无反应的

The second reaction we tested was diastereoselective Michael-Aldol annulation of -keto ester 121 with methacrolein to give a key intermediate for synthesizing (--Huperzine A.

通过对反应条件的筛选，我们得到的最好的结果是以-乳酸苄酯为手性辅基的β-酮酯121i为底物，以(1R， 2R)-环己二胺衍生的手性胍85i为催化剂，以无水四氢呋喃为溶剂，在-20℃反应，得到的产物的de值为73.2%。

The present invention relates to a coating composition comprising; A at least one polyester oligomer prepared from reactants comprising a 20 60 wt.% of at least one polyol, b 5 30 wt.% of at least one polycarboxylic acid selected from the group of cyclic polycarboxylic acids, the esters or the anhydrides thereof, wherein the carboxyl groups are separated by 3 carbon atoms or less, and from the group of alpha , beta -saturated acyclic polycarboxylic acids, the esters or the anhydrides thereof, and c 20 60 wt % of at least one monocarboxylic acid, the sum of the wt.% indicated for the reactants,, and always being 100 wt.%, and the oligomer being a low-viscosity oligomer having a weight average molecular weight Mw of less than 5,000, and a hydroxyl number in the range of about 200 to about 400 mg KOH/g oligomer, and B at least one polyisocyanate.

本发明涉及一种包含如下组分的涂料组合物：A至少一种由包含如下成分的反应物制备的聚酯低聚物：a20-60wt％至少一种多元醇，b5-30wt％至少一种选自其中羧基被3个或更少碳原子隔开的环状多元羧酸、其酯或酸酐以及选自α，β-饱和的无环多元羧酸、其酯或酸酐的多元羧酸，以及c20-60wt％至少一种一元羧酸，其中反应物、和的wt％之和总是为100wt％，所述低聚物是重均分子量Mw低于5000且羟基值为约200-约400mg KOH/g低聚物的低粘度低聚物，以及B至少一种多异氰酸酯。

Effects of some major factors on deoxidize rate of silver, such as Mix ratio connection of tartaric acid and glucose, over all concentration of mixed liquid, the pH level, the reaction temperature, the reaction time etc.

考察了酒石酸与葡萄糖的配比关系、还原混合液的总浓度、pH值、反应温度、反应时间对银还原率的影响，得出了酒石酸与葡萄糖、无水乙醇的质量比为1：2.6：1，pH值为12，在室温下放置时间为3-5d，银的还原率大于92.7%的最佳条件，总回收的金属银纯度为98.2%。

Fuse tartar therapy:The tooth gold biotechnology product that contains a natural plant through to lift to do has no chemistry additive, just like flavor, don't need into appetite absorption, brush teeth to gargle and then can see obvious effect just after needing through contain, use in brief, safety Gao, belong to have no pain go to stone, principle be pass to refine from the plant but of essence composition, reaction happen with tartar this kind of chemistry derivatives, thus attain thorough gum fuse tartar of effect, the tooth stone calculus sheds off to recover the sheen that tooth surface originally possessed, passing to brush teeth will have been already fused of gums bottom the tartar clean up, after return can plus the 1 F protection film in the tooth surface, make the tartar no longer easily re- adhered to.

溶解牙石疗法：通过口含天然植物提练的牙齿黄金生物科技产品，无任何化学添加剂，无异味，无需进入肠胃吸收，只需要通过口含后刷牙漱口就可以看到明显效果，使用简单，安全性高，属于无痛去石，原理就是通过从植物中提炼而出的精华成份，跟牙石这种化学衍生物发生反应，从而达到深入牙龈溶解牙石的功效，牙结石脱落恢复牙齿表面原有的光泽，通过刷牙可将已溶解的龈下牙石清理出来，之后还能在牙齿表面加上一层保护膜，让牙石不再容易重新附着。

The results showed that the inhibition of the ERK pathway in dHP resulted in anhedonia and anxiety-like behavior, and the ERK pathway inhibition in the mPFC induced anhedonia and locomotor impairment in rats.

但值得提出的是两个脑区ERK通路在对具体的抑郁行为表现的调节上存在一定的差异，如海马ERK信号阻断引起显著的焦虑行为反应而无活力水平的降低，而前额叶皮质ERK通路阻断则表现了活力降低而无焦虑行为，从而表现了一定的脑区特异性。

The results showed that the inhibition of the ERK pathway in dHP resulted in anhedonia and anxiety-like behavior, and the ERK pathway inhibition in the mPFC induced anhedonia and locomotor impairment in rats. The phosphorylation of the cyclic AMP-responsive-element-binding protein was decreased following the ERK pathway inhibition either in dHP or mPFC.

但值得提出的是两个脑区ERK通路在对具体的抑郁行为表现的调节上存在一定的差异，如海马ERK信号阻断引起显著的焦虑行为反应而无活力水平的降低，而前额叶皮质ERK通路阻断则表现了活力降低而无焦虑行为，从而表现了一定的脑区特异性。

Among these results, we suggested that the monomer structure play a important role between E-O performances and morphology. Monomer STD02 shows fastest response time, and monomer M3 exhibits slowest one. As a result for roughness, it's the same with response time. From SEM photograph, the beadlike morphology was obtained from monomers without spacers. On the other hand, the filberlike morphology was obtained from monomers with spacers. It's suggested that the more harder structure will lead to the former, and the more softer structure will lead to the latter.

