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There are four kinds of fracture ways of 7075/SiC composite under high-temperature compression, which are the evulsions of SiC from the matrix due to forming cavity near the interface and intensive phase , ductile fracture of the matrix due to the nucleation of cavity near the interface , the fracture near SiC particulate coacervate and brittle fracture of the SiC particulate.

喷射沉积7075/SiC复合材料高温压缩时的断裂方式主要有四种,即空洞在增强相与基体界面处形成而出现增强相从基体中拔出的现象、空洞在基体中形核长大而引起基体的延性断裂、颗粒团聚处的断裂和颗粒的脆性断裂。

The monosaccharides in LBP-4 identified by GC were xylose , galactose , mannose , Rhamnose , glucose and arabinose with the molar ratio of 4. 45: 1. 20: 1. 0: 0.98: 0.90: 0.85. The content of calcium, magnesium, zinc and iron in LBP-4a were 127. 9070mg·g〓, 32. 3953mg·g〓, 0.3845mg·g〓 and 0.2930mg·g〓, respectively. The content of galacturnic acid in LBP-4a was 55. 45% while the content of protein is 3. 80%. According to IR spectra, it contains -COOH group,-NH- roup,-OH group,-NH〓 group and β-D-glucose. The backbone of sugar residues chain in LBP-4a were contained 1→6 indican bond according to periodate oxidation and the results of β-elimination reaction indicated that the chain of polysaccharides and protein were connected by O-linked chemical bond. The photograph of LBP-4a got by laser scanning confocal microscope and scanning electron microscope showed that the LBP-4a combined both with each other and with itself in its crystalloid. The crystalloid was flake and anisotropic.

由LBP-4a的红外光谱图知:LBP-4a中含有-COOH、-OH和-NH〓或-NH-基团,糖链中含有β-D-吡喃葡萄糖;高碘酸氧化实验知LBP-4a糖链中不具有连二羟基和连三羟基结构的单糖残基:具有连二羟基结构的单糖残基:具有连三羟基结构的单糖残基=57.0:16.2:1,六碳糖残基的连接中含有1→6连接的糖苷键;通过β消去反应证明LBP-4a中多糖链和氨基酸间为-O-型连接;由激光扫描共聚焦显微镜和扫描电镜对LBP-4a结晶观察结果推测:LBP-4a结晶中同时存在分子间和分子内结合的现象,LBP-4a分子相互结合时,并不是无规则的相互缠绕形成无规线团结构,而是形成片层结构,并且LBP-4a结晶可能具有各向异性的性质。

This project studies the scale-dependent deformation behavior of the metal matrix composite, the void nucleation and void growth mechanisms at the micron/submicron scale. The main results are:(1) In prophase, growth and coalescence of the void embedded in the graded matrix are analyzed in detailed;(2) Based on the infinite solid model containing a micro-void, coupling effects of the void shape and the void size on the void growth are studied carefully, the results show that it seems to exist a critical equivalent void radius, which is associated with the material length. When radius of a microvoid is close to or smaller than the critical void radius, the micro-void growth rate is essentially eliminated;(3) The coupling effects of the particle shape and size on the mesoscopic stress fields within the particle and matrix are also investigated by introducing the conception of inclusion/matrix interfacial energy. The results show that the stress concentration factors within the particle and on the matrix/particle interface are also strongly size-dependent,so the void nucleation mechanism is size-dependent.(4) By employing a specific orthogonal curve coordinate frame and a 'kernel function' conception, a 'unified method'solving the spheriodal and spherical void problems is suggested; by this unified method, size-dependent plastic potentials of the porous materials containing the spheriodal or spherical voids are obtained, which extend the traditional Gurson model for the spherical void and GLD model for the spheriodal voids to the micron scale.(5) Based on the RVE model containing the spheriodal or spherical particles, the influences of the particle shape and size on the size-dependent mechanical behavior of metal matrix composite are studied.

中文摘要:本项目对金属基复合材料在微细观尺度下的尺度相关变形行为、孔洞形核及长大的机理和模型进行了研究,取得了如下主要结果:1)在前期研究中,探讨了基体的梯度分布对孔洞长大和聚合的影响;2)基于含孔洞的无限大体模型,探讨了孔洞形状和孔洞尺寸对其长大的耦合作用,结果表明:可能存在一个与材料特征长度相关的临界孔洞尺寸,当椭球孔洞的等效半径小于临界孔洞半径时,孔洞的长大受到明显抑制;3)通过引入基体/夹杂界面能的概念,分析了夹杂尺寸、夹杂形状对材料细观应力场的耦合影响,结果表明:颗粒内部和界面上的应力集中因子强烈地依赖于夹杂的尺寸和形状,因此,孔洞的形核机理是尺寸相关的;4)采用一种特殊的正交曲线坐标系和引入"核函数"的概念,"统一"地得到了含椭球和球形孔洞的材料的尺寸相关塑性势,它将传统的Gurson球形孔洞模型和GLD椭球孔洞模型推广到微尺度范围;5)基于含椭球和球形夹杂的体胞模型,初步研究了夹杂形状、夹杂尺寸对金属基复合材料尺寸相关力学行为的影响。

