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4DRG was co-culture with sciatic nerve segment in 10鸖 DMEM;the axons were longer and surround the sciatic nerve segment which was regard as anew evidence for chemotropism.

结果:(1)在无血清条件下单独培养的DRG,背根神经节的轴突数目众多,外形纤细弯曲,不成束,并且施万细胞和成纤维细胞稀少,所以可以排除两者对轴突生长的影响,为观察来源于变性坐骨神经段的可溶性因子对轴突生长的作用提供了有利条件;(2)在无血清条件下DRG和变性坐骨神经段联合培养,①先单独培养DRG,4天后待神经元轴突长出,再与坐骨神经段联合培养,观察到神经元的轴突数目减少,外形挺直,部分轴突之间相互粘附成束;②变性坐骨神经段和DRG同时联合培养,神经元的轴突数目明显减少,外形粗壮,轴突之间相互粘附成束;(3)有血清条件下单独培养DRG,轴突数目较多,外形挺直,长短不一,部分神经元的轴突之间相互粘附,施万细胞和成纤维细胞数目众多,观察到的轴突生长情况受到施万细胞和成纤维细胞的直接或者间接的影响。

Through the experiments on hydration of AH in the following sulphate(Li_2SO_4、MgSO_4 、 Al_2(SO_4)_3 、MnSO_4 、CuSO_4 、CoSO4 、CdSO_4 、ZnSO_4 、NiSO_4 、FeSO_4), dissoluble sulfate hydrate origining from hydration process of AH affects it's hydrous rate, hydrous rate of AH does not connect with Z/R of cation in stimulation, theory that Z/R affect hydrous rate of AH does not exist. Third, hydration of AH in dissoluble sulfate complies with dissolve-nucleate -grow theory, concentration of Ca~2+ from dissolving of CaSO_4 is higher than one of CaSO_4·2H_2O, calcium sulphate dihydrite gets a motivity of crystallization. dissoluble sulfate takes the following function: double-salt or dissoluble sulfate hydrate from hydration of AH in it becomes heterogeneous particle and a kind of nucleation catalyzer, and reduces surface barrier when DH becomes crystal because the crystal of DH precedently appears in uneven place. Results indicate hydration of AH does not conform with double-salt theory, but it conform with this mechanism: dissolve-nucleate-grow, formation of DH is an uneven nucleation and crystalizaion process.

通过对CaSO_4在Na_2SO_4 、K_2SO_4 、Rb_2SO_4 、Cs_2SO_4 、(NH_4)_2SO_4溶液中水化过程,以及CaSO_4·2H_2O、CaSO_4与以上硫酸盐反应速度、产物的研究,说明复盐理论不正确;CaSO_4在(Li_2SO_4、MgSO_4 、 Al_2(SO_4)_3 、MnSO_4 、CuSO_4 、CoSO_4 、CdSO_4 、ZnSO_4 、NiSO_4 、FeSO_4)溶液中水化,水化过程中硫酸盐水合物的析晶影响着无水硫酸钙水化,与激发剂阳离子Z/R值大小无关,阳离子的Z/R参数影响水化率的规律并不存在; 3、无水硫酸钙在可溶性硫酸盐中的水化按照溶解-成核-生长理论进行,CaSO_4达到溶解平衡时Ca~2+的浓度大于CaSO_4·2H_2O溶解平衡的Ca~2+的浓度,CaSO_4·2H_2O获得结晶的驱动力,可溶性硫酸盐起到形成晶核的作用:水化过程与CaSO_4生成复盐或析出水合物所形成的细小物相,作为异质微粒使母相中存在不均匀性,这些不均匀性有效地降低成核时的表面能位垒,使CaSO_4·2H_2O晶核优先地在这些具不均匀性的地方形成,因此这些物质起成核催化剂作用。

Once the sparger installed in the CMT, the fluid temperature above the sparger and the initial pressure of pressurizer are the key factor, which affect the condensation characteristic and temperature equilibrium time.

通过对不同初始条件下的CMT排水量进行了分析,发现CMT排水速度主要受CMT内的压力变化的影响:CMT无遮流板排水实验中所有排水量随时间的变化曲线都是单调递增的,且都有一个较为明显的拐点,在拐点后,斜率明显增大,说明排水速度增加显著;CMT加遮流板排水实验中排水量曲线的拐点不明显且出现时间较无遮流板排水实验要早,说明排水速度增加得较早;CMT加遮流板排水实验如果PRZ初始压力较大,通过改变CMT的初始温度,将会引起排水总量较大的变化;排水速度平衡时间受CMT压力平衡响应时间的影响,且较CMT压力平衡响应时间快。

In the test 5 treatments of single-sowed alfalfa or smooth brome grass, and their mix-sowing with different ratios of 50%+50%, 60%+40% and 70%+30% were set up to analyze pH, CP, NDF, ADF, acetic acid, butyric acid, lactic acid and total acid of the silage in each treatment and study the effect of alfalfa and smooth brome grass with different mix- sowing ratio on silage quality.

