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Several transient compounds were synthesized by the homo- and heterogeneous reactions of reactive halogen compounds, In-situ ultraviolet photoelectron spectroscopy and photoionization mass spectroscopy as well as theoretical calculations were used to study their molecular structures, stability and molecular orbital properties, their electronic structures and geometric structures were obtained for the first time; Simultaneously, the electronic structure and thermal dissociation of acetyl peroxynitrate and trifluoroacetyl peroxynitrate which have great importance in the atmospheric chemistry were studied; The substituent effects of series of halopyridines and halothiophenes were studied by the ultraviolet photoelectron spectroscopy method for the first time. The atmospheric chemical reaction between peroxyacetyl radicals with IO radicals as well as the dissociation of the most stable isomer of CH3COIO3 were calculated by density functional theory, it was found that the CH3COOIO2 isomer may be act as a new reservoir of inorganic iodine in the stratosphere.

通过活性卤素的系列均相与非均相化学反应合成了几种瞬态物种,采用原位紫外光电子能谱和光电离质谱结合量子化学理论计算对化合物的分子结构、稳定性以及分子轨道特性进行了研究,首次获得了这些物种的电子结构和几何结构的信息;同时研究了大气中有重要作用的乙酰过氧硝酸酯和三氟乙酰过氧硝酸酯的电子结构性质及热解过程;采用紫外光电子能谱手段首次研究了系列卤代吡啶和噻吩的取代基效应;通过量子化学理论计算研究了乙酰基过氧自由基与IO自由基的大气化学反应及其最稳定异构体CH3COOIO2的解离,发现该物种可能是无机碘化合物在平流层中的储库物种。

The author'sviewpoint is that information is the universal attribute of all matter, therelationship of infarmation reflects the unisonant corresponding relation in thematerial system of the four-...

信息是物质的普遍属性;信息联系反映了四维世界中物质系统间的同构对应关系;信息过程在物质的不同形态(指无机界、植物和低等动物界、高等动物界、人类社会)有着不同的质,其决定性的区别在"反馈";而意识的本质则是物质世界最高阶的信息过程。

The author'sviewpoint is that information is the universal attribute of all matter, therelationship of infarmation reflects the unisonant corresponding relation in thematerial system of the four-dimensiomal world, and f...

信息是物质的普遍属性;信息联系反映了四维世界中物质系统间的同构对应关系;信息过程在物质的不同形态(指无机界、植物和低等动物界、高等动物界、人类社会)有着不同的质,其决定性的区别在"反馈";而意识的本质则是物质世界最高阶的信息过程。

Silicon quality asphalt modify pharmaceutical whether one of good performance pitch modify the material , it is made of nonmetal ore of inorganic, the break- through and innovation on that it is asphalt to modify, it is the open-up had in application in the diatomaceous earth too.

硅质沥青改性剂是一种性能优良的沥青改性材料,它是用无机非金属矿制成的,因此是沥青改性上的突破和创新,也是在硅藻土的应用上的开拓。

X-ray examination demonstrated that at 4 weeks after implantation, some or even lateral intertransverse bridging regions were unclear, and material density in the repairing group was lower than control group; at 8 weeks after implantation, interspace between up and down bridging was shrunk, and a great quantity of calluses were successively formed; at 12 weeks after implantation, complete confluence was observed, and the density in the repairing group was closed to that in the control group.

结果:采用脱蛋白处理后的松质骨可见大小不等、相互交通、开放孔隙的网架结构,孔径200~500 μm,孔隙率60%左右,其无机成分为羟基磷灰石,有机成分为胶原,力学性能保存良好,细胞相容性良好。X射线片结果显示:植入第4周,横突桥接处部分区域模糊,以内侧明显,此时修复组材料密度略低于对照组;第8周上下桥接部间隙变小,大量连续骨痂生成;12周后完全融合,两组材料密度接近。

Research results indicate that X FLOUR is a kind of amorphous inorganic material which has more than 70% SiO〓 content and 85% or so SiO〓 plus Al〓O〓, it is a pozzolanic additive with great reactivity potential.

