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The traditional catalyst used in acetal synthetic reaction is strong inorganic acid.

文摘:缩醛合成反应的传统催化剂为无机强酸,但由于副反应多、腐蚀性强和易污染环境等缺点,其使用受到限制。

It is by the natural inorganic material, uses the specific craft, to become after the high temperature agglutination.

它是以天然无机材料、采用特定的工艺、经高温烧结而成。

Zeolites are a kind of microporous crystalline aluminosilicate materials with framework structures.

沸石分子筛是一类具有骨架结构的无机硅铝酸盐。

Pristine Li-Al LDHs are synthesized by hydrothermal process in different reaction conditions by varying the aging time for 1 and 24 hours. Both the Li-Al layered double hydroxides (abbreviated as Li-Al LDH1 and Li-Al LDH24 for aging time 1 hour and 24 hours, respectively) were modified by using sulphanilic acid sodium salt hydrate, modified agent to form modified Li-Al LDH1-SAS and Li-Al LDH24-SAS. The morphology of the pristine layered double hydroxides are investigated by using wide angle X-rays diffraction, scanning electron microscopy and particle size analyzer which indicates that the crystallinity and aspect ratio is increased with increasing the aging time from 1 hour to 24 hours. The particle size of Li-Al LDH24 and Li-Al LDH1 are found to be ~1000 nm and ~250 nm, respectively. Both the pristine and modified LDHs are characterized by XRD, FTIR spectra and thermogravimetric analysis.

本研究目的在於改变长晶时间的长短,合成出同径大小的Li-Al LDHs,再经由改质剂sulphanilic acid sodium salt hydrate将Li-Al LDHs无机层材表面有机官能化制备出改质型Li-Al LDHs-SAS,於是进一步藉由扫描式电子显微镜、射径仪和穿透式电子显微镜等仪器分别观察LDHs改质前和改质后其主层结构型态上的变化;从中可以发现Li-Al LDHs随著长晶时间的增加其径有随之增大的趋势,但经有机化改质后其径会由於改质环境的影响明显低许多,针对此现象本实验将未改质和改质后之Li-Al人工无机层材制备成复材进一步探讨其在热性质和难燃特性上的为表现。

When secondary building units characteristic of zeolite Beta detected by FT-IR appeared in the reaction mixture in the absence of crystals of zeolite Beta, the pre-treatment was terminated. The aluminosilicate gel with seconding building units characteristic of zeolite Beta was led to ordered-channel hexagonal mesoporous molecular sieve by the interaction between liquid-crystal micelles formed by the self-assembly of surfactants and pre-treated alumiosilicate gel. Therefore, the mesopore wall of SBU mesoporous materials showed the structural character of zeolite Beta.

当反应混合物出现用FT-IR可以检测到的Beta沸石次级结构单元且又没有生成Beta沸石晶体时,即刻终止预处理过程;然后利用表面活性剂超分子自组装形成的液晶胶团与经过预处理的无机物种通过界面作用把含有Beta沸石次级结构单元的无机物种导向为有规整孔道结构的六角中孔分子筛,这种SBU中孔材料的孔壁因而具有Beta沸石的结构特征。

Based on the previous experiments, we choose CNTs/CdS core-shell nanowires as inorganic materials and poly(benzyl-ether) dendrons with thiol functionalities as organic solubilizer. The solubility of CNTs/CdS core-shell nanowires in normal solvents was expected to improve through chemical interactions between core-shell nanowires and solubilizer. The enhanced solubility can improve facility in processability. It also provides a new application method in nanomaterials.

本论文在课题组原有工作的基础上,以制备可溶、易加工的有机-无机复合纳米材料为应用目标,选择具有自己课题组研究特色的CNTs/CdS核壳纳米线结构作为无机材料,选择带巯基的聚苯甲醚树枝状分子作为有机增溶剂,通过带巯基的聚苯甲醚树枝状分子对CNTs/CdS核壳纳米线的化学作用,改善了核壳纳米线在常用有机溶剂中的溶解性能,为材料的湿法加工提供了基础,也为类似纳米材料的应用开拓了一种新的方法。

Particularly, this product contains organic iodine, the absorption of organic iodine to animals is 3 times of the inorganic iodine, and the effect of organic iodine is 30 times of inorganic iodine, after the absorption by animals, they will stimulate the immune system inside body, therefore, to obtain the immunity against the virus strains including the swine influenza virus A/H1N1!

尤其是该制剂中含有的有机碘,动物对有机碘的吸收是无机碘的3倍,作用效果是无机碘的30倍,动物吸收后,会激发体内的免疫系统,从而获得对包括猪流感A/HINI病毒在内的毒株的免疫力!

