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Unmount image - ejects image from device.

卸载像-从设备弹出像。

This requirement may be satisfied by the submission of information such as the following: name (generic name, chemical name, code number); Chemical Abstracts Service number if available; description (e.g., appearance, color, physical state); molecular formula and molecular weight; structural formula (including ionic state if applicable); stereochemistry identifying chiral centers, cis-trans isomerism, etc.

该要求可以通过提供下述信息来满足:名称(通用名、化学名、编码等)、化学摘要服务编码、性状描述(如:外观、颜色、物理状态)、分子式和分子重量、结构式、立体化学(找出手性中心、顺式反式异性等)、对结构体比率(如:外消旋物、规定的异构体、对异构物和固态形式的混合物)、溶解度概况、分配系数、溶液 pH 值、解离常数、熔点或沸点、折射率、比重。

This requirement may be satisfied by the submission of information such as the following: name (generic name, chemical name, code number ); Chemical Abstracts Service number if available; description (e.g., appearance, color, physical state ); molecular formula and molecular weight; structural formula (including ionic state if applicable ); stereochemistry identifying chiral centers, cis-trans isomerism, etc.

有的话、描述(如:外观、颜色、物理状态)、分子式和分子重量、结构式、立体化学(找出手性中心、顺式贯穿异性等)、对结构体或固态形式比率(如:外消旋物、规定的异构体、对异构物和固态形式的混合物)、溶解性档案、分隔系数、溶液pH值、解离常数、熔点和沸点、拆射率、精确重力。

Mass spectrometry results revealed that the pair of eluents respresented a pair of ternary copper complexes with mixed ligands, providing the first experimental evidence. These complexes are diastereoisomer in nature. The optimized configuration of the diastereoisomer was predicted by theoretical calculation.

质谱实验结果表明,拆分组分是一对铜混合配体复合物离子,其中的一个配体是提供手性环境的流动相添加物,另一配体是待拆分物质的某一构型对体,这对铜混合配体复合物离子本质上属于非对异构体。

Resolution and preparation of ethofumesate enantiomers were achieved under the optimal semi-preparation conditions. The chemical structure of two elutes were identified by GC-MS, the optical property and the eluting order were determined by using the Circular Dichroism detector and polarimeter.

在优化的半制备色谱条件下,完成了乙氧呋草黄对体的拆分、收集和制备,两个组分的化学结构经GC-MS确证,光学性质和流出顺序用圆二色检测器和旋光仪进行测定,获得了光学纯度超过97%的左旋和右旋对体。

This Sm-catalyzed reaction firstly efficiently realized the catalytic cycle in the tandem rearrangement/reduction reaction of α-hydroxy epoxides, and moreover the diastereoselective amplification could be distinctly observed when two C1 epimers in substrate were subjected to this catalytic tandem reaction.

该催化的多功能串联反应,高度非对选择性地一步控制了含有季碳的三个相邻立体中心,有效地构建了&2-季碳1,3-二醇&结构单元,首次实现了此类重排—还原过程的催化循环,其中对于两个C1位的差向异构体底物,此反应具有明显的非对选择性放大特点。

Though enantioslectivity in the epoxidation of some substrates with soluble polymer-supported tartrates is a little lower than that with solution-phase tartrates, it is higher than enantioslectivity with insoluble polystyrene resin-supported tartrates, linear poly s and corrosslinked poly s. It is obvious that soluble polymer-supported tartrates have good catalytic activity and enantioselectivity.

尽管可溶性聚合物支载的酒石酸酯在某些底物环氧化中的对选择性比小分子酒石酸酯低一些,但明显优于文献报道的不溶性聚苯乙烯树脂支载的酒石酸酯、线形聚酒石酸酯和交联聚酒石酸酯配体,显示了良好的催化活性和对选择性。

Some compounds possessing chiral center themselves may be racemates and appear racemic phenomenon in the extraction and separation from medicine herbs, structure modification and chemical synthesis.

但是,由于含有手性中心的中药有效成分本身可能是消旋体、或者在分离提取、结构改造及化学合成时会出现外消旋化现象,使新药研制与开发中面临对体成分的分离制备、体内手性药物分析及对体特异性药代动力学研究等重大难题。

Enantiomer or solid-state form ratios (e.g., for racemates, and for defined admixtures of isomers or enantiomers or solid-state forms); solubility profile (aqueous and nonaqueous as applicable); partition coefficients; solution pH; dissociation constant; melting or boiling point; refractive index; specific gravity.

该要求可以通过提供下述信息来满足:名称(通用名、化学名、编码等)、化学摘要服务编码、性状描述(如:外观、颜色、物理状态)、分子式和分子重量、结构式、立体化学(找出手性中心、顺式反式异性等)、对结构体比率(如:外消旋物、规定的异构体、对异构物和固态形式的混合物)、溶解度概况、分配系数、溶液pH值、解离常数、熔点或沸点、折射率、比重。

Enantiomer or solid-state form ratios (e.g., for racemates, and for defined admixtures of isomers or enantiomers or solid-state forms); solubility profile (aqueous and nonaqueous as applicable); partition coefficients; solution pH; dissociation constant; melting or boiling point; refractie index; specific graity.

该要求可以通过提供下述信息来满足:名称(通用名、化学名、编码等)、化学摘要服务编码、性状描述(如:外观、颜色、物理状态)、分子式和分子重量、结构式、立体化学(找出手性中心、顺式反式异性等)、对结构体比率(如:外消旋物、规定的异构体、对异构物和固态形式的混合物)、溶解度概况、分配系数、溶液pH值、解离常数、熔点或沸点、折射率、比重。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

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