.

1.3为了获得电化学还原稳定双核氧桥联Fe化合物，使用六齿配体合成了一系列含有两个〓单元四核笼状化合物，并用各种谱学手段表征了它们，还研究了它们的物理化学性质确定了〓L=N，N，N'，N'-四(苯骈咪唑基-1，4-丁二胺和〓，〓四-1，4-丁二胺化合物的晶体结构，它们含有两个〓单元，其中两个〓单元是通过配体的〓链桥联成四核笼状结构。

The crystal consists of two similar but independent molecules in the asymmetric unit and the Ce ion coordinated toward ten donor atoms, six of which belong to the nitrogen atoms of two tridentate ligands and four oxygen atoms from two bidentate picrates.

晶体中一个不对称单元内有两个结晶学上独立的分子，这两个分子的构型基本相同，中心Ce3＋均与两个三齿配位的配体及两个双齿配位的苦味酸根配位，配位数为10。

Meanwhile, some progress has been made in the HREM image processing technique, and in the traditional trial-and-error method as well, for crystal structure analysis.

对高分辨电子显微学晶体结构分析的图像处理技术及传统的尝试法作了一定的发展： 1。

In this project, the selection criteria of matrix and reinforcement for obtaining composites with high strength and toughness are determined. The as-cast and aged microstructures of composites reinforced with particles of different strength are observed, and their metallurgical conditions and stabilization mechanisms are analyzed. The aging precipitation behaviors and mechanisms are studied. Some characteristics of nano-materials (micro-distortion areas) are found in 150nm- Al2O3p/Al composites and their formation mechanisms are expatiated. The "flexible" restriction to the deformation of the matrix by low strength AlN particle is observed by in-situ TEM and SEM techniques, and the mechanisms of its resist on cracks propagation and its contribution to composite strength are revealed. The high temperature deformation behaviors of Al2O3p/Al composites are studied. A rare-earth coating is established on sub-micron Al2O3 particles, leading to an improvement in wettability between coated Al2O3 and liquid aluminum and a decrease in infiltration pressure. The strength and ductility of coated particles reinforced composite are also increased. The interfacial characteristics, bonding structures and their formation mechanisms are studied, and the crystal orientation relationships between reinforcement particles and aluminum matrix are investigated. Finally a lighter composite with better balance of strength and damping properties is reinforced with hollow ceramic microballoons of ultra-lower strength.

本项目发现了获得高强度和高韧性复合材料的基体、增强体选择依据；观察了各种强度质点增强复合材料的铸态和时效态微观组织，分析其微观结构形成的金属学条件及稳定性机理，研究了其时效析出规律和时效机制，发现了150nmAl2O3颗粒增强铝基复合材料基体中的纳米材料特征，并解释了其形成机理；利用TEM和SEM动态拉伸技术发现了低强度质点AlN颗粒对变形协调的&柔性强化&机制，揭示了其对裂纹扩展的阻碍作用和对复合材料高强度的贡献；研究了中强度质点的Al2O3颗粒增强铝基复合材料的高温变形行为，并对其进行了稀土界面层设计与制备，改善了颗粒与铝合金之间的界面润湿性，降低了复合材料铸造渗透压力，提高了复合材料的强、韧性；研究了多种复合材料界面结构及形成机理，确定了增强体与基体之间的界面结合机制，分析了复合材料界面处的晶体学位向关系；最后制备了含微孔的中空型陶瓷颗粒增强的特种复合材料，得到了强度和阻尼综合性能较好的轻质复合材料。

Studies of beryls from Xuebaoding by means of crystal chemistry, optical analysis, EPR and infrared spectroscopy indicate that beryls have high alkali ions and water content.

本文对雪宝顶绿柱石的晶体化学、矿物谱学、热释光和流体包裹体特征等进行了分析讨论。结果表明，雪宝顶绿柱石化学成分具有富碱、富水，过渡金属离子以Fe3+、Fe2 +为主的特点。

Beryls ; crystal chemistry ; mineral spectroscopy ; thermoluminescence ; fluid inclusion ; Xuebaoding

绿柱石；晶体化学；矿物谱学；热释光；流体包裹体；雪宝顶

This article mainly divides into three parts, The first part is the albite jade characteristic, uses traditional the gemology method conducts the research to the albite jade physical property as well as the structure, carries on the electron probe analysis to its chemical composition, and the discussion of its mineral component\'s chemical composition change carries on the SPSS statistical software; uses X powder crystal diffraction to determine its lattice parameter, mineral constituent\'s crystal structure conducts the research to the albite jade, carries on the analysis to the feldspar degree of order, and carries on the discussion to the albite jade\'s origin. The above method each other confirms mutually, confirms the data reliability.

本文主要分为三部分，第一部分为钠长石玉的性质，采用常规的宝石学方法对钠长石玉的物理性质以及结构构造进行研究，利用电子探针分析对其化学成分进行分析，并运用SPSS统计软件对其矿物成分的化学成分变化进行探讨；采用X粉晶衍射测定其晶胞参数，对钠长石玉中矿物组成的晶体结构进行研究，对长石的有序度进行分析，并对钠长石玉的成因进行探讨；上述方法彼此相互验证，以证实数据的可靠性。

At last a single crystal of the ν-AlCrFe phase was found and the structure was determined by the combination of direct methods and high resolution electron microscopy. The structure contains a large quantity of slightly distorted icosahedra and the connection among them was analyzed.

利用单晶X射线衍射技术，结合高分辨电子显微学的研究结果，最终测定了ν-AlCrFe相的晶体结构，并对其中的二十面体的连接情况进行了分析。

In this thesis a series of novel transition metal complexes with dicyanamide have beenprepared and characterized by ...

在本论文中，我们制备了一系列新型的过渡金属二氰胺配合物并表征它们的晶体结构，谱学特征和磁性质。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。