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The highest ee value of 71% was achieved by using chiral molybdenum 2'-pyridingyl alcoholate complex at 0 ℃. After addition of phase transfer catalyst Bu4NBr, the yield and ee value were remarkably increased.

其中手性吡啶醇二氧合钼在0℃下的对选择性ee值达到71%;加入相转移催化剂四正丁基溴化铵,催化剂的活性和对选择性有显著提高,其中手性吡啶醇二氧合钨在50℃下ee值由54%提高到78%。

We studied effects of additives in the allylic amination reaction. We found that4NF could improve the reactivity and enantioselectivity.

对于烯丙基胺化反应,我们研究了外加添加剂对对选择性的影响,我们发现四丁基氟化铵的加入可以大大提高反应速度及对选择性。

The appearance of-enantiomer after incubation with single-enantiomer revealed the enantiomeric inversion of-isomer to its antipode. While no obvious stereoselective degradation or enantiomeric inversion were observed in other test soils.

左右旋对体在3~#土壤中的降解速率有明显差异,二者半衰期相差0.95周;添加外消旋体培养6周后ER值达到1.65,表明左旋体被优先降解;同时在该土壤中存在左旋体向右旋体的转化现象;在其他几个土壤中均未有明显的选择性降解或对体转化现象。

The concentration of D-phenylalanine in the external phase and the separation factorαcan be expressed as: The diffusion of boundary layer in outer aqueous phase is the controlled process while the concentration of D-phenylalanine in the external phase far less than the concentration of chiral carrier in the emulsion liquid membrane phase, then the diffusion coefficient k_e of boundary layer in outer aqueous phase can be achieved by data fitting.

外水相苯丙氨酸对体的浓度以及分离因子α表示为:当外相对体浓度远小于液膜相手性载体浓度时,该手性传质过程中外相边界层的扩散为控制步骤,利用数据拟合得到了外水相与液膜相界面边界层扩散的传质系数k_e。

In this paper, a complex mapping function is devised to transform the contour surface of an arc crack to a unit circle on the auxiliary plane.

本文之研究方法乃是首先设计一复变函数,将原有弧形裂纹之几何形状像至辅助平面成为一单位圆,然后再以此像函数代入相关之边界方程式中。

These dendritic NOBIN derived Schiff base ligands have been applied to titanium catalyzed hetero-Diels-Alder reaction of Danishefshy's diene and aldehydes, affording the corresponding 2-substituted 2, 3-dihydro-4H-pyran-4-one in quantitative yields and excellent enantioselectivities (up to 97. 2%ee). Comparing the reactivities and enantioselectivities of reaction catalyzed by the titanium complexes of these Schiff base ligands, it was found that a series of ligands L〓 were superior to the other three series of ligands L〓, L〓 and L〓, a significant positive NLE and a dendrimer effect existed in the L〓 dendritic catalyst system. The disposition of the dendritic wedges and the dendron size in the ligands were observed to have a significant impact on the enantioselectivity of the reaction.

NOBIN衍生的树枝状大分子希夫碱手性配体与钛形成的配合物在催化不对称杂Diels-Alder反应中的应用将得到的四个系列NOBIN衍生的树枝状希夫碱三齿手性配体与四异丙氧基钛形成的配合物用于催化Danishefsky's diene与醛的不对称杂Diels-Alder反应,通过反应条件的优化,获得了定量的收率和最高达97.2%ee值的对选择性;考察了这四个系列NOBIN衍生的树枝状希夫碱钛配合物的催化活性和对选择性,结果发现它们的活性次序依次为L〓≈L〓>L〓>L〓,对选择性次序依次为L〓>L〓>L〓>L〓。

In this graduation thesis, I want to point out how they become success in such a terrible circumstance and the artistic characteristics of their films. I will seek the film's esthete characteristics from the distance between the text and spectator, their character's destiny from the controversy, the relationship between the "Milky way Image" and the "New Wave Film of Hong Kong" the plot Mode of those people's work "Milky way Image" creates its own unique brand of cinema.

文章将从"银河像"诞生之初谈起,从当时惨淡的电影环境入手研究他成功的缘由,着眼于影像文本的艺术特色研究:从作品与观众的距离来探寻作品审美上的特点,从矛盾冲突的角度来探讨人物命运的变化,从历史的角度来梳理"银河像"与香港新浪潮电影的关系,从叙事情节的角度来剖析"银河像"极具个人风格的情节模式等等。

The E-TOF will also be feasible and practical to assist chemists in screening the optimal reaction condition or evaluating the overall efficiency of different catalytic systems for a specific asymmetric reaction.4.For the first time,we explored chiralγ-hydroxy-α,β-acetylenic esters,which were prepared via asymmetric alkynylation,as key intermediates to the synthesis of chiralγ-butyrolactones. This convergent and enantioselective approach to chiralγ-butyrolactones is practical and easily handled with protecting group free.

这一概念包括反应产率、对选择性、配体用量以及反应时间四个重要反应参数,不仅适用同一反应不同催化体系的横向综合性评价,而且适用于某一特定反应催化体系的优化过程,有助于研究人员选择最佳的反应条件。4、我们发展了以手性γ-羟基-α,β-炔酸酯为关键中间体完成了手性γ-丁内酯类天然产物的对立体选择性全合成,该关键中间体能够以我们的催化体系方便的对选择性合成,之后的官能团转换方法成熟,易于操作,无需进行繁琐的官能团保护和脱保护过程,绿色经济。

Moon Over the Second Spring ( Erquan ying yue "二泉映月") is a fantasy based on the famous folk melody by the same name.

《二泉月》(& Moon over the Second Spring &)这是使用了同名的著名民间乐曲素材写就的幻想曲。

Therefore, we study the approaches and questions of XML Schema mapping and propose a schema-based approach, which can match XML Schema automatically. Through the rich content of XML Schema and the well-composed mapping approach, we can produce more accurate mapping results.

因此,本研究探讨XML纲要对的相关方法及问题,并以纲要对为基础,提出一个XML Schema的自动纲要对架构,藉由XML Schema丰富的内容及混合的比对方法,更精确的比对出纲要之间的对关系。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

The new PS20 solar power tower collected sunlight through mirrors known as "heliostats" to produce steam that is converted into electricity by a turbine in Sanlucar la Mayor, Spain, Wednesday.

聚光:照片上是建在西班牙桑路卡拉马尤城的一座新型PS20塔式太阳能电站。被称为&日光反射装置&的镜子将太阳光反射到主塔,然后用聚集的热量产生蒸汽进而通过涡轮机转化为电力