方法]试验设5个处理,即紫花苜蓿单播、无芒雀麦单播、紫花苜蓿+无芒雀麦以50%+50%、60%+40%和70%+30%比例混播,分析各处理青贮材料的pH值、CP、NDF、ADF、乙酸、丁酸、乳酸和总酸的变化,研究无芒雀麦与紫花苜蓿不同比例混播对青贮品质的影响。

The effect of refined cotton,carbon fiber content and length on the safety of caseless ammunition and self-ignition temperature of simulating bore test was analyzed by testing the ignition point of 5 s delay of the propellants containing carbon fiber or refined cotton,impact sensitivity and temperature of simulating bore test.

为了研究含有纤维的无壳弹发射药安全性,通过测试含有碳纤维素或精制棉的无壳弹发射药5s延滞期爆发点、撞击感度和模拟枪膛试验的自燃温度,分析碳纤维含量、长度和精制棉对无壳弹发射药安全性能和模拟枪膛试验的自燃温度影响。

Dealcoholization temperature markedly influences the surface area and porosity of the resultant MAO-supports. When the support was pretreated at lower or higher temperature, the corresponding MAO-support shows very low surface area;2.XRD and IR analyses indicate that MAO has reacted with the residual ethanol in the supports, which is an important manner to get MAO fixed on the carrier. Morever, XPS analyse indicates that MAO can also be coordinated with MgCl_2, which is another way to get MAO fixed on the support;3.ICP and EDX analyses indicate that dealcoholization temperature not only determined the element content on the solid catalyst, but also influences the element distribution on the carrier;4.The activities of the supported phenoxy-imine catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature. The support (MSP-5) obtained by treating MgCl_2·2.56C_2H_5OH at 160℃for 4 h, then modified by MAO is very effective for immobilizing complex 3, the resultant solid catalyst (MSPC-5) shows very high activity in ethylene polymerization, and its kinetics of polymerization is stable during the reaction process. Finally, PEs with spherical morphology and high bulk density (over 0.35g/ml) were obtained, without reactor fouling;5.In this work, polymerization conditions such as alkylaluminums, Al/Zr ratio, temperature and H_2 had a pronounced effect on the activity of MSPC-5 and properties of PE;(3). New MgCl_2-Supported Single-Site Catalysts for Ethylene PolymerizationIn this work, a kind of new MgCl_2 support was obtained by anhydrous MgCl_2 co-milled with solid MAO, and it is a creative contribution. Then some single-site catalysts were supported on the new MgCl_2 support, and the resulted solid catalysts were tested in ethylene polymerization, the results indicated that:1.XRD and IR analyses indicate that MAO does be coordinated with MgCl_2, which is in good agreement with the results obtained by XPS;2.co-mlling time had no obvious effect on the texture of support after 12 hours;3.In this work, MgCl_2 was co-milled with solid MAO for different hours, and then complex 3 was supported on these co-milled supports. It was found that co-milling time markedly influences the activity of solid catalysts, but it had negligible effect on the kinetic profile and the properties of resultant PE.

XPS研究结果表明,MAO不仅仅只和乙醇作用,MAO还与MgCl_2本身有一定的作用,这是一个极为重要的发现;3、通过ICP和EDX表征,发现载体的脱醇温度直接影响着元素在固体催化剂中的含量及分布;4、脱醇温度极大地影响着负载苯氧基亚胺类催化剂的活性和聚合物的性能,特别是原始载体经160℃活化4小时制备得到的固体催化剂MSPC-5的活性明显高于其他脱醇温度条件下制得的固体催化,并且催化剂寿命长,表现出稳定的动力学行为,最终获得了高堆密度(大于0.35g/ml)的球形聚乙烯颗粒;5、本文选择MSPC-5为研究对象,考察了聚合反应参数对催化剂的活性及其聚合物的影响,研究发现:不同的烷基铝对催化剂具有非常重要的影响,特别足TIBA对MSPC-5的助催化活性最高,烷基铝的加入量有一个较佳值,聚合温度为80度时活性最高,H_2的加入使催化剂的活性明显降低且聚合物的分子量也减小;、新型氯化镁载体负载单活性中心催化剂催化乙烯聚合本文创造性采用固体MAO与无水氯化镁直接进行共研磨,制备出了一种的新型的氯化镁载体,并将该载体用于多种单活性中心催化剂的负载化研究,研究表明:1、通过BET、XRD的表征,再次证实了MAO与MgCl_2之间具有直接作用,与XPS的研究结果相一致;2、当研磨时间高于12小时时,延长研磨时间对载体的结构没有显著的影响;3、将配合物3负载于共研磨时间不同的一系列载体上,乙烯聚合结果表明,尽管共研磨时间对负载催化剂的活性具有明显的影响,但是它对聚合物的性能以及催化剂的影响不明显。

