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The yields were 67~89% and 61~90% respectively, and the ees were 66~99. 9% and 68~99. 9% respectively (except for trans-5-decene and ally naphthyl ether). With trans-stilbene as the substrate, chiral ligands and OsO〓 could be recovered and reused five times in the AD reaction with high catalytic activity and stereoselectivity.

4在PF〓/NMO体系中,将配体8和10分别用于八种烯烃的AD反应,配体、OsO〓和底物的摩尔比为0.02/0.015/1时,化学产率分别为67~91%和61~90%,ee值分别为66~99.9%和68~99.9%(反式-5-癸烯和萘基烯丙基醚除外)。

The results of AD reactions are as follows:(1) When the AD reaction of eight olefins was performed at 0.5mo1% OsO〓 and 2mol% ligand 8 in PEG/NMO system, the diols were obtained in 78~90% yields and 78~96% ees (except for trans-5-decene and ally naphthyl ether).

催化结果如下:(1)在PEG/NMO体系中,将配体8用于八种烯烃的AD反应,配体、OsO〓和底物的摩尔比为0.02/0.005/1时,化学产率为78~90%,除反式-5-癸烯和萘基烯丙基醚较低外,其它六种烯烃的相应二醇产物的ee值为78~96%。

By means of the novelly decoded manner and the well constructed fitting function, the global searching performance for the GA is developed so that optimized RBPNN approaches to the parsimonious structure;(4) A ROLS micro-genetic algorithm was built by integrating the micro-genetic algorithm with good convergence performance based on tiny class of group with the ROLS-SOA.

提出一种新的基于径向基概率神经网络的模式识别融合系统,即多分类器系统,避免了单一径向基概率神经网络分类器的分类局限性,减少了寻求单一分类单元结构最优化时的计算复杂度,通过使用D-S融合算法,大大提高了对复杂模式识别问题的分类精度。

In order to solve the problems such as multiple components in products, long time of rectification, high energy consumption, low yield and purity of product occurring during the production of p - octyl phenol, the effects of reaction conditions including reaction temperature, reaction time, the molar ratio of phenol to diisobutene on the conversion and yield of the product were examined.

为解决对辛基酚生产过程中精馏时存在组分多、精馏时间长、能耗高、产品收率和纯度低等问题,用正交实验探讨反应温度、反应时间、苯酚与二异丁烯原料摩尔比3因素对原料转化率和产品对辛基酚收率的影响。

Urumqi 830011, ChinaAbstract: Objective: To investigate the influences of the sperm of male rats impact,when octyl phenol, nonylphenol joint exposured.

目的:观察辛基酚、壬基酚联合染毒时,对雄性大鼠精子状况的影响。

The adsorption results of triethylene tetraamine-modified oxycellulose showed that:(1) when adsorption tests were carried at 37℃and pH7 in 5 h,static adsorption capacity of 0.5g adsorbent for urea(6g/L in dialysis solution),uric acid(1 g/L in redistilled water) and creatinine(0.1 g/L in dialysis solution) were 131.5mg/g,24.6mg/g,3.31mg/g respectively.

三乙烯基四胺基氧化纤维素的吸附性能结果表明:(1)吸附温度为37℃,pH值为7时,0.5g吸附剂对于尿素(6g/L透析液)、尿酸(1g/L二次水)、肌酐(0.1g/L透析液)在5h的静态吸附容量分别为131.5mg/g、24.6mg/g、3.31mg/g。

During the early growth stage of seedlings, basal stem diameter and paripinnate number were decreased with the increasing of shade, taproot length, root : shoot ratio, total dry weight and leaf area per seedling were maximal under 37.3% NS, specific leaf area was increased with the increasing of shade, but the relative growth rate was declined. Seedlings grew fastest under 0.6% NS, suggesting that nutrients stored in seeds played an important role at the early growth stage. The treatment of 37.3% NS was best for established seedlings in seedling height, basal stem diameter, paripinnate number, rachis length, the maximum sub-leaflet number of individual paripinnate, leaf area per seedling, relative growth rate and net assimilation rate. Light intensity was positively correlated to total dry weight, and negatively to specific leaf area. The maximum of SLA was observed under 15.5% NS.

生长早期的幼苗基径和复叶数随遮荫程度的增加而降低;主根长、根冠比、总干重和单株叶面积均以37.3% NS处理最大;比叶面积随遮荫程度的增加而增大,而相对生长率则降低;幼苗株高在0.6% NS下增长最快,表明种子中贮藏的营养物质对幼苗的早期生长可能具有重要作用。37.3% NS处理对定居后绒毛番龙眼幼苗的生长最有利,幼苗的株高、基径、复叶数、叶轴长、复叶最多小叶数、单株叶面积、相对生长率和净同化率均在37.3% NS处理下获得最大增长;幼苗总干重随光照强度的减弱而降低;比叶面积在15.5% NS处理时最大。

The treatment of 37.3% NS was best for established seedlings in seedling height, basal stem diameter, paripinnate number, rachis length, the maximum sub-leaflet number of individual paripinnate, leaf area per seedling, relative growth rate and net assimilation rate.

生长早期的幼苗基径和复叶数随遮荫程度的增加而降低;主根长、根冠比、总干重和单株叶面积均以37.3%NS处理最大;比叶面积随遮荫程度的增加而增大,而相对生长率则降低;幼苗株高在0.6%NS下增长最快,表明种子中贮藏的营养物质对幼苗的早期生长可能具有重要作用。37.3%NS处理对定居后绒毛番龙眼幼苗的生长最有利,幼苗的株高、基径、复叶数、叶轴长、复叶最多小叶数、单株叶面积、相对生长率和净同化率均在37.3%NS处理下获得最大增长;幼苗总干重随光照强度的减弱而降低;比叶面积在15.5%NS处理时最大。

The fact that the compound, 2-methyl-2-di- methylaminomethyl-5--n-pentylidenecyclo- pentanone hydrochloride (T60) possessed little anticancer activity indicated that the Mannich bases that could formed a methylene group were necessary for anticancer activity.

当环戊酮环上的Mannich碱侧链位置上引入取代基时,抗癌活性显著降低,如化合物2-甲基-2-二甲胺甲基-5--亚戊基环戊酮盐酸盐(T60)几乎无抗癌活性。这说明Mannich碱能形成亚甲基是这类化合物产生抗癌活性所必不可少的条件。

The yield reached 67.0% The medicinal and pesticidal activities of a part of the compounds have been measured .

在进行氨基酰化时,论文克服了该类嘧啶环上4位氨基在常规条件下不与芳香类和带有强吸电子基如三氯乙酰基酰化试剂发生反应的困难,通过采用在强碱性条件下进行酰化,得以成功。

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