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The visible spectrum of Mo in Ti-based alloy was analyzed by a digital spectroscope. Mo 553.31nm and Ti 551.44nm were selected as spectral lines for analysis and comparison. Samples of Ti-based alloys with different Mo contents were analyzed quantitatively. The data indicated that the ratio of intensities between analytical spectrum and comparison spectrum has a positive relationship with the content of Mo.

使用数字化看谱镜对钛合金中钼元素可见光谱进行了分析测定,选用M0553.31nm和Ti551.44nm作为分析谱线和比较谱线,对不同Mo元素含量的钛合金样品进行了定量分析探索,数据显示分析谱线和比较谱线的强度比值与Mo元素含量成正比关系。

In some way, the nature of the geochemical field shows that the deep fluid took part in the energy mineral reservoir formation and mineralization.2、 In zones with the strong tectonic activity and basement faults, the elements combination of petroleum is complex and the material from deep resource can be found in which. The character of elements geochemical and carbon isotope all show that there are deep fluid components in some Energy Minerals. The material source of the water accompanying with petroleum reservoir is complex, and which with multi-sources. The character of elements geochemical shows that the uranium of Dongsheng uran ore comes from the upper crust, the greyish-green gritstone and hoary kaolinised argillaceous siltstone is important for the formation of uranium deposits,and the grey gritstone is great potential to surveying uranium deposits .

基底断裂带和构造活动强的区域,原油中元素组合复杂,并含有深源物质;元素地球化学特征和同位素特征反映部分能源矿产中含有深部流体成分;盆地内油气藏伴生水的物质来源较为复杂,具有多源性;元素地球化学特征显示东胜铀矿的铀源主要来自上地壳,灰白色高岭土化泥质粉砂岩及灰绿色粗砂岩对铀矿的形成具有重要的意义,灰色粗砂岩具有良好的找矿潜力;元素地球化学特征还表明,黑岱沟煤及煤层夹矸中微量元素来源于上地壳。

The characters of geochemistry are rich alkali. And at the same time the content of calcium is high. They are rich in alkali, high in Potassium, enriched in LILE, LREE and Pb, depleted in HFSE and have a small Sr, Nd, Pb isotope range. Their source is probably a kind of even metasomatic mantle. This is consistent with the fact that there is kimberlite containing flogopite in the deep-source enclosure of Cenozoic super-K alkali lava in the southern part of this rock zone.

组成这些钾质碱性岩带的岩石:在岩相上,包括深成相、浅成相和喷溢相等不同岩相;在岩性上,从超基性、基性、中性到酸性岩石;造岩矿物,从超基性到酸性岩石中均有透辉石,在基性、超基性岩中有霞石;在岩石化学成分上,所有岩石均表现出富碱高钾富钙,微量元素富集Rb、Sr、Ba等大离子亲石元素和Th、U等放射性元素,贫Nb、Ta、Zr、Hf等高场强元素;稀土元素富集轻稀土,铕负异常不明显;Sr、Nd、Pb同位素组成,显示了物质来源于富集地幔源区。

The results show that the samples are of calc-alkaline series, the primitive mantle normalized trace element patterns are characterized by relative enrichment in large ion lithophile elements and depletion in high field strength elements (Nb, Ta, Ti, P etc.). REE patterns are of slightly right inclined type with unobvious Eu anomaly.

分析得出样品为钙碱性;原始地幔标准化微量元素分布型式显示相对富集大离子亲石元素K、Rb等,亏损高场强元素Nb、Ta、Ti、P等;稀土元素具有略向右倾的配分型式,且铕异常不明显,显示其具有与消减作用有关的岛弧火成岩的特征。

Taking Bendong and Xiqiu granitic bodies as an example, the thesis expounds geochemical characteristics of mantle-derived type granitoids in Sourthern China in REE and trace elements as follows: lower ∑REE, obvious fractionation of LREE and HREE, negative anomaly of Eu, relative higher ∑LREE/∑HREE,〓 and 〓 ratioes, rich in transitional elements and poor in large-ion lithophile and immobile elements compared with acidite means by Vinogradov. Original mantle-normalized distribution pattern of incompatible elements is one kind of rich -in-strongly incompatible elements type with enrich of K and loss of Sr, P, Ti and trace element association makes a feature of siderophile and chalcophile elements. The tectonomagmatic discriminating shows that mantle -derived granitoids in Southern China belong to orogenic granitoids formed in island arc/marginal sea basin system.

以本洞和西裘岩体为例,论文阐明了华南幔源型花岗岩稀土和微量元素地球化学特征,表现为稀土总量较低,轻重稀土元素分馏明显,负铕异常和∑LREE/∑HREE、〓、〓比值较高,与维氏酸性岩平均值相比华南幔源型花岗岩过渡族元素含量较高而大离子亲石元素和非活动性元素含量较低,不相容元素原始地幔标准化分配型式属强不相容元素富集型并呈K富集而Sr、P、Ti亏损的特点,微量元素组合以亲铁和亲铜元素为特征,构造岩浆判别显示华南幔源型花岗岩属造山花岗岩,其形成构造环境为岛弧/边缘海盆系统。

The deposition thickness of allylamine was increased with the treating time. The surface textures were changed following different procedures except allylamine groups and it means that the 30 min deposition thickness of allylamine is too thin to change the surface contours.