Dealcoholization temperature markedly influences the surface area and porosity of the resultant MAO-supports. When the support was pretreated at lower or higher temperature, the corresponding MAO-support shows very low surface area; 2.XRD and IR analyses indicate that MAO has reacted with the residual ethanol in the supports, which is an important manner to get MAO fixed on the carrier. Morever, XPS analyse indicates that MAO can also be coordinated with MgCl_2, which is another way to get MAO fixed on the support; 3.ICP and EDX analyses indicate that dealcoholization temperature not only determined the element content on the solid catalyst, but also influences the element distribution on the carrier; 4.The activities of the supported phenoxy-imine catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature. The support (MSP-5) obtained by treating MgCl_2·2.56C_2H_5OH at 160℃for 4 h, then modified by MAO is very effective for immobilizing complex 3, the resultant solid catalyst (MSPC-5) shows very high activity in ethylene polymerization, and its kinetics of polymerization is stable during the reaction process. Finally, PEs with spherical morphology and high bulk density (over 0.35g/ml) were obtained, without reactor fouling; 5.In this work, polymerization conditions such as alkylaluminums, Al/Zr ratio, temperature and H_2 had a pronounced effect on the activity of MSPC-5 and properties of PE;(3). New MgCl_2-Supported Single-Site Catalysts for Ethylene Polymerization In this work, a kind of new MgCl_2 support was obtained by anhydrous MgCl_2 co-milled with solid MAO, and it is a creative contribution. Then some single-site catalysts were supported on the new MgCl_2 support, and the resulted solid catalysts were tested in ethylene polymerization, the results indicated that: 1.XRD and IR analyses indicate that MAO does be coordinated with MgCl_2, which is in good agreement with the results obtained by XPS; 2.co-mlling time had no obvious effect on the texture of support after 12 hours; 3.In this work, MgCl_2 was co-milled with solid MAO for different hours, and then complex 3 was supported on these co-milled supports. It was found that co-milling time markedly influences the activity of solid catalysts, but it had negligible effect on the kinetic profile and the properties of resultant PE.

XPS研究结果表明,MAO不仅仅只和乙醇作用,MAO还与MgCl_2本身有一定的作用,这是一个极为重要的发现; 3、通过ICP和EDX表征,发现载体的脱醇温度直接影响着元素在固体催化剂中的含量及分布; 4、脱醇温度极大地影响着负载苯氧基亚胺类催化剂的活性和聚合物的性能,特别是原始载体经160℃活化4小时制备得到的固体催化剂MSPC-5的活性明显高于其他脱醇温度条件下制得的固体催化,并且催化剂寿命长,表现出稳定的动力学行为,最终获得了高堆密度(大于0.35g/ml)的球形聚乙烯颗粒; 5、本文选择MSPC-5为研究对象,考察了聚合反应参数对催化剂的活性及其聚合物的影响,研究发现:不同的烷基铝对催化剂具有非常重要的影响,特别足TIBA对MSPC-5的助催化活性最高,烷基铝的加入量有一个较佳值,聚合温度为80度时活性最高,H_2的加入使催化剂的活性明显降低且聚合物的分子量也减小;、新型氯化镁载体负载单活性中心催化剂催化乙烯聚合本文创造性采用固体MAO与无水氯化镁直接进行共研磨,制备出了一种的新型的氯化镁载体,并将该载体用于多种单活性中心催化剂的负载化研究,研究表明: 1、通过BET、XRD的表征,再次证实了MAO与MgCl_2之间具有直接作用,与XPS的研究结果相一致; 2、当研磨时间高于12小时时,延长研磨时间对载体的结构没有显著的影响; 3、将配合物3负载于共研磨时间不同的一系列载体上,乙烯聚合结果表明,尽管共研磨时间对负载催化剂的活性具有明显的影响,但是它对聚合物的性能以及催化剂的影响不明显。

The simulation results of the cylinder-block model were given in the article, consistent with that of Middlemen"s. It was shown that the block part could improve the uniformity of the flow distribution. The analysis of the flow field of some materials with different power-law factor in the die designed by Mckelvey was close to that of Mckelvey"s. It was shown that the flow distribution was uniform in the die that can producesheets with 1200mm in width. During the analysis the flow channel was divided into several parts to get the details about the fluid flow in each area. A conclusion was drawn after analyzing the influence of the die pressure on the flow distribution, that the higher pressure is good for the output and bad for the uniformity of the distribution. Simulation of the die applying the cylindrical main runner showed the fact that when the cylinder replaced the cone the change of uniformity was trivial. The uniformity of the non-block flow channel was so poor that the block in the proper position of the die channel was necessary. The project of the die for the wider sheet was put forth, and the analysis of the fluid flow in the die was shown.