研究结果表明,X粉是一种SiO〓含量在70%以上,SiO〓和Al〓O〓总量在85%左右的非晶质无机材料,是一种活性潜力较大的火山灰质掺合料。

In order to enhance the miscibility between the inorganic and the organic phases,the silanol coupling agent is made from the slane VTMS and the colloid silica. Then the silanol coupling agent and nano-particles of ZnSb2O6 as the conductive filler are successfully bonded and the nano-particles of ZnSb2O6 will become more organic-like. The colloid silane-SiO2-ZnSb2O6 precursor solution is subsequently mixed with a homogeneous lsopropylalcohol solution of SR-399 acrylic monomers (Dipentaerythritol pentaacrylate) and the active free radical agent709. Under nitrogen purging, this reaction solution prepolymerize at 60℃. Then, the solution is spin-coated with the spin coator at room temperature. At last, the coated thin film is cured and crosslinked by the UV curing reactor to form the highly transparent thin film with good optoelectronic properties from hybrid organic-inorganic nano-composite.

首先以矽氧烷VTMS和colloid silica制备矽氧偶合剂,再以此偶合剂对分散於异丙醇溶液之奈米级的colloid ZnSb2O6做有机化改质,以增进其与有机高分子基材的键结相容性,我们将此colloid silane-SiO2 - ZnSb2O6前驱物与SR-399有机基材单体(Dipentaerythritol pentaacrylate)的异丙醇溶液与活性自由基光起始剂709均匀掺混后,在充满氮气反应系统下,加热至60℃进行预聚合反应,接著在室温下以旋转涂布机旋转涂布成厚度均匀薄膜,最后将此薄膜直接高温硬化或以UV硬化机网状键结硬化成透明与具部份导电性等光电特性之无机/有机奈米混成薄膜。

We have synthesized SiO2-main chain acrylate material successfully. First, the surface of SiO2 nanoparticle was modified with MPS (3-Methacryloxypropyl Trimethoxy Silane). Then TEGDA (Tetraethylene glycol diacrylate) was added to control the amount of organic-inorganic ratio(10-60wt%).

本实验室已成它X成二氧化矽主链压克力混成材料,首先将粒径介於20至25nm的SiO2颗粒表面改质成压克力基,利用MPS(3-Methacryloxypropyl Trimethoxy Silane)经水解与缩合,即接在SiO2颗粒表面,再加入压克力单体TEGDA(Tetraethylene glycol diacrylate),藉以调控有机无机的比例。

Research result indicated that the cooperative effect between swell and precursor is main factor for the nanoparticle loaded in Nafion, and moreover, polarity of solvent and water content in Nafion also affects the load largely. To improve away the surface concentration of CdS nanocrystal on two side of membrane for general preparation, thioacetamide was first used as a precursor instead of inorganic sulfur source(H2S and Na2S) in synthesis of CdS nanocrystal. The assembly mechanism for several sulfur source had been studied, and CdS/Nafion with the character of homogeneous disperse had been prepared, which is fit for mass transmission in photocatalitic reaction. Following the investigation of several crystallizing way, simple and reliable hydrothermal-crystallizing was found. According to this way, maximal TiO2 load in Nafion achieved 43%. Activity of TiO2/Nafion or CdS/Nafion as a photocatalyst was explored initially for disintegrating liquid contamination. Maximal decompose rate achieved 86% under condition of this research.

研究结果表明:Nafion膜对纳米粒子负载量的主要影响因素是溶胀作用与前驱体协同效应,同时溶剂极性和薄膜含水量对负载量也影响相当大;本课题首次使用硫代乙酰胺代替传统无机硫源(H2S、Na2S)合成CdS纳晶,研究了各种硫源的组装机理,克服了常规技术存在的CdS纳晶趋于膜表面富集的缺点,得到了有利于光催化传质需要的体相均匀分布CdS/Nafion;研究了多种Nafion膜内纳米粒子晶化途径,找到了简单可靠的水热晶化法,TiO2纳晶最高负载量达43%;初步探索了TiO2/Nafion、CdS/Nafion作为光催化剂降解水中模拟污染物的活性,在本实验条件下最高降解率达86%。

Using doped method low rare earth concentration and chelates matrix luminescence was successful in the chelates systems.

稀土荧光络合物研究中借用无机稀土掺杂的办法也可以实现以络合物为基质的低浓度的稀土发光。

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