Particularly, this product contains organic iodine, the absorption of organic iodine to animals is 3 times of the inorganic iodine, and the effect of organic iodine is 30 times of inorganic iodine, after the absorption by animals, they will stimulate the immune system inside body, therefore, to obtain the immunity against the virus strains including the Influenza A virus subtype H1N1!

尤其是该制剂中含有的有机碘,动物对有机碘的吸收是无机碘的3倍,作用效果是无机碘的30倍,动物吸收后,会激发体内的免疫系统,从而获得对包括甲型H1N1流感A/H1N1病毒在内的毒株的免疫力!

In our research, through derivatization of stable calix[4]pyrroles, active substituting units were jointed on the calixpyrrolic skelecton. After acylamide and free radical transfer reaction, the preparation of new calix[4]pyrrole-bonded stationary phases were fulfilled. the separation abilities of them to inorganic and organic anions and medicines were exploited and new analytical methods were established. The separation mechanisms were discussed. At the same time, through using calix[4]pyrroles as additives in CZE to influence the electrophoresis of inorganic anions, the recognition mechanisms and influencing factors in supramolecular chemistry were also studied.

本项目以新型杯吡咯大环化合物分子识别化学研究为基础,设计合成了含活泼取代基的官能化杯[4]吡咯化合物,通过酰胺化反应和原位自由基链转移反应制备了新型的杯[4]吡咯色谱固定相,系统研究了具有阴离子识别功能的杯[4]吡咯大环化合物作为离子色谱的分离介质对无机、有机离子型化合物和药物分子的色谱分离性能,建立了新的分析方法,对分离机理进行了探索和验证;同时将杯[4]吡咯化合物用作毛细管电泳流动相添加剂,利用其对无机阴离子电泳行为的影响探讨超分子化学中分子识别的机理和影响因素。

It is conducive to uptake soil nitrogen for flue-tobacco on dryland soil with maize-tobacco rotation before topping (60 days after transplanting) and uptake soil nitrogen for flue-tobacco on paddy soil with rice-tobacco rotation after topping.2 The nitrogen utilization efficiency of rapeseed cake, rice straw and rape straw were 19.5%, 15.5%, 8.1% respectively, and the inorganic fertilizer nitrogen utilization efficiency were 41.1%, 42.7% and 35.7% under the combined application of organic additives and inorganic nitrogen fertilizer. The contribution rate of rapeseed cake, rice straw, rape straw to accumulated nitrogen of flue-cured tobacco were 1.0%, 2.4%, 2.7% respectively by the combined application of organic additives and nitrogen fertilizer. Flue-cured tobacco for organic nitrogen absorption meet with the nitrogen needs laws of high-quality tobacco, indicating that the combined application organic additives and inorganic nitrogen fertilizer reduces the nicotine content of tobacco, an increase of sugar/nicotine ratio and improved the quality of tobacco. In which the role of rice and rape straw is greater than the rapeseed cake can be used as measures to lower nicotine.3 Nitrogen accumulation in flue-cured tobacco with the total nitrogen input was a significant positive correlation during the growth stage of flue-cured tobacco. The total nitrogen input for the 156.3-405.5kg.hm-2, in which the soil nitrogen mineralization capacity account for 22.6%-54.3%, with an average of 34.5%, that is, soil nitrogen mineralization accounted for 1/3 of the total nitrogen input.

旱地轮作土壤有利于烤烟生长前期对土壤氮素的吸收,水旱轮作土壤增加了烤烟生长后期对土壤氮的吸收。2在有机添加物与无机氮肥配施条件下,烤烟对有机添加物中氮的吸收规律基本符合优质烟的需氮规律,其中烤烟对菜籽饼肥、稻草秸秆、油菜秸秆所含氮素的利用率分别为19.5%、15.5%、8.1%,所配施无机氮肥的利用率分别为41.1%、42.7%和35.7%,菜籽饼肥、稻草秸秆、油菜秸秆对烤烟氮素累积量的贡献分别为1.0%、2.4%、2.7%。3不同轮作方式及添加有机物条件下氮素平衡结果显示,烤烟生长期间的氮输入总量为156.3-405.5kg.hm-2,其中矿化氮量为输入总氮量的22.6%-54.3%,平均为34.5%,约为输入总氮量的1/3;肥料氮的利用率为31.4%-42.7%;植烟土壤氮素表观损失率在37.5%-57.2%,平均为46.9%,约为输入总氮量的一半。

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However, as the name(read-only memory)implies, CD disks cannot be written onorchanged in any way.

然而,正如其名字所指出的那样,CD盘不能写,也不能用任何方式改变其内容。

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