Based on practical cases and axial stress test of the long-short pile foundation of the same pile caps in the soft clay area, the deformation character of the long-short pile foundation and whole-long pile foundation under the geological condition which the strength of upperstratum is higher than the understratum when two or more layers are appeared in the soft clay area is analysed. Analysis also shows that both settlement and cost of the long-short pile foundation are less than those of the long pile foundation in this kind of ground.

摘要]通过工程实例和对同一承台下长短桩各断面的轴力量测,研究我国沿海城市具有两个或多个较硬的持力层的软土地区,当上持力层变形模量大于下持力层时,长短桩桩基与长桩桩基的变形性状机理,得出在该类地基中,长短桩桩基的沉降小于长桩桩基,且工程造价更低。

The allylation reactions of aldehydes with allyl bromide were carried out in 76%~93% yields with Nd-SnCl2-H2O under ultrasound irradiation at room temperature for 50~60 min.

在Nd-SnCl2-H2O体系中,用烯丙基溴超声诱发下进行了一系列芳香醛的烯丙基反应,室温反应50~60min得76%~93%烯丙基化产物;而不用超声波时同样体系中搅拌3~4h高烯丙基醇产率为30%~86%。

The more the number of hydroxyl substitution in phenyl ring, the better the ability of scavenging DPPH free radical. That is, trihydroxy is better than dihydroxy, and dihydroxy is better than monohydroxy. Moreover, when the polyhydroxy exists in phenyl ring and it is ortho-position or para-position, the ability of scavenging DPPH free radical is better too.

当苯甲醯基的苯环上羟基取代数量越多,其清除DPPH自由基的能力越好,三羟基效果优於双羟基、单羟基,双羟基效果优於单羟基;而苯甲醯基苯环上若为多羟基且羟基的位置为邻位或对位的关系时,其在清除DPPH自由基的能力较佳。

The results of study show:1. White pulp and red pulp in parenchyma of spleen of embryo can be obviously discerned after 18 days. Periarterial lymphoid sheath and ellipsoid periarterial lymphoid sheath also can be obviously discerned in spleen of 4 days chicken. T, B lymphocytes in appendix basement of embryo emerge after 20 days. It is the initial shape of cecal tonsil. Crypt structure of conjunction of esophago and stomachus glandularis form obviously at 4 days. It is the initial shape of esophago tonsil. The germinal center firstly emerges in these three organs at 14 days. With the increase of day age, the characteristic structure peripheral immune organs gradually develop mature. Spleen achieve mature at 21 days and cecal tonsil at 35 days.2. IgM~+ and IgA~+ cells in spleen of embryo emerge at 15 days. IgG~+ cell, CD3~+ and CD8~+T lymphocytes of embryo emerge at 20 days. CD3~+, CD8~+ and IgM~+ cells in cecal tonsil of embryo emerge at 20 days. However CD4~+, IgG~+ and IgA~+ cells all emerge in 1 day age chicken out of crust. CD3~+, CD4~+, CD8~+, IgM~+ and IgG~+ cells in esophago tonsil of embryo all emerge at 20 days. However IgA~+ cells emerge in 1 day age chicken out of crust.3. The amount of T, B lymphocytes in peripheral immune organs increase follow with the increase of day age, and hold an upgrade tendency. The amount of T, B lymphocytes in spleen achieved stabilization at 21 days, and in tonsil of esophago and appendix at 35 days.

