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According to the practical needs of chrome-free tannage, titanium is abundant in nature, easily obtainable and ecologically friendly, titanium tannage can produce a leather with similar performance to chrome-tanned leather, so the research of titanium tannage to alternative chrome tannage was established as the research direction of this thesis. The preparation of novel titanium tanning agent, factors affecting titanium tannage, titannium tannage mechanism and titanium combining tannage were studied.

本文从对非铬鞣体系的实用性要求出发,在对几种常用金属盐鞣剂的鞣性和鞣革综合性能的分析基础上,并结合它们的资源和毒性等方面的因素,提出了钛鞣是理想的铬鞣的替代鞣法的观点,确定了以资源丰富、无毒和鞣革综合性能好的钛盐代替铬盐的研究方向,研究了新型钛鞣剂的制备方法、影响钛鞣的因素,并对钛鞣机理和钛结合鞣法等方面进行了深入的研究。

The results show that, firstly, Stellera chamaejasme L, which rely on their developed axial root system in the 10~40cm soil layer to occupy the competitive priority of volume, length, surface area and so on, in the case of their adaptive faculty to poor surroundings resulting from fruit picking, trampling and overgrazing as well as with the phenomenon of restrained growth among various plants, gradually become the dominant plant in the herbaceous community; secondly, this kind of degraded grassland has not displayed any general characteristic of degradation such as surface exposure, accumulative quantity of vegetation reduced, water loss, soil erosion and so on, therefor, it should be dealt with distinguishingly; thirdly, if"Stellera chamaejasme L Killer"and"Oxytropis ochrocephala Killer"invented by CAS are taken advantage of respectively in the bloom period of Stellera chamaejasme L and at the beginning of florescence of Oxytropis ochrocephala bunge by ultra-low volume spray of 1. 05L/hm〓 and 1. 35~165L/hm〓 dosage separately, the death rates of poisonous herbs may achieve above 95% and 92% correspondently; fourthly, this technology with the characteristics of high work efficiency, exclusive selectivity and convenient operation, is safe to non-target plants and other animals, and has no toxic or side-effect to environment; furthermore, an execution of"Stellera chamaejasme L Killer"spray and a two-year grazing prohibition can be effectively applied on degraded grasslands of"Weed and Poisonous plants Type".

结果表明:狼毒凭借发达的轴根系在10~40cm土层中形成的体积、长度、表面积等竞争优势,以及对采食、践踏、过度放牧所形成的不良环境的适应能力和异株克生现象的存在,逐步成为草群中的优势植物;毒杂草型退化草地没有表现出地表裸露、植物蓄积量减少、水土流失等一般性退化特征,对该类草地的治理应区别对待;应用中科院研制的'灭狼毒'和'灭棘豆'分别在狼毒盛花期和黄花棘豆初花期,以1.05L/hm〓、1.35~165L/hm〓的施用量超低容量喷雾,毒草的死亡率可达到95%、92%以上;该技术具有工效高、选择性专一、灭效高、操作简便,对非靶标植物和其它动物安全,对环境无毒副作用的特点;采用喷施'灭狼毒'+短期禁牧措施,可以有效治理毒杂草型退化草地。

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