本文模拟了圆柱管缝隙流模型的三维流动场,得到了与Middlemen结论一致的流动均匀性,并通过模拟直观地展示了采用阻尼块可以改善挤出均匀性的现象;分析了多种幂率指数的流体在Mckelvey等人设计的流道模型中的流动分布,得到了与Mckelvey的分析结果接近的压力降和流量偏差;本文建立了1200mm幅宽机头流道的三维有限元模型,并逐个分析各个区域和多个截面的流动分布状况,由此揭示了1200mm幅宽L-型机头流道内的流北京化工大学硕士学位论文动分布基本均匀,并在分析了机头压力对于挤出流动分布的影响后得出结论:较高的机头压力可以获得较大的产量,但是不利于物料均匀分布;模拟了采用圆柱管主流道时机头流道内的流动分布,得出结论:主流道由圆锥管改为圆柱管时对流动均匀性影响不大,通过设置适当的阻尼仍然可以达到挤出平衡;模拟了两端进料式圆柱管无阻尼流道的流动均匀性后得到结论:两端进料式无阻尼结构的流动均匀性较差,宽机头中仍然有必要设置阻尼块;确定宽幅机头流道的基本方案,并设计了一种宽幅防水卷材挤出机头流道的结构,通过流动模拟表明该种结构的流动均匀性较好;考察了宽幅机头对于不同厚度片材的挤出适应性,得到结论:当生产不同厚度的片材时,阻尼块高度需要调整。

The compatibility of both Gvirens and B.firmus was researched. The fermentation filtrate of Gvirens , under the concentration of 70%, had not distinct inhibitory activity to B.firmus, the biomass of B.firmus would decrease with above the 70% filtrate of Gvirens, but the fermentation filtrate of B.firmus had not inhibitive role to Gvirens. 7, The cooperation control of both Gvirens and B.firm to the pine needle blight was explored:(1) Pathogen inoculation happened prior to the bio-control treatment for 7 days, however, the disease index and control effect had not distinct differences in any treatments even if combination of the two antagonists, but the susceptibility for different kind of pine were different.(2)when antagonist and pathogen were inoculated at the same time, some control effect to the pine needle blight, including certain extent cooperation control of both Gvirens and B.firm were proved, but it wasn't distinct when two antagonists used separately, and the change of the antagonist concentration had little effect to the control effect.

G.virens与B.firmus对松赤枯病的协同控制显示:(1)预先接种病菌后(7天)再进行生物防治处理,不管那种情况,感病指数和防治效果在处理间差异不明显,浓度影响无显著差异,即使是两种生防制剂联合作用也未显著提高其防效,但不同树种间的感病性有明显差异;(2)领抗菌与病原菌同时接种,对松赤枯病有一定防治效果,两菌联合有一定的协同作用,两菌分别单独施用防效差异不显著,浓度变化对防效影响不大;(3)预先接种颇抗菌能显著提高防治效果,两菌联合处理防效更优,感病树种的感病指数可降至13一15,抗病树种的感病指数可控制在3%左右;在同一浓度下B.f1'r功US、叹叮厂即s间无显著差异,在同一领抗菌下,浓度愈高,防效愈高:松,(4)三种生防接种方式的平均效果分析表明,叹F行ens最高平均防效49.5%黑 B。

In this paper, as a typical lewis acid, anhydrous aluminum (AlCl_3) was used as the catalyst to get PP/PS blends compatibilized by in-situ Fridel-Crafts alkylation. The effects on PP and PS components of AlCl_3 were investigated first, mainly by rheology, including steady rheology method and dynamic rheology method. Then the in-situ reactions in PP/PS alloys under different conditions were executed and studied in detail by selective Soxhlet solvent extraction. And at the same time, the evolutions of phase structures of PP/PS and the resulted PP/PS/AlCl_3 alloys were investigated by SEM and SALS. The steady and dynamic rheological behaviors of in-situ compatibilized PP/PS alloys were obtained systematically.

本文选用典型路易斯酸无水氯化铝(AlCl_3)作为催化剂,利用烷基化反应机理,对PP/PS合金直接进行原位催化反应增容,以流变学方法(包括静态流变和动态流变学方法)为主,详细探讨无水AlCl_3对PP/PS合金体系中PP和PS两组分的影响,并在此基础上进一步系统研究无水AlCl_3原位催化增容PP/PS合金的相结构演变及增容反应特征,然后对不同原位催化增容条件下获得增容合金材料的流变行为特征作了深入探讨。

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