研究结果表明:1、在组织结构方面,脾脏实质内的白髓与红髓在胚胎18日龄后明显可辨,4日龄雏鸡脾脏中形成明显可辨的动脉周围淋巴鞘和椭球周围淋巴鞘;盲肠基部T、B淋巴细胞在胚胎20日龄时开始出现,即初步形成盲肠扁桃体;食管与腺胃结合处在4日龄时形成明显的隐窝结构,即食管扁桃体初步形成;14日龄时,三种器官中首次出现生发中心;随着日龄的增长,外周免疫器官特征结构不断发育成熟,脾脏在21日龄时达到成熟水平,盲肠扁桃体和食管扁桃体在35日龄时达到成熟水平。2、在T、B淋巴细胞出现时间方面,脾脏中IgM~+和IgA~+细胞在胚胎15日龄时开始出现,IgG~+细胞、CD3~+和CD8~+T淋巴细胞在胚胎18日龄时出现,CD4~+细胞在胚胎20日龄时出现;盲肠扁桃体中CD3~+、CD8~+和IgM~+细胞在胚胎20日龄时开始出现,而CD4~+、IgG~+和IgA~+细胞均在雏鸡出壳后1日龄时出现;食管扁桃体中CD3~+、CD4~+、CD8~+、IgM~+和IgG~+细胞均在胚胎20日龄时开始出现,而IgA~+细胞则在雏鸡出壳后1日龄时出现。3、在T、B淋巴细胞数量变化方面,外周免疫器官中T、B淋巴细胞的数量随日龄增长,整体均呈上升趋势。

At 60 ℃ the reaction of 1-O-alkyl-2-O-acetyl-3-O-trityl glycerol with iodine/methanol system removed trityl and acetyl and gave 1-alkyl glycerol. But at r.t. the reaction only removed trityl and gave two isomers 1-O-alkyl-2-O-acetyl glycerol and 1-O-alkyl-3-O-acetyl glycerol.

1-烷氧基-2乙酰氧基-3-三苯甲氧基甘油醚与碘/甲醇体系反应,在60 ℃时,同时发生了脱三苯甲基及乙酰基,在室温下,仅脱三苯甲基,但乙酰基在反应过程中发生了部分转移,产生了两个异构体。

In the space, along with increased distance from the main ore-controlling structures, the frequency of P type of pyrite and their thermoelectricity also decreased gradually. Within one lode, from the upper to the lower parts of an ore body, the vertical change of pyrite in thermoelectricity as the follows:① when the ore body is stable, that is when the ore body is uniformly and continuously mineralized, the Dp andαvalues keep increased from shallow to deeper parts;② when an ore body is discontinuously mineralized, the Dp andαvalues have a wavy increasing tendency from the shallow to the deeper;③ when the deeper part of an ore body contains abundant, Co and Ni high mafic dykes, the Dp andαvalues of pyrite decreased from the shallow to the deeper parts of an ore body, that is, an reversed zoning of pyrite thermoelectricity occurs for pyrite in this situation contain more Ni and Co and belongs to N type.④ For the deposits hosted in the Archean metamorphic rocks, because all of the pyrite in this case is N-type, the vertical change of pyrite is not featured by the transition of pyrite type, but by the increased values of Vnp and α from the shallow to deeper parts of an ore body.

在空间域上,水平分带规律为:随远离主干断裂,矿脉中P型的出现频率逐渐降低或热电系数值逐渐变小;在同一条矿脉中,这是由于矿化不均匀性及脉岩的影响,由矿体的上部到下部,它的垂向变化特征可以有如下几种变化形式:①由矿体的浅部到深部,黄铁矿的Dp值、或α值呈稳定升高的趋势时,矿体往往表现为矿化均匀,连续性好、延伸稳定;②由浅部到深部,黄铁矿的Dp值、α值呈波状变化,但总体又具有增大的趋势时,所在的矿体连续性差;③当矿脉的下部发育有大量的基性脉岩时,由于基性脉岩中常含有较高的Co、Ni,使其中黄铁矿的Co、Ni含量较高而呈N型导电,由矿体的上部到下部,黄铁矿的Dp值、α值呈减少的趋势,而造成黄铁矿热电性特征的逆向分带,④产于太古代变质岩中的中深脉状金矿,由于其中的黄铁矿均为N型导电,所以垂向变化规律并不表现为导型的改变,只是Vnp值或α值从矿体的上部到下部由小变大。

The results show that the zinc coating is eroded mostly, and some red rust and black rust appear on the substrate in the environment of oxygen supplied intermittently.

结果表明:在间歇通O2的情况下,锌层大部分被腐蚀,而且在基体上有一些红锈和黑锈产生,镀锌板表面的腐蚀产物呈现着不均匀的针状物;而在间歇通N2时,镀锌板的锌层脱落面积较少,基体上没有产生红锈,腐蚀产物呈大块状;在间歇通O2和通N2的情况下,镀锌板的腐蚀速率先增后降,在200 h时,前者的腐蚀质量损失速率是后者的2倍左右;镀锌板附着库尔勒泥浆时的腐蚀过程受氧去极化过程控制。

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As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸,那乌黑、忧郁的眼睛,她便会相信,他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失

But because of its youthful corporate culture—most people are hustled out of the door in their mid-40s—it had no one to send.

但是因为该公司年轻的企业文化——大多数员工在40来岁的时候都被请出公司——一时间没有好的人选。