发现 STD02 反应时间最快，而 M3 则是最慢，而粗糙度大小也是与反应时间相符合，最大的是 STD02 而最小的是 M3，在 SEM 下结果显示，各单体所呈现的型态皆为颗粒状且排列均匀，因无含烷链段关系导致形成的型态为颗粒状，论文里有提到另一种单体含烷链段其所形成的型态为纤维状，以结构上来看，越是刚硬之单体所形成的型态都较易为水滴或是米粒状，而结构上越是柔软，所形成的型态都较易为稻穗或是纤维状。

The encapsulated TiO〓 particles by polymer were obtained with soapless emulsion polymerization of methyl methacrylate in water in the presence of the pretreated TiO〓 particles.

一种是用偶联剂钛酸丁酯对亲水性TiO〓粒子进行预处理，钛酸丁酯与TiO〓表面羟基反应，交联到TiO〓粒子表面，使TiO〓粒子表面由亲水性转变为憎水性，改善无机粉体与有机单体的亲合性，再进行TiO〓存在下甲基丙烯酸甲酯的无皂乳液聚合，即可得到TiO〓-PMMA复合粒子：另一种方法是用表面活性剂对TiO〓进行预处理，再进行TiO〓粒子存在下甲基丙烯酸甲酯的无皂乳液聚合，TiO〓粒子表面可形成一层均匀的聚合物膜，提出了包覆机理，指出单体在无机粉体表面发生聚合的关键是预先在粒子表面形成聚合场所，即吸附一层表面活性剂。

In an attempt to evaluate the safety and efficacy of Healon in trabeculectomy, 20 eyes with Healon and 20 eyes without Healon injection after trabeculectomy are compared. Trabeculectomy using Healon will not induce transient rise of intraocular pressure. By filling the anterior chamber with Healon, a tamponing effect results which will maintain a deep chamber and reduce complications such as flat anterior chamber, choroidal detachment and striate keratopathy in the early postoperative period. In long-term evaluation there is no difference in pressure control, conjunctival scarring and corneal endothelial cell loss between Healon group and Non-Healon group.关键词 trabeculectomy , flat anterior chamber , choroidal detachment , intraocular pressure

为了评估Healen在小梁切除术中之疗效及安全性，选20位接受小梁切除术者，同时注射Healon於前房为实验对象，另20位接受传统小梁切除术为对照组，发现使用Healon并不会引起一过性眼压上升的现象，Healon注入前房，产生填塞作用，最大的好处是可以维持前房深度，减少术后合并症如前房消失，脉络膜剥离及角膜水肿等，然长期追踪，对於降眼压的幅度，不因使用Healon而可达到低眼压状态，也不会减少结合膜瘢痕化而促进房水引流，然Healon系一无毒，无炎性，无抗原性高黏稠性的物质，不因使用而发生炎性反应，同时有保护角膜内层细胞的功能。

Histologically, the seminiferous tubules contained numerous Sertoli cells and more Sertoli-spermatozoa complexes, accompanied by the depletion of Leydig cells with deeply stained nuclei. Mature spermatozoa were stored up in the epididymis, but only a few in the efferent ducts. In the second place was testicular atrophy（32/120; 26.7%）. The seminiferous tubules showed moderate to severe inactivity of spermiogenesis with evidence of only spermatogonia, spermatocytes and Sertoli cells. The Leydig cells were obviously decreased in numbers associated with decrease of lipid droplets in their cytoplasms. Testicular hypoplasia was the third disorders（22/120; 18.3%）. Only a few spermatogonia and Sertoli cells appeared without any spermiogenesis. The associated changes was decreased in Leydig cells and fibrous hyperplasia in the interstitium.Epididymal stones were sometimes found（12/120; 10%）. Grossly, yellowish-white nodules with various sizes and firm in consistency were observed in the epididymis and the front efferent ducts. Microscopically, the epididymal ducts were dilated with voluminous spermatozoa storage, even showed calcification in severe cases. The deposited calcium salts were stained positively by Von Kossa and Alizarin red methods.Amyloidosis was also detected in 10 roosters（8.3%）. Eosinophilic, homogeneous, amyloid-like substances were deposited mainly in the testicular interstitium and the periphery of blood vessels. These substances showed positive reaction by Congo red staining. Five roosters（4.2%）had Marek's lesions in the testis, epididymis and peripheral nerves with infiltration of pleomorphic lymphocytes. Only one case showed epithelial necrosis of seminiferous tubules accompanied by fibrous proliferation in the interstitium.

结果发现，在总共搜集的120个病例中，其中因年老所导致的产精力不佳为最多，占38例（31.7%），於镜下可见大量精虫黏附於Sertoli cell的表面，并可见Sertoli cell数量明显增多而Leydig cell明显减少，且其细胞核呈现浓染的现象，而在其副睪中仍可见到成熟精虫蓄留於管腔中，但在其输精管内却只有少量精虫存在；其次为睪丸萎缩，占32例（26.7%），镜下可见中度至重度无造精作用，其生精小管中只见到精母细胞、精原细胞及Sertoli cell存在，但Leydig cell数量明显减少且其细胞质内的脂质也明显减少；睪丸发育不全，占22例（18.3%），於生精小管内只见到精母细胞及少量Sertoli cell存在，不见造精细胞分化，於生精小管间质可见Leydig cell减少并伴随结缔组织增生；副睪结石，占12例（10%），肉眼下可在副睪及输精管前段见到黄白色大小不一的结节，触感坚硬，於镜下可见副睪管扩张并有大量成熟精虫蓄积，严重时可见钙化现象，以Von Kossa及茜素红染色均呈阳性反应；类淀粉沉著症，占10例（8.3%），镜下在睪丸间质及血管周围可见粉红均质样的物质沉积，以刚果红染色成阳性反应；马立克病，占5例（4.2%），镜下可在睪丸、副睪实质及周边神经内均可见到嗜碱性大小不一的淋巴样细胞浸润；睪丸坏死，占1例（0.8%），镜下可见生精小管上皮细胞坏死脱落及间质结缔组织增生。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。