SEM-EDS的结果显示在未经任何处理及经氩气电浆清洁后的钛金属表面,侦测到主要为钛元素,丙烯胺电浆处理后,即可测到氮元素;戊二醛作用后表面有氧元素的出现;白蛋白处理后即可测得碳及氧元素。

FeSi nanoparticles were synthesized via thermal decomposition of iron pentacarbonyl in the solution of dioctyl ether, stabilizers oleic acid and oleylamine. The TEM images showed that FeSi nanoparticles had cubic shape, but it seemed that the composition was not uniform. According to the EDS results, the Fe:Si ratio of gray-uniform nanopaiticles was almost 1:1, and blacker FeSi nanoparticles contained more Fe atoms. Although FeSi didn't have uniform structure, it still could be proved that the incorporation of Fe and Si existed in a single nanoparticle. All possible structure, lattice, binding, morphology, surface condition would be discussed. These results indicated that perhaps FeSi2 was the main structure of the new products; however, due to incompletely combination and less synthesized time, it might still contain some part of Si and Fe structure. Besides, FeSi nanoparticles preserved the optical properties from Si atoms, but the PL intensity was much lower. The maxima PL peak appeared at 388 nm with the excitation at 300 nm. Their saturation magnetization, remanent magnetization and coercivity were measured by the SQUID, exhibiting their nearly superparamagnetic behavior.

利用热裂解系统可成功将研磨矽奈米粒子及五羰铁结合,制备出铁矽奈米粒子;从穿透式显微镜照片可知其粒子呈现立方体型态,但颜色深浅及组成不均,EDS结果则显示颜色均匀之粒子铁与矽之组成大致为1:1,颜色较深之粒子则含有较高量的铁元素;尽管组成比例并不统一,但单颗粒子同时含有矽与铁两种元素,初步说明铁矽奈米粒子之形成;进行多种结构与表面分析并探讨所有可能之键结、结构及表面元素后,推测铁矽奈米粒子可能以FeSi2之结构形成,并同时包含未重组完成的矽及铁之结构;利用PL分析得知铁矽奈米粒子确实保留矽之放光特性,并在300 nm激发光源下,於波长388 nm处有一最强放光特性峰,但整体发光效益不及研磨矽奈米粒子之结果;最后,利用超导量子干涉磁化仪量测其饱和磁化量、残留磁化量、与矫顽磁力,发现磁滞现象并不明显而几乎呈超顺磁性。

The content of platinum-group elements in samples of sulfides and gold-bearing breccia from the Taibai gold deposit was determined by the nickel sulfide fire assay and inductively coupled plasma-mass spectrometry.The results show that the PGE content in these samples is higher than that in the Baguamiao gold deposit,Qinling,but lower than that in the primitive mantle.

采用硫镍火法试金结合电感耦合等离子质谱分析了太白金矿硫化物和含金角砾岩中铂族元素的含量,结果显示,与秦岭地区八卦庙相比铂族元素含量较高,而低于原始地幔,其中铂、钯、钌富集,并结合前人研究资料对铂族元素的来源和迁移机制进行探讨。

The results of XEDS suggested that U and Ba were enriched on the surface; at the same time, Ca and Ti had a little depleted on the surface of pyrochlore-rich synroc; the results of XRD and SEM indicated that Fe〓O〓 can increase the corrosion of glass and pyrochlore-rich synroc; The results of glass mass loss rate showed that bentonite had the most corrosive to the glass specimens among barrier media; the results of XEDS indicated that Ca、Fe and A1 element were enriched on the glass surfaces, Si and Mg had slightly depleted, and Na was completely depleted.

玻璃固化体样品分析结果显示,膨润土体系有增加玻璃腐蚀的倾向。X-射线能谱分析表明,在玻璃样品表面Ca、Fe和Al元素呈富集,Si和Mg元素略有浸出,Na元素基本完全浸出,这同其他浸出实验结果一致。

Sherds were collected from Hongzhou Kiln covering 8 periods from Eastern Han to Late Tang Dynasty/the Five Dynastied and their bodies were analysed by NAA. The results show that the elemental contents in different samples are quite distinct, even for those in the same period. It means no single element can be used as "fingerprint" to distinguish the period. The curves of the contents of Na, Rb, Ba and Fe varying with lime are very similar, like "U" shape.

对江西洪州窑从东汉晚期至晚唐五代8期400个瓷胎样品进行了中子活化分析,分析结果显示碱金属元素Na和Rb、碱土金属元素Ba及Fe等作为胎的助熔剂元素随年代的变化趋势相似,都呈现出两头高中间低的U字形变化规律,其中Fe作为呈色元素,其含量的高低与瓷胎颜色的深浅是一致的。

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