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This dissertation involves the study of the growth dynamics of colloidal particles under unequilibrium and irreversibility condition. Firstly, it is of interest to investigate whether the ideal diffusion or reaction-limited aggregation universal behavior can be observed for the initially polydisperse practical system of basic yttrium carbonate as well. The fractal structure of basic yttrium carbonate aggregate cluster was observed using transmission eletron microscopy. The aggregation kinetics of basic yttrium carbonate colloids was studed using dynamic 1ight-scattering techniques. At 1.00mol/l NaCl solution the fast diffusion-limited aggregation behavior was observed with an increase in the aggregate size over time described by a power law. The aggregates are characterized by a fractal dimension D=1.82. The disordered and ramified cluster is consisted of primary colloidal particles and tenuous and more open. These are in good agreement with those observed for other colloidal system such as colloidal gold (1.86), silica (1.85) and polystyrene latex (1.82) in diffusion-limited aggregation from the static and dynamic light scattering by Lin. Therefore ideal diffusion-limited aggregation behavior can be observed in practical polydisperse system as well. Smoluchwski and fractal theories were used to obtain the aggregation rate constant for initially polydisperse system for the first time.

本论文研究胶粒的非平衡不可逆聚集动态学,分为两个部分,第一部分是通过实验研究一个新的初始多分散的碱式碳酸钇胶粒实际体系中,聚集标度性质的普适性,即使用透射电子显微技术观测聚集粒子簇的分形结构,使用动态激光光散射研究碱式碳酸钇胶粒的聚集动力学,胶粒带电而产生静电排斥作用使得碱式碳酸钇胶粒处于稳定状态,当加入电解质NaCl溶液时,碱式碳酸钇胶粒间的Debye-Hückel屏蔽距离缩短,从而降低静电排斥能垒,引起胶粒发生不可逆聚集,加入电解质NaCl的浓度为1.00mol/l时,碱式碳酸钇胶粒进行快速聚集,经历扩散控制聚集机理,形成结构疏松、更为开放的分形聚集粒子簇,其分形维数为1.82,碱式碳酸钇胶粒聚集增长动力学遵循幂函数增长规律,与Lin等使用静态激光光散射和动态激光光散射测量硅胶(1.85)、金胶(1.86)和聚苯乙烯胶乳(1.82)在扩散控制聚集状态形成聚集粒子簇的分形维数值以及粒子簇聚集增长的动力学规律相一致,表明胶粒聚集标度性质的普适性质在初始多分散的实际体系中也是存在的,首次由动态激光光散射的实验数据得到初始多分散胶粒分形粒子簇的聚集速率常数,并且其值与Smoluchowski聚集速率理论预期相符。

Under the background of digital DEM of maor mountain area, and through the program of Avenue in Arcview, the result of potential ravine highly inosculates with the real ravine. With the comparison of potential ravine and real ravine, it can reflect the developing tendency of ravine in this area. Through positioning with GPS and investigation in this area, we can divide the potential ravine of this area into three forms, that is parallel ravine area steep ripe ravine area and evenness swamp area. It can provide scientific reference for forest management and tree planting, and it is a new theory to prevent soil and water loss, and carry through the ravine controlling by people.

在数字化生成的帽儿山地区DEM基础上,通过二次开发生成的潜在沟系,具有与现实沟系高度的吻合性,并通过与现实沟系的比较,能客观的反映出该地区沟系发生、发展的趋势,借助于GPS的定位及实际踏查研究,可将帽儿山地区的潜在沟系划分为平行沟系区、陡坡显沟区和平坦沼泽区三种类型,可为合理的森林经营和植树造林提供科学的借鉴,并为防止水土流失,进行沟系治理提供了新的理论依据。

However the economic law has changed a lot during the economic transformation, such as, more autonomy legislation other than restricted legislation, mono-legislative bodies changed into diversity and standardization, legislative process changed from self-contained into civilized, the legislative right changed into clear other than obscure, and the legislative object changed form political into independent, which is obvious to everyone.

经济立法在经济转型过程中发生了巨大转变,如从受制性立法到自主性立法、从立法主体的单一化到多元化和规范化、从立法程序的封闭化到民主化、从立法权限的模糊到明晰、从立法目的政治化到独立化等方面的转变,而对这些转变的研究正是我们研究新背景下经济法发展的重点之一。

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